Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function

Autores
De Geronimo, Eduardo; Aparicio, Virginia Carolina; Costa, Jose Luis
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Argentine agricultural production is fundamentally based on technological package that combines direct seeding and glyphosate with transgenic crops (soybean, maize and cotton), which makes glyphosate the most widely employed herbicide in the country. Glyphosate is strongly sorbed to soil in a reversible process that regulates the half-life and mobility of the herbicide, with the resulting risk of contaminating surface and groundwater courses. However, this behavior may vary depending on the characteristics of the soil on which it is applied. Sorption coefficients are thus the most sensitive parameters in models used for environmental risk assessment. The aim of this work was to study the affinity of glyphosate to 12 different soils of Argentina and create a model to estimate the glyphosate Freundlich sorption coefficient (Kf) from easily measurable soil properties. Batch equilibration adsorption data are shown by Freundlich adsorption isotherms. Principal component analysis and multiple linear regressions were used to correlate the effects of soil properties on glyphosate adsorption coefficients. Results indicate that pH and clay contents were the major soil parameters governing glyphosate adsorption in soils. The Freundlich (Kf) pedotransfer function obtained by stepwise regression analysis has 97.9% of the variation in glyphosate sorption coefficients that could be attributed to the variation of the soil clay contents, pH, PBray and Alin.
EEA Balcarce
Fil: De Geronimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fuente
Geoderma 322 : 140-148. (15 July 2018)
Materia
Fertilidad del suelo
Glifosato
Sorción del Suelo
Soil Sorption
Soil Fertility
Glyphosate
Función de Pedotransferencia
Nivel de accesibilidad
acceso restringido
Condiciones de uso
Repositorio
INTA Digital (INTA)
Institución
Instituto Nacional de Tecnología Agropecuaria
OAI Identificador
oai:localhost:20.500.12123/2008
Acceder
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oai_identifier_str oai:localhost:20.500.12123/2008
network_acronym_str INTADig
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network_name_str INTA Digital (INTA)
spelling Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer functionDe Geronimo, EduardoAparicio, Virginia CarolinaCosta, Jose LuisFertilidad del sueloGlifosatoSorción del SueloSoil SorptionSoil FertilityGlyphosateFunción de PedotransferenciaArgentine agricultural production is fundamentally based on technological package that combines direct seeding and glyphosate with transgenic crops (soybean, maize and cotton), which makes glyphosate the most widely employed herbicide in the country. Glyphosate is strongly sorbed to soil in a reversible process that regulates the half-life and mobility of the herbicide, with the resulting risk of contaminating surface and groundwater courses. However, this behavior may vary depending on the characteristics of the soil on which it is applied. Sorption coefficients are thus the most sensitive parameters in models used for environmental risk assessment. The aim of this work was to study the affinity of glyphosate to 12 different soils of Argentina and create a model to estimate the glyphosate Freundlich sorption coefficient (Kf) from easily measurable soil properties. Batch equilibration adsorption data are shown by Freundlich adsorption isotherms. Principal component analysis and multiple linear regressions were used to correlate the effects of soil properties on glyphosate adsorption coefficients. Results indicate that pH and clay contents were the major soil parameters governing glyphosate adsorption in soils. The Freundlich (Kf) pedotransfer function obtained by stepwise regression analysis has 97.9% of the variation in glyphosate sorption coefficients that could be attributed to the variation of the soil clay contents, pH, PBray and Alin.EEA BalcarceFil: De Geronimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaFil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaFil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaElsevier2018-03-09T16:49:00Z2018-03-09T16:49:00Z2018info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12123/2008https://www.sciencedirect.com/science/article/pii/S0016706117316002https://doi.org/10.1016/j.geoderma.2018.02.037Geoderma 322 : 140-148. (15 July 2018)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología AgropecuariaengArgentina (nation)info:eu-repo/semantics/restrictedAccess2025-10-23T11:16:28Zoai:localhost:20.500.12123/2008instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-10-23 11:16:28.514INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse
dc.title.none.fl_str_mv Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function
title Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function
spellingShingle Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function
De Geronimo, Eduardo
Fertilidad del suelo
Glifosato
Sorción del Suelo
Soil Sorption
Soil Fertility
Glyphosate
Función de Pedotransferencia
