A phenomenological approach to ionic mass transfer at rotating disc electrodes with a hanging column of electrolyte solution

Autores
Elsner, Cecilia Inés; Schilardi, Patricia Laura; Marchiano, Susana Lucy
Año de publicación
1993
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Experimental data for the behaviour of a rotating disc electrode with a hanging electrolyte column of varying height are presented. A correlation involving the limiting current density, the rotation speed, and the physicochemical properties of the solution is established. The macroscopic effective copper electrodeposit thickness distribution is determined. Results obtained for different electrode designs are discussed in terms of an additional flow of reactant, and an apparent change in the effective electrode area caused by liquid column contraction. From the results the most suitable experimental conditions for the application of the rotating disc electrode with a hanging column of electrolyte to electrochemical kinetic studies can be found.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Química
Ciencias Exactas
rotating disc electrode
copper electrodeposit
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/141717
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/141717
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling A phenomenological approach to ionic mass transfer at rotating disc electrodes with a hanging column of electrolyte solutionElsner, Cecilia InésSchilardi, Patricia LauraMarchiano, Susana LucyQuímicaCiencias Exactasrotating disc electrodecopper electrodepositExperimental data for the behaviour of a rotating disc electrode with a hanging electrolyte column of varying height are presented. A correlation involving the limiting current density, the rotation speed, and the physicochemical properties of the solution is established. The macroscopic effective copper electrodeposit thickness distribution is determined. Results obtained for different electrode designs are discussed in terms of an additional flow of reactant, and an apparent change in the effective electrode area caused by liquid column contraction. From the results the most suitable experimental conditions for the application of the rotating disc electrode with a hanging column of electrolyte to electrochemical kinetic studies can be found.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1993info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf1181-1186http://sedici.unlp.edu.ar/handle/10915/141717enginfo:eu-repo/semantics/altIdentifier/issn/0021-891xinfo:eu-repo/semantics/altIdentifier/issn/1572-8838info:eu-repo/semantics/altIdentifier/doi/10.1007/bf00625593info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/Creative Commons Attribution 4.0 International (CC BY 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:32:11Zoai:sedici.unlp.edu.ar:10915/141717Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:32:12.179SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv A phenomenological approach to ionic mass transfer at rotating disc electrodes with a hanging column of electrolyte solution
title A phenomenological approach to ionic mass transfer at rotating disc electrodes with a hanging column of electrolyte solution
spellingShingle A phenomenological approach to ionic mass transfer at rotating disc electrodes with a hanging column of electrolyte solution
Elsner, Cecilia Inés
Química
Ciencias Exactas
rotating disc electrode
copper electrodeposit
title_short A phenomenological approach to ionic mass transfer at rotating disc electrodes with a hanging column of electrolyte solution
title_full A phenomenological approach to ionic mass transfer at rotating disc electrodes with a hanging column of electrolyte solution
title_fullStr A phenomenological approach to ionic mass transfer at rotating disc electrodes with a hanging column of electrolyte solution
title_full_unstemmed A phenomenological approach to ionic mass transfer at rotating disc electrodes with a hanging column of electrolyte solution
title_sort A phenomenological approach to ionic mass transfer at rotating disc electrodes with a hanging column of electrolyte solution
dc.creator.none.fl_str_mv Elsner, Cecilia Inés
Schilardi, Patricia Laura
Marchiano, Susana Lucy
author Elsner, Cecilia Inés
author_facet Elsner, Cecilia Inés
Schilardi, Patricia Laura
Marchiano, Susana Lucy
author_role author
author2 Schilardi, Patricia Laura
Marchiano, Susana Lucy
author2_role author
author
dc.subject.none.fl_str_mv Química
Ciencias Exactas
rotating disc electrode
copper electrodeposit
topic Química
Ciencias Exactas
rotating disc electrode
copper electrodeposit
dc.description.none.fl_txt_mv Experimental data for the behaviour of a rotating disc electrode with a hanging electrolyte column of varying height are presented. A correlation involving the limiting current density, the rotation speed, and the physicochemical properties of the solution is established. The macroscopic effective copper electrodeposit thickness distribution is determined. Results obtained for different electrode designs are discussed in terms of an additional flow of reactant, and an apparent change in the effective electrode area caused by liquid column contraction. From the results the most suitable experimental conditions for the application of the rotating disc electrode with a hanging column of electrolyte to electrochemical kinetic studies can be found.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description Experimental data for the behaviour of a rotating disc electrode with a hanging electrolyte column of varying height are presented. A correlation involving the limiting current density, the rotation speed, and the physicochemical properties of the solution is established. The macroscopic effective copper electrodeposit thickness distribution is determined. Results obtained for different electrode designs are discussed in terms of an additional flow of reactant, and an apparent change in the effective electrode area caused by liquid column contraction. From the results the most suitable experimental conditions for the application of the rotating disc electrode with a hanging column of electrolyte to electrochemical kinetic studies can be found.
publishDate 1993
dc.date.none.fl_str_mv 1993
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/141717
url http://sedici.unlp.edu.ar/handle/10915/141717
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0021-891x
info:eu-repo/semantics/altIdentifier/issn/1572-8838
info:eu-repo/semantics/altIdentifier/doi/10.1007/bf00625593
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
Creative Commons Attribution 4.0 International (CC BY 4.0)
dc.format.none.fl_str_mv application/pdf
1181-1186
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.070432

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