Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterization

Autores
Lopez, Carlos Alberto; Abia, Carmen; Rodrigues, Joao E.; Serrano Sánchez, Federico; Nemes, Norbert M.; Martínez, José L.; Fernandez Díaz, María T.; Biškup, Neven; Alvarez Galván, Consuelo; Carrascoso, Felix; Castellanos Gomez, Andres; Alonso, José A.
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Among the hybrid organic–inorganic perovskites MAPbX3 (MA: methyl-ammonium CH3–NH3+, X = halogen), the triiodide specimen (MAPbI3) is still the material of choice for solar energy applications. Although it is able to absorb light above its 1.6 eV bandgap, its poor stability in humid air atmosphere has been a major drawback for its use in solar cells. However, we discovered that this perovskite can be prepared by ball milling in a straightforward way, yielding specimens with a superior stability. This fact allowed us to take atomic-resolution STEM images for the first time, with sufficient quality to unveil microscopic aspects of this material. We demonstrated full Iodine content, which might be related to the enhanced stability, in a more compact PbI6 framework with reduced unit-cell volume. A structural investigation from neutron powder diffraction (NPD) data of an undeuterated specimen was essential to determine the configuration of the organic MA unit in the 100–298 K temperature range. A phase transition is identified, from the tetragonal structure observed at RT (space group I4/mcm) to an orthorhombic (space group Pnma) phase where the methyl-ammonium organic units are fully localized. Our NPD data reveal that the MA changes are gradual and start before reaching the phase transition. Optoelectronic measurements yield a photocurrent peak at an illumination wavelength of 820 nm, which is redshifted by 30 nm with respect to previously reported measurements on MAPbI3 perovskites synthesized by crystallization from organic solvents.
Fil: Lopez, Carlos Alberto. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Abia, Carmen. Instituto de Ciencia de Materiales de Madrid; España. Institut Laue Langevin; Francia
Fil: Rodrigues, Joao E.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Serrano Sánchez, Federico. Instituto de Ciencia de Materiales de Madrid; España
Fil: Nemes, Norbert M.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Martínez, José L.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Fernandez Díaz, María T.. Institut Laue Langevin; Francia
Fil: Biškup, Neven. Universidad Complutense de Madrid; España
Fil: Alvarez Galván, Consuelo. Consejo Superior de Investigaciones Científicas; España
Fil: Carrascoso, Felix. Instituto de Ciencia de Materiales de Madrid; España
Fil: Castellanos Gomez, Andres. Instituto de Ciencia de Materiales de Madrid; España
Fil: Alonso, José A.. Instituto de Ciencia de Materiales de Madrid; España
Materia
­CH3NH3PbI3 hybrid perovskite
Optoelectronic characterization
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/143836
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/143836
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterizationLopez, Carlos AlbertoAbia, CarmenRodrigues, Joao E.Serrano Sánchez, FedericoNemes, Norbert M.Martínez, José L.Fernandez Díaz, María T.Biškup, NevenAlvarez Galván, ConsueloCarrascoso, FelixCastellanos Gomez, AndresAlonso, José A.­CH3NH3PbI3 hybrid perovskiteOptoelectronic characterizationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Among the hybrid organic–inorganic perovskites MAPbX3 (MA: methyl-ammonium CH3–NH3+, X = halogen), the triiodide specimen (MAPbI3) is still the material of choice for solar energy applications. Although it is able to absorb light above its 1.6 eV bandgap, its poor stability in humid air atmosphere has been a major drawback for its use in solar cells. However, we discovered that this perovskite can be prepared by ball milling in a straightforward way, yielding specimens with a superior stability. This fact allowed us to take atomic-resolution STEM images for the first time, with sufficient quality to unveil microscopic aspects of this material. We demonstrated full Iodine content, which might be related to the enhanced stability, in a more compact PbI6 framework with reduced unit-cell volume. A structural investigation from neutron powder diffraction (NPD) data of an undeuterated specimen was essential to determine the configuration of the organic MA unit in the 100–298 K temperature range. A phase transition is identified, from the tetragonal structure observed at RT (space group I4/mcm) to an orthorhombic (space group Pnma) phase where the methyl-ammonium organic units are fully localized. Our NPD data reveal that the MA changes are gradual and start before reaching the phase transition. Optoelectronic measurements yield a photocurrent peak at an illumination wavelength of 820 nm, which is redshifted by 30 nm with respect to previously reported measurements on MAPbI3 perovskites synthesized by crystallization from organic solvents.Fil: Lopez, Carlos Alberto. