Glyphosate runoff and its occurrence in rainwater and subsurface soil in the nearby area of agricultural fields in Argentina
- Autores
- Lupi, Leonardo; Bedmar, Francisco; Puricelli, Marino Marcelo; Marino, Damián; Aparicio, Virginia Carolina; Wunderlin, Daniel; Miglioranza, Karina S.B.
- Año de publicación
- 2019
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Glyphosate-based products are among the most important herbicides applied to enhance the production of food commodities, leading to the worldwide spread of this herbicide. The main goal of this work was to evaluate the off-site transport of glyphosate in a runoff experiment. A micro-plot experiment was conducted to assess the retention, leaching and runoff of glyphosate under rainfall simulation. Glyphosate losses due to spray drift were estimated. Concentrations of glyphosate and AMPA were determined in rainwater and subsurface soil from agricultural and riparian zones. Analyses were performed with UHPLC-MS/MS. Experimental results demonstrated that 88.1% of the applied glyphosate was retained in the surface soil layer (0–9 cm). Glyphosate leaching was negligible compared to its runoff (3.9%) and spray drift (6.9%). Thus, the risk of groundwater pollution would be lower in comparison to that of both surface waters and rainwater. Moreover, under field conditions, glyphosate and AMPA were detected in 52% of the rainwater samples and glyphosate was detected up to 1 m in both soil profiles. Although the experimental application was made with hand-held knapsack under low wind condition to minimize glyphosate aerial dispersion, the spray drift was the main source of glyphosate off-site transport, degrading air quality and rainwater for human consumption. The balance among spray drift, runoff and soil absorption of glyphosate when it was sprayed close to the soil surface (hand held equipment), demonstrated the importance of spray drift in mass balance studies during runoff and leaching experiments with glyphosate.
EEA Balcarce
Fil: Lupi, Leonardo. Universidad Nacional de Mar del Plata. Facultad de Ciencias Agrarias; Argentina
Fil: Bedmar, Francisco. Universidad Nacional de Mar del Plata. Facultad de Ciencias Agrarias;, Argentina
Fil: Puricelli, Marino Marcelo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: Marino, Damián. Universidad Nacional de La Plata, Facultad de Ciencias Exactas; Argentina
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: Wunderlin, Daniel. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Fil: Miglioranza, Karina S.B. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina - Fuente
- Chesmosphere 225 : 906-914 (June 2019)
- Materia
-
Suelo
Glifosato
Agua de Escorrentía
Agua de Lluvia
Experimentación en Campo
Argentina
Soil
Glyphosate
Runoff Water
Rainwater
Field Experimentation - Nivel de accesibilidad
- acceso restringido
- Condiciones de uso
- Repositorio
.jpg)
- Institución
- Instituto Nacional de Tecnología Agropecuaria
- OAI Identificador
- oai:localhost:20.500.12123/5042
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Glyphosate runoff and its occurrence in rainwater and subsurface soil in the nearby area of agricultural fields in ArgentinaLupi, LeonardoBedmar, FranciscoPuricelli, Marino MarceloMarino, DamiánAparicio, Virginia CarolinaWunderlin, DanielMiglioranza, Karina S.B.SueloGlifosatoAgua de EscorrentíaAgua de LluviaExperimentación en CampoArgentinaSoilGlyphosateRunoff WaterRainwaterField ExperimentationGlyphosate-based products are among the most important herbicides applied to enhance the production of food commodities, leading to the worldwide spread of this herbicide. The main goal of this work was to evaluate the off-site transport of glyphosate in a runoff experiment. A micro-plot experiment was conducted to assess the retention, leaching and runoff of glyphosate under rainfall simulation. Glyphosate losses due to spray drift were estimated. Concentrations of glyphosate and AMPA were determined in rainwater and subsurface soil from agricultural and riparian zones. Analyses were performed with UHPLC-MS/MS. Experimental results demonstrated that 88.1% of the applied glyphosate was retained in the surface soil layer (0–9 cm). Glyphosate leaching was negligible compared to its runoff (3.9%) and spray drift (6.9%). Thus, the risk of groundwater pollution would be lower in comparison to that of both surface waters and rainwater. Moreover, under field conditions, glyphosate