Lanthanum Derivative from “Tara” Tannin for Steel Temporary Protection

Autores
D'Alessandro, Oriana; Selmi, Gonzalo Julián; Deyá, Marta Cecilia; Di Sarli, Alejandro Ramón; Romagnoli, Roberto
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Tannins are extracted from certain plants and contain numerous phenol groups. They may be employed, together with their derivatives, to formulate protective coatings due to their inhibitive properties. The objective of this research was to synthesize lanthanum “tannates”, to formulate washprimers. Two “Tara” (Caesalpinia spinosa) tannins and 0.1 M La(NO3)3 were employed to obtain the corresponding tannates. The inhibitive action of the tannates was evaluated by linear polarization and corrosion potential measurements employing a SAE 1010 electrode. Lanthanum tannates were used to formulate wash-primers whose anticorrosion performance was evaluated by corrosion potential and ionic resistance measurements. The primers were incorporated in alkyd paint systems and their anticorrosion performance was tested in the salt spray chamber and by electrochemical impedance spectroscopy. Lanthanum tannate primers protected steel and behaved in a similar way to that formulated with zinc tetroxychromate.
Centro de Investigación y Desarrollo en Tecnología de Pinturas
Materia
Ingeniería Química
Lantano
Taninos
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-nd/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/95466

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network_name_str SEDICI (UNLP)
spelling Lanthanum Derivative from “Tara” Tannin for Steel Temporary ProtectionD'Alessandro, OrianaSelmi, Gonzalo JuliánDeyá, Marta CeciliaDi Sarli, Alejandro RamónRomagnoli, RobertoIngeniería QuímicaLantanoTaninosTannins are extracted from certain plants and contain numerous phenol groups. They may be employed, together with their derivatives, to formulate protective coatings due to their inhibitive properties. The objective of this research was to synthesize lanthanum “tannates”, to formulate washprimers. Two “Tara” (Caesalpinia spinosa) tannins and 0.1 M La(NO3)3 were employed to obtain the corresponding tannates. The inhibitive action of the tannates was evaluated by linear polarization and corrosion potential measurements employing a SAE 1010 electrode. Lanthanum tannates were used to formulate wash-primers whose anticorrosion performance was evaluated by corrosion potential and ionic resistance measurements. The primers were incorporated in alkyd paint systems and their anticorrosion performance was tested in the salt spray chamber and by electrochemical impedance spectroscopy. Lanthanum tannate primers protected steel and behaved in a similar way to that formulated with zinc tetroxychromate.Centro de Investigación y Desarrollo en Tecnología de Pinturas2018info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdf3215-3226http://sedici.unlp.edu.ar/handle/10915/95466enginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acs.iecr.7b03317info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2025-09-29T11:20:36Zoai:sedici.unlp.edu.ar:10915/95466Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292025-09-29 11:20:36.936SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Lanthanum Derivative from “Tara” Tannin for Steel Temporary Protection
title Lanthanum Derivative from “Tara” Tannin for Steel Temporary Protection
spellingShingle Lanthanum Derivative from “Tara” Tannin for Steel Temporary Protection
D'Alessandro, Oriana
Ingeniería Química
Lantano
Taninos
title_short Lanthanum Derivative from “Tara” Tannin for Steel Temporary Protection
title_full Lanthanum Derivative from “Tara” Tannin for Steel Temporary Protection
title_fullStr Lanthanum Derivative from “Tara” Tannin for Steel Temporary Protection
title_full_unstemmed Lanthanum Derivative from “Tara” Tannin for Steel Temporary Protection
title_sort Lanthanum Derivative from “Tara” Tannin for Steel Temporary Protection
dc.creator.none.fl_str_mv D'Alessandro, Oriana
Selmi, Gonzalo Julián
Deyá, Marta Cecilia
Di Sarli, Alejandro Ramón
Romagnoli, Roberto
author D'Alessandro, Oriana
author_facet D'Alessandro, Oriana
Selmi, Gonzalo Julián
Deyá, Marta Cecilia
Di Sarli, Alejandro Ramón
Romagnoli, Roberto
author_role author
author2 Selmi, Gonzalo Julián
Deyá, Marta Cecilia
Di Sarli, Alejandro Ramón
Romagnoli, Roberto
author2_role author
author
author
author
dc.subject.none.fl_str_mv Ingeniería Química
Lantano
Taninos
topic Ingeniería Química
Lantano
Taninos
dc.description.none.fl_txt_mv Tannins are extracted from certain plants and contain numerous phenol groups. They may be employed, together with their derivatives, to formulate protective coatings due to their inhibitive properties. The objective of this research was to synthesize lanthanum “tannates”, to formulate washprimers. Two “Tara” (Caesalpinia spinosa) tannins and 0.1 M La(NO3)3 were employed to obtain the corresponding tannates. The inhibitive action of the tannates was evaluated by linear polarization and corrosion potential measurements employing a SAE 1010 electrode. Lanthanum tannates were used to formulate wash-primers whose anticorrosion performance was evaluated by corrosion potential and ionic resistance measurements. The primers were incorporated in alkyd paint systems and their anticorrosion performance was tested in the salt spray chamber and by electrochemical impedance spectroscopy. Lanthanum tannate primers protected steel and behaved in a similar way to that formulated with zinc tetroxychromate.
Centro de Investigación y Desarrollo en Tecnología de Pinturas
description Tannins are extracted from certain plants and contain numerous phenol groups. They may be employed, together with their derivatives, to formulate protective coatings due to their inhibitive properties. The objective of this research was to synthesize lanthanum “tannates”, to formulate washprimers. Two “Tara” (Caesalpinia spinosa) tannins and 0.1 M La(NO3)3 were employed to obtain the corresponding tannates. The inhibitive action of the tannates was evaluated by linear polarization and corrosion potential measurements employing a SAE 1010 electrode. Lanthanum tannates were used to formulate wash-primers whose anticorrosion performance was evaluated by corrosion potential and ionic resistance measurements. The primers were incorporated in alkyd paint systems and their anticorrosion performance was tested in the salt spray chamber and by electrochemical impedance spectroscopy. Lanthanum tannate primers protected steel and behaved in a similar way to that formulated with zinc tetroxychromate.
publishDate 2018
dc.date.none.fl_str_mv 2018
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
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dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/95466
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dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.iecr.7b03317
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
dc.format.none.fl_str_mv application/pdf
3215-3226
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instname:Universidad Nacional de La Plata
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reponame_str SEDICI (UNLP)
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repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
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