One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hulls

Autores
Castagnino Schirmer, Malena; Bertoni, Fernando Ariel; Giordano, Enrique David Victor
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A novel quaternized microcrystalline cellulose (Q-MCC) was obtained through a one-pot synthesis using agro-industrial waste, specifically soybean hulls (SBH), as the starting material. This work focuses on discussing the synthesis, physicochemical characterization, and application of Q-MCC, particularly its potential use in the removal of industrial textile dyes. The material underwent various characterization techniques, including Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM), optical microscopy, thermogravimetric analysis/differential thermal analysis (TGA/DTA), and differential scanning calorimetry (DSC). Additionally, Kjeldahl analysis, swelling measurements, and determination of the pH at the zero-point charge (pHzpc) were performed. FTIR spectroscopy confirmed the presence of attached quaternary ammonium groups. SEM and XRD analysis of Q-MCC revealed that the material consisted of short fibers with an average length of 30.93 µm and exhibited an increased crystallinity index of 76.4 %, respectively. Moreover, the pH at the point of zero charge (pHpzc) indicated that the adsorbent displayed a cationic nature across the tested pH range. The modification of SBH led to enhanced water absorption, and excellent dye removal results were achieved using two types of dyes: Direct Black 22 (DB 22) and Reactive Orange 122 (RO 122). To further investigate the behavior of Q-MCC in the adsorption of DB 22 dye, various studies were conducted, including kinetic, adsorption, thermodynamic analyses, and Weber-Morris intraparticle diffusion analysis. The kinetics results demonstrated that more than 90 % of the dye was adsorbed within just one minute of contact and were better represented by the pseudo-second order model, while the maximum adsorption capacity was approximately 470 mg/g. The experimental data fit very well with the Langmuir isotherm model. The adsorption process was determined to be exothermic, and the mechanism was proposed to be electrostatic interaction between the quaternary ammonium moiety and negatively charge anionic dyes. Finally, the Weber-Morris study suggested that both film diffusion and intraparticle diffusion contribute to the adsorption process.
Fil: Castagnino Schirmer, Malena. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; Argentina
Fil: Bertoni, Fernando Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; Argentina. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina
Fil: Giordano, Enrique David Victor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; Argentina
Materia
QUATERNIZED MICROCRYSTALLINE CELLULOSE
SOYBEAN HULLS
TEXTILE DYES
ADSORPTION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/255317
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/255317
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hullsCastagnino Schirmer, MalenaBertoni, Fernando ArielGiordano, Enrique David VictorQUATERNIZED MICROCRYSTALLINE CELLULOSESOYBEAN HULLSTEXTILE DYESADSORPTIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A novel quaternized microcrystalline cellulose (Q-MCC) was obtained through a one-pot synthesis using agro-industrial waste, specifically soybean hulls (SBH), as the starting material. This work focuses on discussing the synthesis, physicochemical characterization, and application of Q-MCC, particularly its potential use in the removal of industrial textile dyes. The material underwent various characterization techniques, including Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM), optical microscopy, thermogravimetric analysis/differential thermal analysis (TGA/DTA), and differential scanning calorimetry (DSC). Additionally, Kjeldahl analysis, swelling measurements, and determination of the pH at the zero-point charge (pHzpc) were performed. FTIR spectroscopy confirmed the presence of attached quaternary ammonium groups. SEM and XRD analysis of Q-MCC revealed that the material consisted of short fibers with an average length of 30.93 µm and exhibited an increased crystallinity index of 76.4 %, respectively. Moreover, the pH at the point of zero charge (pHpzc) indicated that the adsorbent displayed a cationic nature across the tested pH range. The modification of SBH led to enhanced water absorption, and excellent dye removal results were achieved using two types of dyes: Direct Black 22 (DB 22) and Reactive Orange 122 (RO 122). To further investigate the behavior of Q-MCC in the adsorption of DB 22 dye, various studies were conducted, including kinetic, adsorption, thermodynamic analyses, and Weber-Morris intraparticle diffusion analysis. The kinetics results demonstrated that more than 90 % of the dye was adsorbed within just one minute of contact and were better represented by the pseudo-second order model, while the maximum adsorption capacity was approximately 470 mg/g. The experimental data fit very well with the Langmuir isotherm model. The adsorption process was determined to be exothermic, and the mechanism was proposed to be electrostatic interaction between the quaternary ammonium moiety and negatively charge anionic dyes. Finally, the Weber-Morris study suggested that both film diffusion and intraparticle diffusion contribute to the adsorption process.Fil: Castagnino Schirmer, Malena. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; ArgentinaFil: Bertoni, Fernando Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; Argentina. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; ArgentinaFil: Giordano, Enrique David Victor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; ArgentinaElsevier2023-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/255317Castagnino Schirmer, Malena; Bertoni, Fernando Ariel; Giordano, Enrique David Victor; One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hulls; Elsevier; Next Materials; 1; 3; 7-2023; 1-142949-8228CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S2949822823000291info:eu-repo/semantics/altIdentifier/doi/10.1016/j.nxmate.2023.100029info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:41:48Zoai:ri.conicet.gov.ar:11336/255317instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:41:49.234CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hulls
title One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hulls
spellingShingle One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hulls
Castagnino Schirmer, Malena
QUATERNIZED MICROCRYSTALLINE CELLULOSE
SOYBEAN HULLS
TEXTILE DYES
ADSORPTION
title_short One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hulls