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Abia, Carmen. Instituto de Ciencia de Materiales de Madrid; España. Institut Laue Langevin; FranciaFil: Rodrigues, Joao E.. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Serrano Sánchez, Federico. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Nemes, Norbert M.. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Martínez, José L.. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Fernandez Díaz, María T.. Institut Laue Langevin; FranciaFil: Biškup, Neven. Universidad Complutense de Madrid; EspañaFil: Alvarez Galván, Consuelo. Consejo Superior de Investigaciones Científicas; EspañaFil: Carrascoso, Felix. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Castellanos Gomez, Andres. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Alonso, José A.. Instituto de Ciencia de Materiales de Madrid; EspañaNature2020-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/143836Lopez, Carlos Alberto; Abia, Carmen; Rodrigues, Joao E.; Serrano Sánchez, Federico; Nemes, Norbert M.; et al.; Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterization; Nature; Scientific Reports; 10; 11228; 12-2020; 1-112045-2322CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.nature.com/articles/s41598-020-68085-0info:eu-repo/semantics/altIdentifier/doi/10.1038/s41598-020-68085-0info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:12:11Zoai:ri.conicet.gov.ar:11336/143836instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:12:11.942CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterization
title Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterization
spellingShingle Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterization
Lopez, Carlos Alberto
­CH3NH3PbI3 hybrid perovskite
Optoelectronic characterization
title_short Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterization
title_full Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterization
title_fullStr Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterization
title_full_unstemmed Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterization
title_sort Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterization
dc.creator.none.fl_str_mv Lopez, Carlos Alberto
Abia, Carmen
Rodrigues, Joao E.
Serrano Sánchez, Federico
Nemes, Norbert M.
Martínez, José L.
Fernandez Díaz, María T.
Biškup, Neven
Alvarez Galván, Consuelo
Carrascoso, Felix
Castellanos Gomez, Andres
Alonso, José A.
author Lopez, Carlos Alberto
author_facet Lopez, Carlos Alberto
Abia, Carmen
Rodrigues, Joao E.
Serrano Sánchez, Federico
Nemes, Norbert M.
Martínez, José L.
Fernandez Díaz, María T.
Biškup, Neven
Alvarez Galván, Consuelo
Carrascoso, Felix
Castellanos Gomez, Andres
Alonso, José A.
author_role author
author2 Abia, Carmen
Rodrigues, Joao E.
Serrano Sánchez, Federico
Nemes, Norbert M.
Martínez, José L.
Fernandez Díaz, María T.
Biškup, Neven
Alvarez Galván, Consuelo
Carrascoso, Felix
Castellanos Gomez, Andres
Alonso, José A.
author2_role author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv ­CH3NH3PbI3 hybrid perovskite
Optoelectronic characterization
topic ­CH3NH3PbI3 hybrid perovskite
Optoelectronic characterization
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Among the hybrid organic–inorganic perovskites MAPbX3 (MA: methyl-ammonium CH3–NH3+, X = halogen), the triiodide specimen (MAPbI3) is still the material of choice for solar energy applications. Although it is able to absorb light above its 1.6 eV bandgap, its poor stability in humid air atmosphere has been a major drawback for its use in solar cells. However, we discovered that this perovskite can be prepared by ball milling in a straightforward way, yielding specimens with a superior stability. This fact allowed us to take atomic-resolution STEM images for the first time, with sufficient quality to unveil microscopic aspects of this material. We demonstrated full Iodine content, which might be related to the enhanced stability, in a more compact PbI6 framework with reduced unit-cell volume. A structural investigation from neutron powder diffraction (NPD) data of an undeuterated specimen was essential to determine the configuration of the organic MA unit in the 100–298 K temperature range. A phase transition is identified, from the tetragonal structure observed at RT (space group I4/mcm) to an orthorhombic (space group Pnma) phase where the methyl-ammonium organic units are fully localized. Our NPD data reveal that the MA changes are gradual and start before reaching the phase transition. Optoelectronic measurements yield a photocurrent peak at an illumination wavelength of 820 nm, which is redshifted by 30 nm with respect to previously reported measurements on MAPbI3 perovskites synthesized by crystallization from organic solvents.