and AMPA were detected in 52% of the rainwater samples and glyphosate was detected up to 1 m in both soil profiles. Although the experimental application was made with hand-held knapsack under low wind condition to minimize glyphosate aerial dispersion, the spray drift was the main source of glyphosate off-site transport, degrading air quality and rainwater for human consumption. The balance among spray drift, runoff and soil absorption of glyphosate when it was sprayed close to the soil surface (hand held equipment), demonstrated the importance of spray drift in mass balance studies during runoff and leaching experiments with glyphosate.EEA BalcarceFil: Lupi, Leonardo. Universidad Nacional de Mar del Plata. Facultad de Ciencias Agrarias; ArgentinaFil: Bedmar, Francisco. Universidad Nacional de Mar del Plata. Facultad de Ciencias Agrarias;, ArgentinaFil: Puricelli, Marino Marcelo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaFil: Marino, Damián. Universidad Nacional de La Plata, Facultad de Ciencias Exactas; ArgentinaFil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaFil: Wunderlin, Daniel. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Instituto de Ciencia y Tecnología de Alimentos Córdoba; ArgentinaFil: Miglioranza, Karina S.B. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier2019-05-06T14:42:42Z2019-05-06T14:42:42Z2019-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttps://www.sciencedirect.com/science/article/pii/S0045653519305260http://hdl.handle.net/20.500.12123/50420045-6535https://doi.org/10.1016/j.chemosphere.2019.03.090Chesmosphere 225 : 906-914 (June 2019)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/restrictedAccess2025-09-04T09:47:57Zoai:localhost:20.500.12123/5042instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-04 09:47:57.495INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse |
| dc.title.none.fl_str_mv |
Glyphosate runoff and its occurrence in rainwater and subsurface soil in the nearby area of agricultural fields in Argentina |
| title |
Glyphosate runoff and its occurrence in rainwater and subsurface soil in the nearby area of agricultural fields in Argentina |
| spellingShingle |
Glyphosate runoff and its occurrence in rainwater and subsurface soil in the nearby area of agricultural fields in Argentina Lupi, Leonardo Suelo Glifosato Agua de Escorrentía Agua de Lluvia Experimentación en Campo Argentina Soil Glyphosate Runoff Water Rainwater Field Experimentation |
| title_short |
Glyphosate runoff and its occurrence in rainwater and subsurface soil in the nearby area of agricultural fields in Argentina |
| title_full |
Glyphosate runoff and its occurrence in rainwater and subsurface soil in the nearby area of agricultural fields in Argentina |
| title_fullStr |
Glyphosate runoff and its occurrence in rainwater and subsurface soil in the nearby area of agricultural fields in Argentina |
| title_full_unstemmed |
Glyphosate runoff and its occurrence in rainwater and subsurface soil in the nearby area of agricultural fields in Argentina |
| title_sort |
Glyphosate runoff and its occurrence in rainwater and subsurface soil in the nearby area of agricultural fields in Argentina |
| dc.creator.none.fl_str_mv |
Lupi, Leonardo Bedmar, Francisco Puricelli, Marino Marcelo Marino, Damián Aparicio, Virginia Carolina Wunderlin, Daniel Miglioranza, Karina S.B. |
| author |
Lupi, Leonardo |
| author_facet |
Lupi, Leonardo Bedmar, Francisco Puricelli, Marino Marcelo Marino, Damián Aparicio, Virginia Carolina Wunderlin, Daniel Miglioranza, Karina S.B. |
| author_role |
author |
| author2 |
Bedmar, Francisco Puricelli, Marino Marcelo Marino, Damián Aparicio, Virginia Carolina Wunderlin, Daniel Miglioranza, Karina S.B. |
| author2_role |
author author author author author author |
| dc.subject.none.fl_str_mv |
Suelo Glifosato Agua de Escorrentía Agua de Lluvia Experimentación en Campo Argentina Soil Glyphosate Runoff Water Rainwater Field Experimentation |
| topic |
Suelo Glifosato Agua de Escorrentía Agua de Lluvia Experimentación en Campo Argentina Soil Glyphosate Runoff Water Rainwater Field Experimentation |
| dc.description.none.fl_txt_mv |
