Glyphosate loss by runoff and its relationship with phosphorus fertilization

Autores
Sasal, Maria Carolina; Demonte, Luisina Delma; Cislaghi, Andrea; Gabioud, Emmanuel Adrian; Oszust, José Daniel; Wilson, Marcelo German; Michlig, Nicolas; Beldoménico, Horacio Ramón; Repetti, María Rosa
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this study was to evaluate the relationship between glyphosate and phosphate fertilizer application and their contribution to surface water runoff contamination. The study was performed in Aquic Argiudoll soil (Tezanos Pinto series). Four treatments were assessed on three dates of rainfall simulation after fertilizer and herbicide application. The soluble phosphorus in runoff water was determined by a colorimetric method. For the determination of glyphosate and aminomethylphosphonic acid (AMPA), a method based on fluorenylmethyloxycarbonyl (FMOC) group derivatization, solid phase extraction (SPE) purification, and ultrahigh-performance liquid chromatography−tandem mass spectrometry (UHPLCMS/MS) was employed. The application of phosphorus fertilizer resulted in an increased loss of glyphosate by runoff after 1 day of application. These results suggest the need for further study to understand the interactions and to determine appropriate application timing with the goal of reducing the pollution risk by runoff.
Fil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná; Argentina
Fil: Demonte, Luisina Delma. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Investigación y Análisis de Residuos y Contaminantes Químicos; Argentina
Fil: Cislaghi, Andrea. Universidad Nacional de Entre Ríos. Facultad de Ciencias Agropecuarias; Argentina
Fil: Gabioud, Emmanuel Adrian. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná; Argentina
Fil: Oszust, José Daniel. Universidad Nacional de Entre Ríos. Facultad de Ciencias Agropecuarias; Argentina
Fil: Wilson, Marcelo German. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná; Argentina. Universidad Nacional de Entre Ríos. Facultad de Ciencias Agropecuarias; Argentina
Fil: Michlig, Nicolas. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Investigación y Análisis de Residuos y Contaminantes Químicos; Argentina
Fil: Beldoménico, Horacio Ramón. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Investigación y Análisis de Residuos y Contaminantes Químicos; Argentina
Fil: Repetti, María Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Investigación y Análisis de Residuos y Contaminantes Químicos; Argentina
Fuente
Journal of agricultural and food chemistry 63 (18) : 4444-4448. (2015)
Materia
Glifosato
Escorrentia
Abonos Fosfatados
Phosphate Fertilizers
Runoff
Glyphosate
Fertilización Fosfatada
Nivel de accesibilidad
acceso restringido
Condiciones de uso
Repositorio
INTA Digital (INTA)
Institución
Instituto Nacional de Tecnología Agropecuaria
OAI Identificador
oai:localhost:20.500.12123/2112
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oai_identifier_str oai:localhost:20.500.12123/2112
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spelling Glyphosate loss by runoff and its relationship with phosphorus fertilizationSasal, Maria CarolinaDemonte, Luisina DelmaCislaghi, AndreaGabioud, Emmanuel AdrianOszust, José DanielWilson, Marcelo GermanMichlig, NicolasBeldoménico, Horacio RamónRepetti, María RosaGlifosatoEscorrentiaAbonos FosfatadosPhosphate FertilizersRunoffGlyphosateFertilización FosfatadaThe aim of this study was to evaluate the relationship between glyphosate and phosphate fertilizer application and their contribution to surface water runoff contamination. The study was performed in Aquic Argiudoll soil (Tezanos Pinto series). Four treatments were assessed on three dates of rainfall simulation after fertilizer and herbicide application. The soluble phosphorus in runoff water was determined by a colorimetric method. For the determination of glyphosate and aminomethylphosphonic acid (AMPA), a method based on fluorenylmethyloxycarbonyl (FMOC) group derivatization, solid phase extraction (SPE) purification, and ultrahigh-performance liquid chromatography−tandem mass spectrometry (UHPLCMS/MS) was employed. The application of phosphorus fertilizer resulted in an increased loss of glyphosate by runoff after 1 day of application. These results suggest the need for further study to understand the interactions and to determine appropriate application timing with the goal of reducing the pollution risk by runoff.Fil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná; ArgentinaFil: Demonte, Luisina Delma. