Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function
- Autores
- De Geronimo, Eduardo; Aparicio, Virginia Carolina; Costa, Jose Luis
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Argentine agricultural production is fundamentally based on technological package that combines direct seeding and glyphosate with transgenic crops (soybean, maize and cotton), which makes glyphosate the most widely employed herbicide in the country. Glyphosate is strongly sorbed to soil in a reversible process that regulates the half-life and mobility of the herbicide, with the resulting risk of contaminating surface and groundwater courses. However, this behavior may vary depending on the characteristics of the soil on which it is applied. Sorption coefficients are thus the most sensitive parameters in models used for environmental risk assessment. The aim of this work was to study the affinity of glyphosate to 12 different soils of Argentina and create a model to estimate the glyphosate Freundlich sorption coefficient (Kf) from easily measurable soil properties. Batch equilibration adsorption data are shown by Freundlich adsorption isotherms. Principal component analysis and multiple linear regressions were used to correlate the effects of soil properties on glyphosate adsorption coefficients. Results indicate that pH and clay contents were the major soil parameters governing glyphosate adsorption in soils. The Freundlich (Kf) pedotransfer function obtained by stepwise regression analysis has 97.9% of the variation in glyphosate sorption coefficients that could be attributed to the variation of the soil clay contents, pH, PBray and Alin.
EEA Balcarce
Fil: De Geronimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina
Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina - Fuente
- Geoderma 322 : 140-148. (15 July 2018)
- Materia
-
Fertilidad del suelo
Glifosato
Sorción del Suelo
Soil Sorption
Soil Fertility
Glyphosate
Función de Pedotransferencia - Nivel de accesibilidad
- acceso restringido
- Condiciones de uso
- Repositorio
- Institución
- Instituto Nacional de Tecnología Agropecuaria
- OAI Identificador
- oai:localhost:20.500.12123/2008
Ver los metadatos del registro completo
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Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer functionDe Geronimo, EduardoAparicio, Virginia CarolinaCosta, Jose LuisFertilidad del sueloGlifosatoSorción del SueloSoil SorptionSoil FertilityGlyphosateFunción de PedotransferenciaArgentine agricultural production is fundamentally based on technological package that combines direct seeding and glyphosate with transgenic crops (soybean, maize and cotton), which makes glyphosate the most widely employed herbicide in the country. Glyphosate is strongly sorbed to soil in a reversible process that regulates the half-life and mobility of the herbicide, with the resulting risk of contaminating surface and groundwater courses. However, this behavior may vary depending on the characteristics of the soil on which it is applied. Sorption coefficients are thus the most sensitive parameters in models used for environmental risk assessment. The aim of this work was to study the affinity of glyphosate to 12 different soils of Argentina and create a model to estimate the glyphosate Freundlich sorption coefficient (Kf) from easily measurable soil properties. Batch equilibration adsorption data are shown by Freundlich adsorption isotherms. Principal component analysis and multiple linear regressions were used to correlate the effects of soil properties on glyphosate adsorption coefficients. Results indicate that pH and clay contents were the major soil parameters governing glyphosate adsorption in soils. The Freundlich (Kf) pedotransfer function obtained by stepwise regression analysis has 97.9% of the variation in glyphosate sorption coefficients that could be attributed to the variation of the soil clay contents, pH, PBray and Alin.EEA BalcarceFil: De Geronimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaFil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaFil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; ArgentinaElsevier2018-03-09T16:49:00Z2018-03-09T16:49:00Z2018info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12123/2008https://www.sciencedirect.com/science/article/pii/S0016706117316002https://doi.org/10.1016/j.geoderma.2018.02.037Geoderma 322 : 140-148. (15 July 2018)reponame:INTA Digital (INTA)instname:Instituto Nacional de Tecnología AgropecuariaengArgentina (nation)info:eu-repo/semantics/restrictedAccess2025-09-29T13:44:15Zoai:localhost:20.500.12123/2008instacron:INTAInstitucionalhttp://repositorio.inta.gob.ar/Organismo científico-tecnológicoNo correspondehttp://repositorio.inta.gob.ar/oai/requesttripaldi.nicolas@inta.gob.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:l2025-09-29 13:44:15.899INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuariafalse |
dc.title.none.fl_str_mv |
Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function |
title |
Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function |
spellingShingle |
Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function De Geronimo, Eduardo Fertilidad del suelo Glifosato Sorción del Suelo Soil Sorption Soil Fertility Glyphosate Función de Pedotransferencia |
title_short |
Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function |
title_full |
Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function |
title_fullStr |
Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function |
title_full_unstemmed |
Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function |
title_sort |
Glyphosate sorption to soils of Argentina. Estimation of affinity coefficient by pedotransfer function |
dc.creator.none.fl_str_mv |
De Geronimo, Eduardo Aparicio, Virginia Carolina Costa, Jose Luis |
author |
De Geronimo, Eduardo |
author_facet |
De Geronimo, Eduardo Aparicio, Virginia Carolina Costa, Jose Luis |
author_role |
author |
author2 |
Aparicio, Virginia Carolina Costa, Jose Luis |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Fertilidad del suelo Glifosato Sorción del Suelo Soil Sorption Soil Fertility Glyphosate Función de Pedotransferencia |
topic |
Fertilidad del suelo Glifosato Sorción del Suelo Soil Sorption Soil Fertility Glyphosate Función de Pedotransferencia |
dc.description.none.fl_txt_mv |
Argentine agricultural production is fundamentally based on technological package that combines direct seeding and glyphosate with transgenic crops (soybean, maize and cotton), which makes glyphosate the most widely employed herbicide in the country. Glyphosate is strongly sorbed to soil in a reversible process that regulates the half-life and mobility of the herbicide, with the resulting risk of contaminating surface and groundwater courses. However, this behavior may vary depending on the characteristics of the soil on which it is applied. Sorption coefficients are thus the most sensitive parameters in models used for environmental risk assessment. The aim of this work was to study the affinity of glyphosate to 12 different soils of Argentina and create a model to estimate the glyphosate Freundlich sorption coefficient (Kf) from easily measurable soil properties. Batch equilibration adsorption data are shown by Freundlich adsorption isotherms. Principal component analysis and multiple linear regressions were used to correlate the effects of soil properties on glyphosate adsorption coefficients. Results indicate that pH and clay contents were the major soil parameters governing glyphosate adsorption in soils. The Freundlich (Kf) pedotransfer function obtained by stepwise regression analysis has 97.9% of the variation in glyphosate sorption coefficients that could be attributed to the variation of the soil clay contents, pH, PBray and Alin. EEA Balcarce Fil: De Geronimo, Eduardo. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina Fil: Aparicio, Virginia Carolina. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina Fil: Costa, José Luis. Instituto Nacional de Tecnología Agropecuaria (INTA). Estación Experimental Agropecuaria Balcarce; Argentina |
description |
Argentine agricultural production is fundamentally based on technological package that combines direct seeding and glyphosate with transgenic crops (soybean, maize and cotton), which makes glyphosate the most widely employed herbicide in the country. Glyphosate is strongly sorbed to soil in a reversible process that regulates the half-life and mobility of the herbicide, with the resulting risk of contaminating surface and groundwater courses. However, this behavior may vary depending on the characteristics of the soil on which it is applied. Sorption coefficients are thus the most sensitive parameters in models used for environmental risk assessment. The aim of this work was to study the affinity of glyphosate to 12 different soils of Argentina and create a model to estimate the glyphosate Freundlich sorption coefficient (Kf) from easily measurable soil properties. Batch equilibration adsorption data are shown by Freundlich adsorption isotherms. Principal component analysis and multiple linear regressions were used to correlate the effects of soil properties on glyphosate adsorption coefficients. Results indicate that pH and clay contents were the major soil parameters governing glyphosate adsorption in soils. The Freundlich (Kf) pedotransfer function obtained by stepwise regression analysis has 97.9% of the variation in glyphosate sorption coefficients that could be attributed to the variation of the soil clay contents, pH, PBray and Alin. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-03-09T16:49:00Z 2018-03-09T16:49:00Z 2018 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/20.500.12123/2008 https://www.sciencedirect.com/science/article/pii/S0016706117316002 https://doi.org/10.1016/j.geoderma.2018.02.037 |
url |
http://hdl.handle.net/20.500.12123/2008 https://www.sciencedirect.com/science/article/pii/S0016706117316002 https://doi.org/10.1016/j.geoderma.2018.02.037 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/restrictedAccess |
eu_rights_str_mv |
restrictedAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.coverage.none.fl_str_mv |
Argentina (nation) |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
Geoderma 322 : 140-148. (15 July 2018) reponame:INTA Digital (INTA) instname:Instituto Nacional de Tecnología Agropecuaria |
reponame_str |
INTA Digital (INTA) |
collection |
INTA Digital (INTA) |
instname_str |
Instituto Nacional de Tecnología Agropecuaria |
repository.name.fl_str_mv |
INTA Digital (INTA) - Instituto Nacional de Tecnología Agropecuaria |
repository.mail.fl_str_mv |
tripaldi.nicolas@inta.gob.ar |
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1844619120279027712 |
score |
12.559606 |