Glyphosate-based products are among the most important herbicides applied to enhance the production of food commodities, leading to the worldwide spread of this herbicide. The main goal of this work was to evaluate the off-site transport of glyphosate in a runoff experiment. A micro-plot experiment was conducted to assess the retention, leaching and runoff of glyphosate under rainfall simulation. Glyphosate losses due to spray drift were estimated. Concentrations of glyphosate and AMPA were determined in rainwater and subsurface soil from agricultural and riparian zones. Analyses were performed with UHPLC-MS/MS. Experimental results demonstrated that 88.1% of the applied glyphosate was retained in the surface soil layer (0–9 cm). Glyphosate leaching was negligible compared to its runoff (3.9%) and spray drift (6.9%). Thus, the risk of groundwater pollution would be lower in comparison to that of both surface waters and rainwater. Moreover, under field conditions, glyphosate and AMPA were detected in 52% of the rainwater samples and glyphosate was detected up to 1 m in both soil profiles. Although the experimental application was made with hand-held knapsack under low wind condition to minimize glyphosate aerial dispersion, the spray drift was the main source of glyphosate off-site transport, degrading air quality and rainwater for human consumption. The balance among spray drift, runoff and soil absorption of glyphosate when it was sprayed close to the soil surface (hand held equipment), demonstrated the importance of spray drift in mass balance studies during runoff and leaching experiments with glyphosate. EEA Balcarce Fil: Lupi, Leonardo. Universidad Nacional de Mar del Plata. Facultad de Ciencias Agrarias; Argentina Fil: Bedmar, Francisco. Universidad Nacional de Mar del Plata. Facultad de Ciencias Agrarias;, Argentina Fil: Puricelli, Marino Marcelo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina Fil: Marino, Damián. Universidad Nacional de La Plata, Facultad de Ciencias Exactas; Argentina Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina Fil: Wunderlin, Daniel. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina Fil: Miglioranza, Karina S.B. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina |
| description |
Glyphosate-based products are among the most important herbicides applied to enhance the production of food commodities, leading to the worldwide spread of this herbicide. The main goal of this work was to evaluate the off-site transport of glyphosate in a runoff experiment. A micro-plot experiment was conducted to assess the retention, leaching and runoff of glyphosate under rainfall simulation. Glyphosate losses due to spray drift were estimated. Concentrations of glyphosate and AMPA were determined in rainwater and subsurface soil from agricultural and riparian zones. Analyses were performed with UHPLC-MS/MS. Experimental results demonstrated that 88.1% of the applied glyphosate was retained in the surface soil layer (0–9 cm). Glyphosate leaching was negligible compared to its runoff (3.9%) and spray drift (6.9%). Thus, the risk of groundwater pollution would be lower in comparison to that of both surface waters and rainwater. Moreover, under field conditions, glyphosate and AMPA were detected in 52% of the rainwater samples and glyphosate was detected up to 1 m in both soil profiles. Although the experimental application was made with hand-held knapsack under low wind condition to minimize glyphosate aerial dispersion, the spray drift was the main source of glyphosate off-site transport, degrading air quality and rainwater for human consumption. The balance among spray drift, runoff and soil absorption of glyphosate when it was sprayed close to the soil surface (hand held equipment), demonstrated the importance of spray drift in mass balance studies during runoff and leaching experiments with glyphosate. |
| publishDate |
2019 |
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2019-05-06T14:42:42Z 2019-05-06T14:42:42Z 2019-06 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
https://www.sciencedirect.com/science/article/pii/S0045653519305260 http://hdl.handle.net/20.500.12123/5042 0045-6535 https://doi.org/10.1016/j.chemosphere.2019.03.090 |
| url |
https://www.sciencedirect.com/science/article/pii/S0045653519305260 http://hdl.handle.net/20.500.12123/5042 https://doi.org/10.1016/j.chemosphere.2019.03.090 |
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0045-6535 |
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eng |
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Elsevier |
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Elsevier |
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