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Investigación y Análisis de Residuos y Contaminantes Químicos; ArgentinaFil: Cislaghi, Andrea. Universidad Nacional de Entre Ríos. Facultad de Ciencias Agropecuarias; ArgentinaFil: Gabioud, Emmanuel Adrian. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná; ArgentinaFil: Oszust, José Daniel. Universidad Nacional de Entre Ríos. Facultad de Ciencias Agropecuarias; ArgentinaFil: Wilson, Marcelo German. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná; Argentina. Universidad Nacional de Entre Ríos. Facultad de Ciencias Agropecuarias; ArgentinaFil: Michlig, Nicolas. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Investigación y Análisis de Residuos y Contaminantes Químicos; ArgentinaFil: Beldoménico, Horacio Ramón. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Investigación y Análisis de Residuos y Contaminantes Químicos; ArgentinaFil: Repetti, María Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Investigación y Análisis de Residuos y Contaminantes Químicos; Argentina2018-03-23T17:43:14Z2018-03-23T17:43:14Z2015-02-23info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12123/2112https://pubs.acs.org/doi/10.1021/jf505533r0021-85611520-5118 (Online)Journal of agricultural and food chemistry 63 (18) : 4444-4448. (2015)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repograntAgreement/INTA/PNNAT/1128041/AR./Gestion de sistemas agropecuarios y agroindustriales para reducir la contaminación.info:eu-repograntAgreement/INTA/PNNAT/1128043/AR./Los agroquímicos como fuente de contaminación difusa en agroecosistemas.info:eu-repo/semantics/restrictedAccess2025-09-29T13:44:16Zoai:localhost:20.500.12123/2112instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-29 13:44:16.734INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse
dc.title.none.fl_str_mv Glyphosate loss by runoff and its relationship with phosphorus fertilization
title Glyphosate loss by runoff and its relationship with phosphorus fertilization
spellingShingle Glyphosate loss by runoff and its relationship with phosphorus fertilization
Sasal, Maria Carolina
Glifosato
Escorrentia
Abonos Fosfatados
Phosphate Fertilizers
Runoff
Glyphosate
Fertilización Fosfatada
title_short Glyphosate loss by runoff and its relationship with phosphorus fertilization
title_full Glyphosate loss by runoff and its relationship with phosphorus fertilization
title_fullStr Glyphosate loss by runoff and its relationship with phosphorus fertilization
title_full_unstemmed Glyphosate loss by runoff and its relationship with phosphorus fertilization
title_sort Glyphosate loss by runoff and its relationship with phosphorus fertilization
dc.creator.none.fl_str_mv Sasal, Maria Carolina
Demonte, Luisina Delma
Cislaghi, Andrea
Gabioud, Emmanuel Adrian
Oszust, José Daniel
Wilson, Marcelo German
Michlig, Nicolas
Beldoménico, Horacio Ramón
Repetti, María Rosa
author Sasal, Maria Carolina
author_facet Sasal, Maria Carolina
Demonte, Luisina Delma
Cislaghi, Andrea
Gabioud, Emmanuel Adrian
Oszust, José Daniel
Wilson, Marcelo German
Michlig, Nicolas
Beldoménico, Horacio Ramón
Repetti, María Rosa
author_role author
author2 Demonte, Luisina Delma
Cislaghi, Andrea
Gabioud, Emmanuel Adrian
Oszust, José Daniel
Wilson, Marcelo German
Michlig, Nicolas
Beldoménico, Horacio Ramón
Repetti, María Rosa
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Glifosato
Escorrentia
Abonos Fosfatados
Phosphate Fertilizers
Runoff
Glyphosate
Fertilización Fosfatada
topic Glifosato
Escorrentia
Abonos Fosfatados
Phosphate Fertilizers
Runoff
Glyphosate
Fertilización Fosfatada
dc.description.none.fl_txt_mv The aim of this study was to evaluate the relationship between glyphosate and phosphate fertilizer application and their contribution to surface water runoff contamination. The study was performed in Aquic Argiudoll soil (Tezanos Pinto series). Four treatments were assessed on three dates of rainfall simulation after fertilizer and herbicide application. The soluble phosphorus in runoff water was determined by a colorimetric method. For the determination of glyphosate and aminomethylphosphonic acid (AMPA), a method based on fluorenylmethyloxycarbonyl (FMOC) group derivatization, solid phase extraction (SPE) purification, and ultrahigh-performance liquid chromatography−tandem mass spectrometry (UHPLCMS/MS) was employed. The application of phosphorus fertilizer resulted in an increased loss of glyphosate by runoff after 1 day of application. These results suggest the need for further study to understand the interactions and to determine appropriate application timing with the goal of reducing the pollution risk by runoff.
