Potentiostatic transients related to the electrolytic oxidation of KSCN and mixtures of NaSCN + KSCN melts on polycrystalline platinum

Autores
Vásquez Moll, Víctor Dennis; Arvia, Alejandro Jorge
Año de publicación
1985
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Potentiostatic transients related to the electrolytic oxidation of molten thiocyanate (KSCN and KSCN + NaSCN, 0.7:0.3 mol/mol) on polycrystalline Pt obtained in the 168–290°C range are interpreted in terms of a nucleation and growth mechanism under diffusion control which involves the formation of two different products constituting the passivating anodic layer. The different adjustable parameters are compatible with the possible molecular structure of the anodic layer.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Ciencias Exactas
Química
electrolytic oxidation
polycrystalline Pt
passivating anodic layer
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/125787
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/125787
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Potentiostatic transients related to the electrolytic oxidation of KSCN and mixtures of NaSCN + KSCN melts on polycrystalline platinumVásquez Moll, Víctor DennisArvia, Alejandro JorgeCiencias ExactasQuímicaelectrolytic oxidationpolycrystalline Ptpassivating anodic layerPotentiostatic transients related to the electrolytic oxidation of molten thiocyanate (KSCN and KSCN + NaSCN, 0.7:0.3 mol/mol) on polycrystalline Pt obtained in the 168–290°C range are interpreted in terms of a nucleation and growth mechanism under diffusion control which involves the formation of two different products constituting the passivating anodic layer. The different adjustable parameters are compatible with the possible molecular structure of the anodic layer.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1985-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf291-300http://sedici.unlp.edu.ar/handle/10915/125787enginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/0022072885800280info:eu-repo/semantics/altIdentifier/issn/0022-0728info:eu-repo/semantics/altIdentifier/doi/10.1016/0022-0728(85)80028-0info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:30:23Zoai:sedici.unlp.edu.ar:10915/125787Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:30:24.185SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Potentiostatic transients related to the electrolytic oxidation of KSCN and mixtures of NaSCN + KSCN melts on polycrystalline platinum
title Potentiostatic transients related to the electrolytic oxidation of KSCN and mixtures of NaSCN + KSCN melts on polycrystalline platinum
spellingShingle Potentiostatic transients related to the electrolytic oxidation of KSCN and mixtures of NaSCN + KSCN melts on polycrystalline platinum
Vásquez Moll, Víctor Dennis
Ciencias Exactas
Química
electrolytic oxidation
polycrystalline Pt
passivating anodic layer
title_short Potentiostatic transients related to the electrolytic oxidation of KSCN and mixtures of NaSCN + KSCN melts on polycrystalline platinum
title_full Potentiostatic transients related to the electrolytic oxidation of KSCN and mixtures of NaSCN + KSCN melts on polycrystalline platinum
title_fullStr Potentiostatic transients related to the electrolytic oxidation of KSCN and mixtures of NaSCN + KSCN melts on polycrystalline platinum
title_full_unstemmed Potentiostatic transients related to the electrolytic oxidation of KSCN and mixtures of NaSCN + KSCN melts on polycrystalline platinum
title_sort Potentiostatic transients related to the electrolytic oxidation of KSCN and mixtures of NaSCN + KSCN melts on polycrystalline platinum
dc.creator.none.fl_str_mv Vásquez Moll, Víctor Dennis
Arvia, Alejandro Jorge
author Vásquez Moll, Víctor Dennis
author_facet Vásquez Moll, Víctor Dennis
Arvia, Alejandro Jorge
author_role author
author2 Arvia, Alejandro Jorge
author2_role author
dc.subject.none.fl_str_mv Ciencias Exactas
Química
electrolytic oxidation
polycrystalline Pt
passivating anodic layer
topic Ciencias Exactas
Química
electrolytic oxidation
polycrystalline Pt
passivating anodic layer
dc.description.none.fl_txt_mv Potentiostatic transients related to the electrolytic oxidation of molten thiocyanate (KSCN and KSCN + NaSCN, 0.7:0.3 mol/mol) on polycrystalline Pt obtained in the 168–290°C range are interpreted in terms of a nucleation and growth mechanism under diffusion control which involves the formation of two different products constituting the passivating anodic layer. The different adjustable parameters are compatible with the possible molecular structure of the anodic layer.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description Potentiostatic transients related to the electrolytic oxidation of molten thiocyanate (KSCN and KSCN + NaSCN, 0.7:0.3 mol/mol) on polycrystalline Pt obtained in the 168–290°C range are interpreted in terms of a nucleation and growth mechanism under diffusion control which involves the formation of two different products constituting the passivating anodic layer. The different adjustable parameters are compatible with the possible molecular structure of the anodic layer.
publishDate 1985
dc.date.none.fl_str_mv 1985-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/125787
url http://sedici.unlp.edu.ar/handle/10915/125787
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/0022072885800280
info:eu-repo/semantics/altIdentifier/issn/0022-0728
info:eu-repo/semantics/altIdentifier/doi/10.1016/0022-0728(85)80028-0
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
291-300
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.070432

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