Kinetics and mechanism of the electroreduction of anodic layers produced on cadmium in alkaline solution containing sodium sulphide

Autores
Gassa, Liliana Mabel; Saidman, S. B.; Vilche, Jorge Roberto; Arvia, Alejandro Jorge
Año de publicación
1991
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The kinetics of the potentiostatic electroreduction of different anodic layers produced on cadmium in Na₂S containing alkaline solutions has been studied at 25°C. Two types of anodic layer were used: (i) layers produced in the potential range of CdS and Cd(OH)₂ stability, and (ii) layers predominantly composed of CdS. The electroreduction kinetics for both layers can be explained reasonably well throughout the nucleation and growth processes under diffusion control.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Materia
Física
Química
Sodium
Physical Chemistry
Sulphide
Cadmium
Growth Process
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/146526
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/146526
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Kinetics and mechanism of the electroreduction of anodic layers produced on cadmium in alkaline solution containing sodium sulphideGassa, Liliana MabelSaidman, S. B.Vilche, Jorge RobertoArvia, Alejandro JorgeFísicaQuímicaSodiumPhysical ChemistrySulphideCadmiumGrowth ProcessThe kinetics of the potentiostatic electroreduction of different anodic layers produced on cadmium in Na₂S containing alkaline solutions has been studied at 25°C. Two types of anodic layer were used: (i) layers produced in the potential range of CdS and Cd(OH)₂ stability, and (ii) layers predominantly composed of CdS. The electroreduction kinetics for both layers can be explained reasonably well throughout the nucleation and growth processes under diffusion control.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas1991info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf816-823http://sedici.unlp.edu.ar/handle/10915/146526enginfo:eu-repo/semantics/altIdentifier/issn/0021-891Xinfo:eu-repo/semantics/altIdentifier/issn/1572-8838info:eu-repo/semantics/altIdentifier/doi/10.1007/bf01402819info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:32:31Zoai:sedici.unlp.edu.ar:10915/146526Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:32:32.143SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Kinetics and mechanism of the electroreduction of anodic layers produced on cadmium in alkaline solution containing sodium sulphide
title Kinetics and mechanism of the electroreduction of anodic layers produced on cadmium in alkaline solution containing sodium sulphide
spellingShingle Kinetics and mechanism of the electroreduction of anodic layers produced on cadmium in alkaline solution containing sodium sulphide
Gassa, Liliana Mabel
Física
Química
Sodium
Physical Chemistry
Sulphide
Cadmium
Growth Process
title_short Kinetics and mechanism of the electroreduction of anodic layers produced on cadmium in alkaline solution containing sodium sulphide
title_full Kinetics and mechanism of the electroreduction of anodic layers produced on cadmium in alkaline solution containing sodium sulphide
title_fullStr Kinetics and mechanism of the electroreduction of anodic layers produced on cadmium in alkaline solution containing sodium sulphide
title_full_unstemmed Kinetics and mechanism of the electroreduction of anodic layers produced on cadmium in alkaline solution containing sodium sulphide
title_sort Kinetics and mechanism of the electroreduction of anodic layers produced on cadmium in alkaline solution containing sodium sulphide
dc.creator.none.fl_str_mv Gassa, Liliana Mabel
Saidman, S. B.
Vilche, Jorge Roberto
Arvia, Alejandro Jorge
author Gassa, Liliana Mabel
author_facet Gassa, Liliana Mabel
Saidman, S. B.
Vilche, Jorge Roberto
Arvia, Alejandro Jorge
author_role author
author2 Saidman, S. B.
Vilche, Jorge Roberto
Arvia, Alejandro Jorge
author2_role author
author
author
dc.subject.none.fl_str_mv Física
Química
Sodium
Physical Chemistry
Sulphide
Cadmium
Growth Process
topic Física
Química
Sodium
Physical Chemistry
Sulphide
Cadmium
Growth Process
dc.description.none.fl_txt_mv The kinetics of the potentiostatic electroreduction of different anodic layers produced on cadmium in Na₂S containing alkaline solutions has been studied at 25°C. Two types of anodic layer were used: (i) layers produced in the potential range of CdS and Cd(OH)₂ stability, and (ii) layers predominantly composed of CdS. The electroreduction kinetics for both layers can be explained reasonably well throughout the nucleation and growth processes under diffusion control.
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
description The kinetics of the potentiostatic electroreduction of different anodic layers produced on cadmium in Na₂S containing alkaline solutions has been studied at 25°C. Two types of anodic layer were used: (i) layers produced in the potential range of CdS and Cd(OH)₂ stability, and (ii) layers predominantly composed of CdS. The electroreduction kinetics for both layers can be explained reasonably well throughout the nucleation and growth processes under diffusion control.
publishDate 1991
dc.date.none.fl_str_mv 1991
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/146526
url http://sedici.unlp.edu.ar/handle/10915/146526
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/0021-891X
info:eu-repo/semantics/altIdentifier/issn/1572-8838
info:eu-repo/semantics/altIdentifier/doi/10.1007/bf01402819
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
816-823
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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score 13.070432

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