Glyphosate Loss by Runoff and Its Relationship with Phosphorus Fertilization

Autores
Sasal, Maria Carolina; Demonte, Luisina Delma; Cislaghi, Andrea; Gabioud, Emmanuel Adrián; Oszust, José Daniel; Wilson, Marcelo G.; Michlig, Nicolás; Beldomenico, Horacio Ramon; Repetti, María Rosa
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this study was to evaluate the relationship between glyphosate and phosphate fertilizer application and their contribution to surface water runoff contamination. The study was performed in Aquic Argiudoll soil (Tezanos Pinto series). Four treatments were assessed on three dates of rainfall simulation after fertilizer and herbicide application. The soluble phosphorus in runoff water was determined by a colorimetric method. For the determination of glyphosate and aminomethylphosphonic acid (AMPA), a method based on fluorenylmethyloxycarbonyl (FMOC) group derivatization, solid phase extraction (SPE) purification, and ultrahigh-performance liquid chromatography?tandem mass spectrometry (UHPLC-MS/MS) was employed. The application of phosphorus fertilizer resulted in an increased loss of glyphosate by runoff after 1 day of application. These results suggest the need for further study to understand the interactions and to determine appropriate application timing with the goal of reducing the pollution risk by runoff.
Fil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Demonte, Luisina Delma. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Cislaghi, Andrea. Universidad Nacional de Entre Ríos; Argentina
Fil: Gabioud, Emmanuel Adrián. Instituto Nacional de Tecnología Agropecuaria; Argentina
Fil: Oszust, José Daniel. Universidad Nacional de Entre Ríos; Argentina
Fil: Wilson, Marcelo G.. Instituto Nacional de Tecnología Agropecuaria; Argentina. Universidad Nacional de Entre Ríos; Argentina
Fil: Michlig, Nicolás. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Beldomenico, Horacio Ramon. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Repetti, María Rosa. Universidad Nacional del Litoral; Argentina
Materia
Glyphosate
Phosphorus Fertilization
Surface Runoff
Phosphorus-Glyfosate Interaction
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44671
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/44671
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Glyphosate Loss by Runoff and Its Relationship with Phosphorus FertilizationSasal, Maria CarolinaDemonte, Luisina DelmaCislaghi, AndreaGabioud, Emmanuel AdriánOszust, José DanielWilson, Marcelo G.Michlig, NicolásBeldomenico, Horacio RamonRepetti, María RosaGlyphosatePhosphorus FertilizationSurface RunoffPhosphorus-Glyfosate Interactionhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1The aim of this study was to evaluate the relationship between glyphosate and phosphate fertilizer application and their contribution to surface water runoff contamination. The study was performed in Aquic Argiudoll soil (Tezanos Pinto series). Four treatments were assessed on three dates of rainfall simulation after fertilizer and herbicide application. The soluble phosphorus in runoff water was determined by a colorimetric method. For the determination of glyphosate and aminomethylphosphonic acid (AMPA), a method based on fluorenylmethyloxycarbonyl (FMOC) group derivatization, solid phase extraction (SPE) purification, and ultrahigh-performance liquid chromatography?tandem mass spectrometry (UHPLC-MS/MS) was employed. The application of phosphorus fertilizer resulted in an increased loss of glyphosate by runoff after 1 day of application. These results suggest the need for further study to understand the interactions and to determine appropriate application timing with the goal of reducing the pollution risk by runoff.Fil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Demonte, Luisina Delma. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Cislaghi, Andrea. Universidad Nacional de Entre Ríos; ArgentinaFil: Gabioud, Emmanuel Adrián. Instituto Nacional de Tecnología Agropecuaria; ArgentinaFil: Oszust, José Daniel. Universidad Nacional de Entre Ríos; ArgentinaFil: Wilson, Marcelo G.. Instituto Nacional de Tecnología Agropecuaria; Argentina. Universidad Nacional de Entre Ríos; ArgentinaFil: Michlig, Nicolás. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Beldomenico, Horacio Ramon. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; ArgentinaFil: Repetti, María Rosa. Universidad Nacional del Litoral; ArgentinaAmerican Chemical Society2015-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44671Sasal, Maria Carolina; Demonte, Luisina Delma; Cislaghi, Andrea; Gabioud, Emmanuel Adrián; Oszust, José Daniel; et al.; Glyphosate Loss by Runoff and Its Relationship with Phosphorus Fertilization; American Chemical Society; Journal of Agricultural and Food Chemistry; 63; 18; 5-2015; 4444-44480021-8561CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/jf505533rinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jf505533rinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:09:58Zoai:ri.conicet.gov.ar:11336/44671instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:09:59.134CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Glyphosate Loss by Runoff and Its Relationship with Phosphorus Fertilization
title Glyphosate Loss by Runoff and Its Relationship with Phosphorus Fertilization
spellingShingle Glyphosate Loss by Runoff and Its Relationship with Phosphorus Fertilization
Sasal, Maria Carolina
Glyphosate
Phosphorus Fertilization
Surface Runoff
Phosphorus-Glyfosate Interaction
title_short Glyphosate Loss by Runoff and Its Relationship with Phosphorus Fertilization
title_full Glyphosate Loss by Runoff and Its Relationship with Phosphorus Fertilization
title_fullStr Glyphosate Loss by Runoff and Its Relationship with Phosphorus Fertilization
title_full_unstemmed Glyphosate Loss by Runoff and Its Relationship with Phosphorus Fertilization
title_sort Glyphosate Loss by Runoff and Its Relationship with Phosphorus Fertilization
dc.creator.none.fl_str_mv Sasal, Maria Carolina
Demonte, Luisina Delma
Cislaghi, Andrea
Gabioud, Emmanuel Adrián
Oszust, José Daniel
Wilson, Marcelo G.