title_full One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hulls
title_fullStr One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hulls
title_full_unstemmed One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hulls
title_sort One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hulls
dc.creator.none.fl_str_mv Castagnino Schirmer, Malena
Bertoni, Fernando Ariel
Giordano, Enrique David Victor
author Castagnino Schirmer, Malena
author_facet Castagnino Schirmer, Malena
Bertoni, Fernando Ariel
Giordano, Enrique David Victor
author_role author
author2 Bertoni, Fernando Ariel
Giordano, Enrique David Victor
author2_role author
author
dc.subject.none.fl_str_mv QUATERNIZED MICROCRYSTALLINE CELLULOSE
SOYBEAN HULLS
TEXTILE DYES
ADSORPTION
topic QUATERNIZED MICROCRYSTALLINE CELLULOSE
SOYBEAN HULLS
TEXTILE DYES
ADSORPTION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A novel quaternized microcrystalline cellulose (Q-MCC) was obtained through a one-pot synthesis using agro-industrial waste, specifically soybean hulls (SBH), as the starting material. This work focuses on discussing the synthesis, physicochemical characterization, and application of Q-MCC, particularly its potential use in the removal of industrial textile dyes. The material underwent various characterization techniques, including Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM), optical microscopy, thermogravimetric analysis/differential thermal analysis (TGA/DTA), and differential scanning calorimetry (DSC). Additionally, Kjeldahl analysis, swelling measurements, and determination of the pH at the zero-point charge (pHzpc) were performed. FTIR spectroscopy confirmed the presence of attached quaternary ammonium groups. SEM and XRD analysis of Q-MCC revealed that the material consisted of short fibers with an average length of 30.93 µm and exhibited an increased crystallinity index of 76.4 %, respectively. Moreover, the pH at the point of zero charge (pHpzc) indicated that the adsorbent displayed a cationic nature across the tested pH range. The modification of SBH led to enhanced water absorption, and excellent dye removal results were achieved using two types of dyes: Direct Black 22 (DB 22) and Reactive Orange 122 (RO 122). To further investigate the behavior of Q-MCC in the adsorption of DB 22 dye, various studies were conducted, including kinetic, adsorption, thermodynamic analyses, and Weber-Morris intraparticle diffusion analysis. The kinetics results demonstrated that more than 90 % of the dye was adsorbed within just one minute of contact and were better represented by the pseudo-second order model, while the maximum adsorption capacity was approximately 470 mg/g. The experimental data fit very well with the Langmuir isotherm model. The adsorption process was determined to be exothermic, and the mechanism was proposed to be electrostatic interaction between the quaternary ammonium moiety and negatively charge anionic dyes. Finally, the Weber-Morris study suggested that both film diffusion and intraparticle diffusion contribute to the adsorption process.
Fil: Castagnino Schirmer, Malena. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; Argentina
Fil: Bertoni, Fernando Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; Argentina. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas; Argentina
Fil: Giordano, Enrique David Victor. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Procesos Biotecnológicos y Químicos Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Procesos Biotecnológicos y Químicos Rosario; Argentina
description A novel quaternized microcrystalline cellulose (Q-MCC) was obtained through a one-pot synthesis using agro-industrial waste, specifically soybean hulls (SBH), as the starting material. This work focuses on discussing the synthesis, physicochemical characterization, and application of Q-MCC, particularly its potential use in the removal of industrial textile dyes. The material underwent various characterization techniques, including Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM), optical microscopy, thermogravimetric analysis/differential thermal analysis (TGA/DTA), and differential scanning calorimetry (DSC). Additionally, Kjeldahl analysis, swelling measurements, and determination of the pH at the zero-point charge (pHzpc) were performed. FTIR spectroscopy confirmed the presence of attached quaternary ammonium groups. SEM and XRD analysis of Q-MCC revealed that the material consisted of short fibers with an average length of 30.93 µm and exhibited an increased crystallinity index of 76.4 %, respectively. Moreover, the pH at the point of zero charge (pHpzc) indicated that the adsorbent displayed a cationic nature across the tested pH range. The modification of SBH led to enhanced water absorption, and excellent dye removal results were achieved using two types of dyes: Direct Black 22 (DB 22) and Reactive Orange 122 (RO 122). To further investigate the behavior of Q-MCC in the adsorption of DB 22 dye, various studies were conducted, including kinetic, adsorption, thermodynamic analyses, and Weber-Morris intraparticle diffusion analysis. The kinetics results demonstrated that more than 90 % of the dye was adsorbed within just one minute of contact and were better represented by the pseudo-second order model, while the maximum adsorption capacity was approximately 470 mg/g. The experimental data fit very well with the Langmuir isotherm model. The adsorption process was determined to be exothermic, and the mechanism was proposed to be electrostatic interaction between the quaternary ammonium moiety and negatively charge anionic dyes. Finally, the Weber-Morris study suggested that both film diffusion and intraparticle diffusion contribute to the adsorption process.
publishDate 2023
dc.date.none.fl_str_mv 2023-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/255317
Castagnino Schirmer, Malena; Bertoni, Fernando Ariel; Giordano, Enrique David Victor; One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hulls; Elsevier; Next Materials; 1; 3; 7-2023; 1-14
2949-8228
CONICET Digital
CONICET
url http://hdl.handle.net/11336/255317
identifier_str_mv Castagnino Schirmer, Malena; Bertoni, Fernando Ariel; Giordano, Enrique David Victor; One-pot synthesis of quaternized microcrystalline cellulose obtained from soybean hulls; Elsevier; Next Materials; 1; 3; 7-2023; 1-14
2949-8228
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S2949822823000291
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.nxmate.2023.100029
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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