Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance

Autores
Díaz, Liliana Alicia; Hnát, Jaromír; Heredia, Nayra; Bruno, Mariano Martín; Viva, Federico Andrés; Paidar, Martin; Corti, Horacio Roberto; Bouzek, Karel; Abuin, Graciela Carmen
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The properties and performance of linear and cross-linked KOH doped ABPBI membranes as electrolyte/separator for zero gap alkaline water electrolysis cells are evaluated and compared with a commercial Zirfon® diaphragm. Stability in alkaline environment, swelling, thermal properties, water sorption, KOH uptake and conductivity of linear (L-ABPBI) and cross-linked (C-ABPBI) membranes doped with different concentrations of KOH are analyzed. Linear membranes show stability up to 3.0 mol·dm−3 KOH doping, while cross-linked membranes are stable up to 4.2 mol·dm−3 KOH doping. Both kinds of membranes exhibit good thermal stability and reasonable specific ionic conductivity at 22 °C in the range between 7 and 25 mS·cm−1, being slightly higher the conductivity of C-ABPBI membranes than that of L-ABPBI ones. In short-term electrolysis tests both L-ABPBI and C-ABPBI membranes show better performance than Zirfon diaphragm in the range from 50 to 70 °C. A current density of 335 mA·cm−2 at a cell voltage of 2.0 V is attained with C-ABPBI membranes doped in 3 mol·dm−3 KOH at 70 °C, a performance comparable with that of commercial units operating at temperatures ca. 80 °C and 30 wt% KOH (6.7 mol·dm−3) as electrolyte.
Fil: Díaz, Liliana Alicia. Instituto Nacional de Tecnología Industrial; Argentina
Fil: Hnát, Jaromír. University of Chemistry and Technology Prague; República Checa
Fil: Heredia, Nayra. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Bruno, Mariano Martín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Viva, Federico Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Paidar, Martin. University of Chemistry and Technology Prague; República Checa
Fil: Corti, Horacio Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Bouzek, Karel. University of Chemistry and Technology Prague; República Checa
Fil: Abuin, Graciela Carmen. Instituto Nacional de Tecnología Industrial; Argentina
Materia
Abpbi
Membranes
Electrolyzers
Water Electrolysis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/43981
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/43981
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performanceDíaz, Liliana AliciaHnát, JaromírHeredia, NayraBruno, Mariano MartínViva, Federico AndrésPaidar, MartinCorti, Horacio RobertoBouzek, KarelAbuin, Graciela CarmenAbpbiMembranesElectrolyzersWater Electrolysishttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The properties and performance of linear and cross-linked KOH doped ABPBI membranes as electrolyte/separator for zero gap alkaline water electrolysis cells are evaluated and compared with a commercial Zirfon® diaphragm. Stability in alkaline environment, swelling, thermal properties, water sorption, KOH uptake and conductivity of linear (L-ABPBI) and cross-linked (C-ABPBI) membranes doped with different concentrations of KOH are analyzed. Linear membranes show stability up to 3.0 mol·dm−3 KOH doping, while cross-linked membranes are stable up to 4.2 mol·dm−3 KOH doping. Both kinds of membranes exhibit good thermal stability and reasonable specific ionic conductivity at 22 °C in the range between 7 and 25 mS·cm−1, being slightly higher the conductivity of C-ABPBI membranes than that of L-ABPBI ones. In short-term electrolysis tests both L-ABPBI and C-ABPBI membranes show better performance than Zirfon diaphragm in the range from 50 to 70 °C. A current density of 335 mA·cm−2 at a cell voltage of 2.0 V is attained with C-ABPBI membranes doped in 3 mol·dm−3 KOH at 70 °C, a performance comparable with that of commercial units operating at temperatures ca. 80 °C and 30 wt% KOH (6.7 mol·dm−3) as electrolyte.Fil: Díaz, Liliana Alicia. Instituto Nacional de Tecnología Industrial; ArgentinaFil: Hnát, Jaromír. University of Chemistry and Technology Prague; República ChecaFil: Heredia, Nayra. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaFil: Bruno, Mariano Martín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaFil: Viva, Federico Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaFil: Paidar, Martin. University of Chemistry and Technology Prague; República ChecaFil: Corti, Horacio Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaFil: Bouzek, Karel. University of Chemistry and Technology Prague; República ChecaFil: Abuin, Graciela Carmen. Instituto Nacional de Tecnología Industrial; ArgentinaElsevier Science2016-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/43981Díaz, Liliana Alicia; Hnát, Jaromír; Heredia, Nayra; Bruno, Mariano Martín; Viva, Federico Andrés; et al.; Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance; Elsevier Science; Journal of Power Sources; 312; 4-2016; 128-1360378-7753CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jpowsour.2016.02.032info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0378775316301409info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:47:43Zoai:ri.conicet.gov.ar:11336/43981instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:47:43.625CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance
title Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance
