A New Methodological Approach to Study the Interaction of Humic Acids, Minerals and Polyvalent Cations in Soil

Autores
Kloster, Nanci Soledad; Puccia, Virginia; Fernandez, Romina; Avena, Marcelo; Tan, Wenfeng; Wang, Mingxia
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión aceptada
Descripción
A new methodological approach of humic acid (HA) extraction is applied to study soil samples with contrasting management regimes: natural vegetation (NV) and agricultural (A). This innovative approach involves a modification of the Swift’s method, wherein several steps HCl/HF are replaced by a single-step HCl/HF. This modification enabled us to investigate the ability of HA to retain inorganic constituents. The carbon content was significantly higher in soils under NV (19.8–27.3 g C kg−1) than under A (11.2– 13.4 g C kg−1). The same pattern was observed for the HA content. The new methodology revealed that HA from NV soils had a much higher capacity to retain inorganics (ash contents in HA from 12.3–28.3%) than in A soils (ashcontent in HA from 1.6–2.6%). Similar results were found for Ca+Al+Fe contents in the HA (3.7–2.5 meq g−1 in HA from NV soils; 2.2–.9 meq g−1 in HA from A soils). Some differences were observed in IR spectra, mainly an intense band at around 1050 cm−1 of HA from NV that reflects the high ash content of the HA and its capacity of retaining inorganic material. Ca binding isotherms of HA also showed that the HA differed significantly in their ability to retain inorganic components when extracted. Humic acid from NV was more efficient in retaining metal ions and minerals than HA from A soils. All results point to a better contact between organic and inorganic matter in NV soils, and this contact contributes to the stabilization of organic matter.
EEA Anguil, INTA
Fil: Kloster, Nanci. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Anguil; Argentina
Fil: Fernandez, Romina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Anguil; Argentina. Universidad Nacional de La Pampa. Facultad de Agronomía; Argentina
Fil: Puccia, Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina
Fil: Avena, Marcelo Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina
Fil: Tan, Wenfeng. Huazhong Agricultural University. College of Resources and Environment. State Environmental Protection Key Laboratory of Soil Health and Green Remediation; China
Fil: Wang, Mingxia. Huazhong Agricultural University. College of Resources and Environment. State Environmental Protection Key Laboratory of Soil Health and Green Remediation; China
Fuente
Communications in Soil Science and Plant Analysis : 1-13 (2024)
Materia
Almacenamiento
Iones
Suelo
Quimica del Suelo
Storage
Ions
Soil
Soil Chemistry
Ácidos Húmicos
Nivel de accesibilidad
acceso restringido
Condiciones de uso
http://creativecommons.org/licenses/by-nc-sa/4.0/
Repositorio
INTA Digital (INTA)
Institución
Instituto Nacional de Tecnología Agropecuaria
OAI Identificador
oai:localhost:20.500.12123/17231
Acceder
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oai_identifier_str oai:localhost:20.500.12123/17231
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network_name_str INTA Digital (INTA)
spelling A New Methodological Approach to Study the Interaction of Humic Acids, Minerals and Polyvalent Cations in SoilKloster, Nanci SoledadPuccia, VirginiaFernandez, RominaAvena, MarceloTan, WenfengWang, MingxiaAlmacenamientoIonesSueloQuimica del SueloStorageIonsSoilSoil ChemistryÁcidos HúmicosA new methodological approach of humic acid (HA) extraction is applied to study soil samples with contrasting management regimes: natural vegetation (NV) and agricultural (A). This innovative approach involves a modification of the Swift’s method, wherein several steps HCl/HF are replaced by a single-step HCl/HF. This modification enabled us to investigate the ability of HA to retain inorganic constituents. The carbon content was significantly higher in soils under NV (19.8–27.3 g C kg−1) than under A (11.2– 13.4 g C kg−1). The same pattern was observed for the HA content. The new methodology revealed that HA from NV soils had a much higher capacity to retain inorganics (ash contents in HA from 12.3–28.3%) than in A soils (ashcontent in HA from 1.6–2.6%). Similar results were found for Ca+Al+Fe contents in the HA (3.7–2.5 meq g−1 in HA from NV soils; 2.2–.9 meq g−1 in HA from A soils). Some differences were observed in IR spectra, mainly an intense band at around 1050 cm−1 of HA from NV that reflects the high ash content of the HA and its capacity of retaining inorganic material. Ca binding isotherms of HA also showed that the HA differed significantly in their ability to retain inorganic components when extracted. Humic acid from NV was more efficient in retaining metal ions and minerals than HA from A soils. All results point to a better contact between organic and inorganic matter in NV soils, and this contact contributes to the stabilization of organic matter.EEA Anguil, INTAFil: Kloster, Nanci. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Anguil; ArgentinaFil: Fernandez, Romina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Anguil; Argentina. Universidad Nacional de La Pampa. Facultad de Agronomía; ArgentinaFil: Puccia, Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; ArgentinaFil: Avena, Marcelo Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; ArgentinaFil: Tan, Wenfeng. Huazhong Agricultural University. College of Resources and Environment. State Environmental Protection Key Laboratory of Soil Health and Green Remediation; ChinaFil: Wang, Mingxia. Huazhong Agricultural University. College of Resources and Environment. State Environmental Protection Key Laboratory of Soil Health and Green Remediation; ChinaTaylor & Francis2024-03-27T10:55:26Z2024-03-27T10:55:26Z2024-02-20info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12123/17231https://www.tandfonline.com/doi/10.1080/00103624.2024.23230791532-2416https://doi.org/10.1080/00103624.2024.2323079Communications in Soil Science and Plant Analysis : 1-13 (2024)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología Agropecuariaenginfo:eu-repo/semantics/restrictedAccesshttp://creativecommons.org/licenses/by-nc-sa/4.0/Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)2025-09-04T09:50:16Zoai:localhost:20.500.12123/17231instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-04 09:50:16.36INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse
dc.title.none.fl_str_mv A New Methodological Approach to Study the Interaction of Humic Acids, Minerals and Polyvalent Cations in Soil
title A New Methodological Approach to Study the Interaction of Humic Acids, Minerals and Polyvalent Cations in Soil
spellingShingle A New Methodological Approach to Study the Interaction of Humic Acids, Minerals and Polyvalent Cations in Soil
Kloster, Nanci Soledad
Almacenamiento
Iones
Suelo
Quimica del Suelo
Storage
Ions
Soil
Soil Chemistry
Ácidos Húmicos
title_short A New Methodological Approach to Study the Interaction of Humic Acids, Minerals and Polyvalent Cations in Soil
title_full A New Methodological Approach to Study the Interaction of Humic Acids, Minerals and Polyvalent Cations in Soil
title_fullStr A New Methodological Approach to Study the Interaction of Humic Acids, Minerals and Polyvalent Cations in Soil
title_full_unstemmed A New Methodological Approach to Study the Interaction of Humic Acids, Minerals and Polyvalent Cations in Soil
title_sort A New Methodological Approach to Study the Interaction of Humic Acids, Minerals and Polyvalent Cations in Soil
dc.creator.none.fl_str_mv Kloster, Nanci Soledad
Puccia, Virginia
Fernandez, Romina
Avena, Marcelo
Tan, Wenfeng
Wang, Mingxia
author Kloster, Nanci Soledad
author_facet Kloster, Nanci Soledad
Puccia, Virginia
Fernandez, Romina
Avena, Marcelo
Tan, Wenfeng
Wang, Mingxia
author_role author
author2 Puccia, Virginia
Fernandez, Romina
Avena, Marcelo
Tan, Wenfeng
Wang, Mingxia
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Almacenamiento
Iones
Suelo
Quimica del Suelo
Storage
Ions
Soil
Soil Chemistry
Ácidos Húmicos
topic Almacenamiento
Iones
Suelo
Quimica del Suelo
Storage
Ions
Soil
Soil Chemistry
Ácidos Húmicos
dc.description.none.fl_txt_mv A new methodological approach of humic acid (HA) extraction is applied to study soil samples with contrasting management regimes: natural vegetation (NV) and agricultural (A). This innovative approach involves a modification of the Swift’s method, wherein several steps HCl/HF are replaced by a single-step HCl/HF. This modification enabled us to investigate the ability of HA to retain inorganic constituents. The carbon content was significantly higher in soils under NV (19.8–27.3 g C kg−1) than under A (11.2– 13.4 g C kg−1). The same pattern was observed for the HA content. The new methodology revealed that HA from NV soils had a much higher capacity to retain inorganics (ash contents in HA from 12.3–28.3%) than in A soils (ashcontent in HA from 1.6–2.6%). Similar results were found for Ca+Al+Fe contents in the HA (3.7–2.5 meq g−1 in HA from NV soils; 2.2–.9 meq g−1 in HA from A soils). Some differences were observed in IR spectra, mainly an intense band at around 1050 cm−1 of HA from NV that reflects the high ash content of the HA and its capacity of retaining inorganic material. Ca binding isotherms of HA also showed that the HA differed significantly in their ability to retain inorganic components when extracted. Humic acid from NV was more efficient in retaining metal ions and minerals than HA from A soils. All results point to a better contact between organic and inorganic matter in NV soils, and this contact contributes to the stabilization of organic matter.