title_short Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function
title_full Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function
title_fullStr Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function
title_full_unstemmed Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function
title_sort Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function
dc.creator.none.fl_str_mv De Geronimo, Eduardo
Aparicio, Virginia Carolina
Costa, Jose Luis
author De Geronimo, Eduardo
author_facet De Geronimo, Eduardo
Aparicio, Virginia Carolina
Costa, Jose Luis
author_role author
author2 Aparicio, Virginia Carolina
Costa, Jose Luis
author2_role author
author
dc.subject.none.fl_str_mv Fertilidad del suelo
Glifosato
Sorción del Suelo
Soil Sorption
Soil Fertility
Glyphosate
Función de Pedotransferencia
topic Fertilidad del suelo
Glifosato
Sorción del Suelo
Soil Sorption
Soil Fertility
Glyphosate
Función de Pedotransferencia
dc.description.none.fl_txt_mv Argentine agricultural production is fundamentally based on technological package that combines direct seeding and glyphosate with transgenic crops (soybean, maize and cotton), which makes glyphosate the most widely employed herbicide in the country. Glyphosate is strongly sorbed to soil in a reversible process that regulates the half-life and mobility of the herbicide, with the resulting risk of contaminating surface and groundwater courses. However, this behavior may vary depending on the characteristics of the soil on which it is applied. Sorption coefficients are thus the most sensitive parameters in models used for environmental risk assessment. The aim of this work was to study the affinity of glyphosate to 12 different soils of Argentina and create a model to estimate the glyphosate Freundlich sorption coefficient (Kf) from easily measurable soil properties. Batch equilibration adsorption data are shown by Freundlich adsorption isotherms. Principal component analysis and multiple linear regressions were used to correlate the effects of soil properties on glyphosate adsorption coefficients. Results indicate that pH and clay contents were the major soil parameters governing glyphosate adsorption in soils. The Freundlich (Kf) pedotransfer function obtained by stepwise regression analysis has 97.9% of the variation in glyphosate sorption coefficients that could be attributed to the variation of the soil clay contents, pH, PBray and Alin.
EEA Balcarce
Fil: De Geronimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
description Argentine agricultural production is fundamentally based on technological package that combines direct seeding and glyphosate with transgenic crops (soybean, maize and cotton), which makes glyphosate the most widely employed herbicide in the country. Glyphosate is strongly sorbed to soil in a reversible process that regulates the half-life and mobility of the herbicide, with the resulting risk of contaminating surface and groundwater courses. However, this behavior may vary depending on the characteristics of the soil on which it is applied. Sorption coefficients are thus the most sensitive parameters in models used for environmental risk assessment. The aim of this work was to study the affinity of glyphosate to 12 different soils of Argentina and create a model to estimate the glyphosate Freundlich sorption coefficient (Kf) from easily measurable soil properties. Batch equilibration adsorption data are shown by Freundlich adsorption isotherms. Principal component analysis and multiple linear regressions were used to correlate the effects of soil properties on glyphosate adsorption coefficients. Results indicate that pH and clay contents were the major soil parameters governing glyphosate adsorption in soils. The Freundlich (Kf) pedotransfer function obtained by stepwise regression analysis has 97.9% of the variation in glyphosate sorption coefficients that could be attributed to the variation of the soil clay contents, pH, PBray and Alin.
publishDate 2018
dc.date.none.fl_str_mv 2018-03-09T16:49:00Z
2018-03-09T16:49:00Z
2018
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12123/2008
https://www.sciencedirect.com/science/article/pii/S0016706117316002
https://doi.org/10.1016/j.geoderma.2018.02.037
url http://hdl.handle.net/20.500.12123/2008
https://www.sciencedirect.com/science/article/pii/S0016706117316002
https://doi.org/10.1016/j.geoderma.2018.02.037
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/restrictedAccess
eu_rights_str_mv restrictedAccess
dc.format.none.fl_str_mv application/pdf
dc.coverage.none.fl_str_mv Argentina (nation)
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv Geoderma 322 : 140-148. (15 July 2018)
reponame:INTA Digital (INTA)
instname:Instituto Nacional de Tecnología Agropecuaria
reponame_str INTA Digital (INTA)
collection INTA Digital (INTA)
instname_str Instituto Nacional de Tecnología Agropecuaria
repository.name.fl_str_mv INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria
repository.mail.fl_str_mv tripaldi.nicolas@inta.gob.ar
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score 12.982451

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