Fil: Lopez, Carlos Alberto. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Área Química General e Inorgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Abia, Carmen. Instituto de Ciencia de Materiales de Madrid; España. Institut Laue Langevin; Francia
Fil: Rodrigues, Joao E.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Serrano Sánchez, Federico. Instituto de Ciencia de Materiales de Madrid; España
Fil: Nemes, Norbert M.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Martínez, José L.. Instituto de Ciencia de Materiales de Madrid; España
Fil: Fernandez Díaz, María T.. Institut Laue Langevin; Francia
Fil: Biškup, Neven. Universidad Complutense de Madrid; España
Fil: Alvarez Galván, Consuelo. Consejo Superior de Investigaciones Científicas; España
Fil: Carrascoso, Felix. Instituto de Ciencia de Materiales de Madrid; España
Fil: Castellanos Gomez, Andres. Instituto de Ciencia de Materiales de Madrid; España
Fil: Alonso, José A.. Instituto de Ciencia de Materiales de Madrid; España
description Among the hybrid organic–inorganic perovskites MAPbX3 (MA: methyl-ammonium CH3–NH3+, X = halogen), the triiodide specimen (MAPbI3) is still the material of choice for solar energy applications. Although it is able to absorb light above its 1.6 eV bandgap, its poor stability in humid air atmosphere has been a major drawback for its use in solar cells. However, we discovered that this perovskite can be prepared by ball milling in a straightforward way, yielding specimens with a superior stability. This fact allowed us to take atomic-resolution STEM images for the first time, with sufficient quality to unveil microscopic aspects of this material. We demonstrated full Iodine content, which might be related to the enhanced stability, in a more compact PbI6 framework with reduced unit-cell volume. A structural investigation from neutron powder diffraction (NPD) data of an undeuterated specimen was essential to determine the configuration of the organic MA unit in the 100–298 K temperature range. A phase transition is identified, from the tetragonal structure observed at RT (space group I4/mcm) to an orthorhombic (space group Pnma) phase where the methyl-ammonium organic units are fully localized. Our NPD data reveal that the MA changes are gradual and start before reaching the phase transition. Optoelectronic measurements yield a photocurrent peak at an illumination wavelength of 820 nm, which is redshifted by 30 nm with respect to previously reported measurements on MAPbI3 perovskites synthesized by crystallization from organic solvents.
publishDate 2020
dc.date.none.fl_str_mv 2020-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/143836
Lopez, Carlos Alberto; Abia, Carmen; Rodrigues, Joao E.; Serrano Sánchez, Federico; Nemes, Norbert M.; et al.; Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterization; Nature; Scientific Reports; 10; 11228; 12-2020; 1-11
2045-2322
CONICET Digital
CONICET
url http://hdl.handle.net/11336/143836
identifier_str_mv Lopez, Carlos Alberto; Abia, Carmen; Rodrigues, Joao E.; Serrano Sánchez, Federico; Nemes, Norbert M.; et al.; Enhanced stability in CH3NH3PbI3 hybrid perovskite from mechano-chemical synthesis: structural, microstructural and optoelectronic characterization; Nature; Scientific Reports; 10; 11228; 12-2020; 1-11
2045-2322
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.nature.com/articles/s41598-020-68085-0
info:eu-repo/semantics/altIdentifier/doi/10.1038/s41598-020-68085-0
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Nature
publisher.none.fl_str_mv Nature
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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