EEA Anguil, INTA
Fil: Kloster, Nanci. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Anguil; Argentina
Fil: Fernandez, Romina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Anguil; Argentina. Universidad Nacional de La Pampa. Facultad de Agronomía; Argentina
Fil: Puccia, Virginia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina
Fil: Avena, Marcelo Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina
Fil: Tan, Wenfeng. Huazhong Agricultural University. College of Resources and Environment. State Environmental Protection Key Laboratory of Soil Health and Green Remediation; China
Fil: Wang, Mingxia. Huazhong Agricultural University. College of Resources and Environment. State Environmental Protection Key Laboratory of Soil Health and Green Remediation; China
description A new methodological approach of humic acid (HA) extraction is applied to study soil samples with contrasting management regimes: natural vegetation (NV) and agricultural (A). This innovative approach involves a modification of the Swift’s method, wherein several steps HCl/HF are replaced by a single-step HCl/HF. This modification enabled us to investigate the ability of HA to retain inorganic constituents. The carbon content was significantly higher in soils under NV (19.8–27.3 g C kg−1) than under A (11.2– 13.4 g C kg−1). The same pattern was observed for the HA content. The new methodology revealed that HA from NV soils had a much higher capacity to retain inorganics (ash contents in HA from 12.3–28.3%) than in A soils (ashcontent in HA from 1.6–2.6%). Similar results were found for Ca+Al+Fe contents in the HA (3.7–2.5 meq g−1 in HA from NV soils; 2.2–.9 meq g−1 in HA from A soils). Some differences were observed in IR spectra, mainly an intense band at around 1050 cm−1 of HA from NV that reflects the high ash content of the HA and its capacity of retaining inorganic material. Ca binding isotherms of HA also showed that the HA differed significantly in their ability to retain inorganic components when extracted. Humic acid from NV was more efficient in retaining metal ions and minerals than HA from A soils. All results point to a better contact between organic and inorganic matter in NV soils, and this contact contributes to the stabilization of organic matter.
publishDate 2024
dc.date.none.fl_str_mv 2024-03-27T10:55:26Z
2024-03-27T10:55:26Z
2024-02-20
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12123/17231
https://www.tandfonline.com/doi/10.1080/00103624.2024.2323079
1532-2416
https://doi.org/10.1080/00103624.2024.2323079
url http://hdl.handle.net/20.500.12123/17231
https://www.tandfonline.com/doi/10.1080/00103624.2024.2323079
https://doi.org/10.1080/00103624.2024.2323079
identifier_str_mv 1532-2416
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/restrictedAccess
http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
eu_rights_str_mv restrictedAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-sa/4.0/
Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis
publisher.none.fl_str_mv Taylor & Francis
dc.source.none.fl_str_mv Communications in Soil Science and Plant Analysis : 1-13 (2024)
reponame:INTA Digital (INTA)
instname:Instituto Nacional de Tecnología Agropecuaria
reponame_str INTA Digital (INTA)
collection INTA Digital (INTA)
instname_str Instituto Nacional de Tecnología Agropecuaria
repository.name.fl_str_mv INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria
repository.mail.fl_str_mv tripaldi.nicolas@inta.gob.ar
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score 12.623145

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