Fil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná; Argentina
Fil: Demonte, Luisina Delma. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Investigación y Análisis de Residuos y Contaminantes Químicos; Argentina
Fil: Cislaghi, Andrea. Universidad Nacional de Entre Ríos. Facultad de Ciencias Agropecuarias; Argentina
Fil: Gabioud, Emmanuel Adrian. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná; Argentina
Fil: Oszust, José Daniel. Universidad Nacional de Entre Ríos. Facultad de Ciencias Agropecuarias; Argentina
Fil: Wilson, Marcelo German. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Paraná; Argentina. Universidad Nacional de Entre Ríos. Facultad de Ciencias Agropecuarias; Argentina
Fil: Michlig, Nicolas. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Investigación y Análisis de Residuos y Contaminantes Químicos; Argentina
Fil: Beldoménico, Horacio Ramón. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Investigación y Análisis de Residuos y Contaminantes Químicos; Argentina
Fil: Repetti, María Rosa. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Programa de Investigación y Análisis de Residuos y Contaminantes Químicos; Argentina
description The aim of this study was to evaluate the relationship between glyphosate and phosphate fertilizer application and their contribution to surface water runoff contamination. The study was performed in Aquic Argiudoll soil (Tezanos Pinto series). Four treatments were assessed on three dates of rainfall simulation after fertilizer and herbicide application. The soluble phosphorus in runoff water was determined by a colorimetric method. For the determination of glyphosate and aminomethylphosphonic acid (AMPA), a method based on fluorenylmethyloxycarbonyl (FMOC) group derivatization, solid phase extraction (SPE) purification, and ultrahigh-performance liquid chromatography−tandem mass spectrometry (UHPLCMS/MS) was employed. The application of phosphorus fertilizer resulted in an increased loss of glyphosate by runoff after 1 day of application. These results suggest the need for further study to understand the interactions and to determine appropriate application timing with the goal of reducing the pollution risk by runoff.
publishDate 2015
dc.date.none.fl_str_mv 2015-02-23
2018-03-23T17:43:14Z
2018-03-23T17:43:14Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12123/2112
https://pubs.acs.org/doi/10.1021/jf505533r
0021-8561
1520-5118 (Online)
url http://hdl.handle.net/20.500.12123/2112
https://pubs.acs.org/doi/10.1021/jf505533r
identifier_str_mv 0021-8561
1520-5118 (Online)
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repograntAgreement/INTA/PNNAT/1128041/AR./Gestion de sistemas agropecuarios y agroindustriales para reducir la contaminación.
info:eu-repograntAgreement/INTA/PNNAT/1128043/AR./Los agroquímicos como fuente de contaminación difusa en agroecosistemas.
dc.rights.none.fl_str_mv info:eu-repo/semantics/restrictedAccess
eu_rights_str_mv restrictedAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv Journal of agricultural and food chemistry 63 (18) : 4444-4448. (2015)
reponame:INTA Digital (INTA)
instname:Instituto Nacional de Tecnología Agropecuaria
reponame_str INTA Digital (INTA)
collection INTA Digital (INTA)
instname_str Instituto Nacional de Tecnología Agropecuaria
repository.name.fl_str_mv INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria
repository.mail.fl_str_mv tripaldi.nicolas@inta.gob.ar
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score 12.559606

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