spellingShingle Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance
Díaz, Liliana Alicia
Abpbi
Membranes
Electrolyzers
Water Electrolysis
title_short Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance
title_full Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance
title_fullStr Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance
title_full_unstemmed Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance
title_sort Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance
dc.creator.none.fl_str_mv Díaz, Liliana Alicia
Hnát, Jaromír
Heredia, Nayra
Bruno, Mariano Martín
Viva, Federico Andrés
Paidar, Martin
Corti, Horacio Roberto
Bouzek, Karel
Abuin, Graciela Carmen
author Díaz, Liliana Alicia
author_facet Díaz, Liliana Alicia
Hnát, Jaromír
Heredia, Nayra
Bruno, Mariano Martín
Viva, Federico Andrés
Paidar, Martin
Corti, Horacio Roberto
Bouzek, Karel
Abuin, Graciela Carmen
author_role author
author2 Hnát, Jaromír
Heredia, Nayra
Bruno, Mariano Martín
Viva, Federico Andrés
Paidar, Martin
Corti, Horacio Roberto
Bouzek, Karel
Abuin, Graciela Carmen
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Abpbi
Membranes
Electrolyzers
Water Electrolysis
topic Abpbi
Membranes
Electrolyzers
Water Electrolysis
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The properties and performance of linear and cross-linked KOH doped ABPBI membranes as electrolyte/separator for zero gap alkaline water electrolysis cells are evaluated and compared with a commercial Zirfon® diaphragm. Stability in alkaline environment, swelling, thermal properties, water sorption, KOH uptake and conductivity of linear (L-ABPBI) and cross-linked (C-ABPBI) membranes doped with different concentrations of KOH are analyzed. Linear membranes show stability up to 3.0 mol·dm−3 KOH doping, while cross-linked membranes are stable up to 4.2 mol·dm−3 KOH doping. Both kinds of membranes exhibit good thermal stability and reasonable specific ionic conductivity at 22 °C in the range between 7 and 25 mS·cm−1, being slightly higher the conductivity of C-ABPBI membranes than that of L-ABPBI ones. In short-term electrolysis tests both L-ABPBI and C-ABPBI membranes show better performance than Zirfon diaphragm in the range from 50 to 70 °C. A current density of 335 mA·cm−2 at a cell voltage of 2.0 V is attained with C-ABPBI membranes doped in 3 mol·dm−3 KOH at 70 °C, a performance comparable with that of commercial units operating at temperatures ca. 80 °C and 30 wt% KOH (6.7 mol·dm−3) as electrolyte.
Fil: Díaz, Liliana Alicia. Instituto Nacional de Tecnología Industrial; Argentina
Fil: Hnát, Jaromír. University of Chemistry and Technology Prague; República Checa
Fil: Heredia, Nayra. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Bruno, Mariano Martín. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Viva, Federico Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Paidar, Martin. University of Chemistry and Technology Prague; República Checa
Fil: Corti, Horacio Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Bouzek, Karel. University of Chemistry and Technology Prague; República Checa
Fil: Abuin, Graciela Carmen. Instituto Nacional de Tecnología Industrial; Argentina
description The properties and performance of linear and cross-linked KOH doped ABPBI membranes as electrolyte/separator for zero gap alkaline water electrolysis cells are evaluated and compared with a commercial Zirfon® diaphragm. Stability in alkaline environment, swelling, thermal properties, water sorption, KOH uptake and conductivity of linear (L-ABPBI) and cross-linked (C-ABPBI) membranes doped with different concentrations of KOH are analyzed. Linear membranes show stability up to 3.0 mol·dm−3 KOH doping, while cross-linked membranes are stable up to 4.2 mol·dm−3 KOH doping. Both kinds of membranes exhibit good thermal stability and reasonable specific ionic conductivity at 22 °C in the range between 7 and 25 mS·cm−1, being slightly higher the conductivity of C-ABPBI membranes than that of L-ABPBI ones. In short-term electrolysis tests both L-ABPBI and C-ABPBI membranes show better performance than Zirfon diaphragm in the range from 50 to 70 °C. A current density of 335 mA·cm−2 at a cell voltage of 2.0 V is attained with C-ABPBI membranes doped in 3 mol·dm−3 KOH at 70 °C, a performance comparable with that of commercial units operating at temperatures ca. 80 °C and 30 wt% KOH (6.7 mol·dm−3) as electrolyte.
publishDate 2016
dc.date.none.fl_str_mv 2016-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/43981
Díaz, Liliana Alicia; Hnát, Jaromír; Heredia, Nayra; Bruno, Mariano Martín; Viva, Federico Andrés; et al.; Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance; Elsevier Science; Journal of Power Sources; 312; 4-2016; 128-136
0378-7753
CONICET Digital
CONICET
url http://hdl.handle.net/11336/43981
identifier_str_mv Díaz, Liliana Alicia; Hnát, Jaromír; Heredia, Nayra; Bruno, Mariano Martín; Viva, Federico Andrés; et al.; Alkali doped poly (2,5-benzimidazole) membrane for alkaline water electrolysis: Characterization and performance; Elsevier Science; Journal of Power Sources; 312; 4-2016; 128-136
0378-7753
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jpowsour.2016.02.032
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0378775316301409
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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