Michlig, Nicolás
Beldomenico, Horacio Ramon
Repetti, María Rosa
author Sasal, Maria Carolina
author_facet Sasal, Maria Carolina
Demonte, Luisina Delma
Cislaghi, Andrea
Gabioud, Emmanuel Adrián
Oszust, José Daniel
Wilson, Marcelo G.
Michlig, Nicolás
Beldomenico, Horacio Ramon
Repetti, María Rosa
author_role author
author2 Demonte, Luisina Delma
Cislaghi, Andrea
Gabioud, Emmanuel Adrián
Oszust, José Daniel
Wilson, Marcelo G.
Michlig, Nicolás
Beldomenico, Horacio Ramon
Repetti, María Rosa
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Glyphosate
Phosphorus Fertilization
Surface Runoff
Phosphorus-Glyfosate Interaction
topic Glyphosate
Phosphorus Fertilization
Surface Runoff
Phosphorus-Glyfosate Interaction
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The aim of this study was to evaluate the relationship between glyphosate and phosphate fertilizer application and their contribution to surface water runoff contamination. The study was performed in Aquic Argiudoll soil (Tezanos Pinto series). Four treatments were assessed on three dates of rainfall simulation after fertilizer and herbicide application. The soluble phosphorus in runoff water was determined by a colorimetric method. For the determination of glyphosate and aminomethylphosphonic acid (AMPA), a method based on fluorenylmethyloxycarbonyl (FMOC) group derivatization, solid phase extraction (SPE) purification, and ultrahigh-performance liquid chromatography?tandem mass spectrometry (UHPLC-MS/MS) was employed. The application of phosphorus fertilizer resulted in an increased loss of glyphosate by runoff after 1 day of application. These results suggest the need for further study to understand the interactions and to determine appropriate application timing with the goal of reducing the pollution risk by runoff.
Fil: Sasal, Maria Carolina. Instituto Nacional de Tecnología Agropecuaria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Demonte, Luisina Delma. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Cislaghi, Andrea. Universidad Nacional de Entre Ríos; Argentina
Fil: Gabioud, Emmanuel Adrián. Instituto Nacional de Tecnología Agropecuaria; Argentina
Fil: Oszust, José Daniel. Universidad Nacional de Entre Ríos; Argentina
Fil: Wilson, Marcelo G.. Instituto Nacional de Tecnología Agropecuaria; Argentina. Universidad Nacional de Entre Ríos; Argentina
Fil: Michlig, Nicolás. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Beldomenico, Horacio Ramon. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina
Fil: Repetti, María Rosa. Universidad Nacional del Litoral; Argentina
description The aim of this study was to evaluate the relationship between glyphosate and phosphate fertilizer application and their contribution to surface water runoff contamination. The study was performed in Aquic Argiudoll soil (Tezanos Pinto series). Four treatments were assessed on three dates of rainfall simulation after fertilizer and herbicide application. The soluble phosphorus in runoff water was determined by a colorimetric method. For the determination of glyphosate and aminomethylphosphonic acid (AMPA), a method based on fluorenylmethyloxycarbonyl (FMOC) group derivatization, solid phase extraction (SPE) purification, and ultrahigh-performance liquid chromatography?tandem mass spectrometry (UHPLC-MS/MS) was employed. The application of phosphorus fertilizer resulted in an increased loss of glyphosate by runoff after 1 day of application. These results suggest the need for further study to understand the interactions and to determine appropriate application timing with the goal of reducing the pollution risk by runoff.
publishDate 2015
dc.date.none.fl_str_mv 2015-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44671
Sasal, Maria Carolina; Demonte, Luisina Delma; Cislaghi, Andrea; Gabioud, Emmanuel Adrián; Oszust, José Daniel; et al.; Glyphosate Loss by Runoff and Its Relationship with Phosphorus Fertilization; American Chemical Society; Journal of Agricultural and Food Chemistry; 63; 18; 5-2015; 4444-4448
0021-8561
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44671
identifier_str_mv Sasal, Maria Carolina; Demonte, Luisina Delma; Cislaghi, Andrea; Gabioud, Emmanuel Adrián; Oszust, José Daniel; et al.; Glyphosate Loss by Runoff and Its Relationship with Phosphorus Fertilization; American Chemical Society; Journal of Agricultural and Food Chemistry; 63; 18; 5-2015; 4444-4448
0021-8561
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/jf505533r
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/jf505533r
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613984405159936
score 13.070432

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