Synthesis and properties of a novel alkylselenium substituted phthalocyanine

Autores
Ezquerra Riega, Sergio Dario; Garcia Vior, María Cecilia; Awruch, Josefina
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The preparation and characterization of a tetrasubstituted alkylselenium zinc(II) phthalocyanine are reported herein for the first time. The precursor 4-(butylselanyl)phthalonitrile (4) was obtained in 65% yield. Tetrasubstituted alkylselenium zinc(II) phthalocyanine 5 was synthesized from 4 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene in butanol.
Fil: Ezquerra Riega, Sergio Dario. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Garcia Vior, María Cecilia. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Awruch, Josefina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Alkylselenium Phthalocyanine
Fluorescence
Singlet Oxygen
Spectroscopy
Synthesis
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/38726
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/38726
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and properties of a novel alkylselenium substituted phthalocyanineEzquerra Riega, Sergio DarioGarcia Vior, María CeciliaAwruch, JosefinaAlkylselenium PhthalocyanineFluorescenceSinglet OxygenSpectroscopySynthesishttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The preparation and characterization of a tetrasubstituted alkylselenium zinc(II) phthalocyanine are reported herein for the first time. The precursor 4-(butylselanyl)phthalonitrile (4) was obtained in 65% yield. Tetrasubstituted alkylselenium zinc(II) phthalocyanine 5 was synthesized from 4 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene in butanol.Fil: Ezquerra Riega, Sergio Dario. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Garcia Vior, María Cecilia. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Awruch, Josefina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaPergamon-Elsevier Science Ltd2015-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/38726Ezquerra Riega, Sergio Dario; Garcia Vior, María Cecilia; Awruch, Josefina; Synthesis and properties of a novel alkylselenium substituted phthalocyanine; Pergamon-Elsevier Science Ltd; Tetrahedron Letters; 56; 26; 5-2015; 4047-40490040-4039CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0040403915008369info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tetlet.2015.05.027info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:09:53Zoai:ri.conicet.gov.ar:11336/38726instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:09:54.066CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and properties of a novel alkylselenium substituted phthalocyanine
title Synthesis and properties of a novel alkylselenium substituted phthalocyanine
spellingShingle Synthesis and properties of a novel alkylselenium substituted phthalocyanine
Ezquerra Riega, Sergio Dario
Alkylselenium Phthalocyanine
Fluorescence
Singlet Oxygen
Spectroscopy
Synthesis
title_short Synthesis and properties of a novel alkylselenium substituted phthalocyanine
title_full Synthesis and properties of a novel alkylselenium substituted phthalocyanine
title_fullStr Synthesis and properties of a novel alkylselenium substituted phthalocyanine
title_full_unstemmed Synthesis and properties of a novel alkylselenium substituted phthalocyanine
title_sort Synthesis and properties of a novel alkylselenium substituted phthalocyanine
dc.creator.none.fl_str_mv Ezquerra Riega, Sergio Dario
Garcia Vior, María Cecilia
Awruch, Josefina
author Ezquerra Riega, Sergio Dario
author_facet Ezquerra Riega, Sergio Dario
Garcia Vior, María Cecilia
Awruch, Josefina
author_role author
author2 Garcia Vior, María Cecilia
Awruch, Josefina
author2_role author
author
dc.subject.none.fl_str_mv Alkylselenium Phthalocyanine
Fluorescence
Singlet Oxygen
Spectroscopy
Synthesis
topic Alkylselenium Phthalocyanine
Fluorescence
Singlet Oxygen
Spectroscopy
Synthesis
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The preparation and characterization of a tetrasubstituted alkylselenium zinc(II) phthalocyanine are reported herein for the first time. The precursor 4-(butylselanyl)phthalonitrile (4) was obtained in 65% yield. Tetrasubstituted alkylselenium zinc(II) phthalocyanine 5 was synthesized from 4 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene in butanol.
Fil: Ezquerra Riega, Sergio Dario. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Garcia Vior, María Cecilia. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Awruch, Josefina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description The preparation and characterization of a tetrasubstituted alkylselenium zinc(II) phthalocyanine are reported herein for the first time. The precursor 4-(butylselanyl)phthalonitrile (4) was obtained in 65% yield. Tetrasubstituted alkylselenium zinc(II) phthalocyanine 5 was synthesized from 4 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene in butanol.
publishDate 2015
dc.date.none.fl_str_mv 2015-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/38726
Ezquerra Riega, Sergio Dario; Garcia Vior, María Cecilia; Awruch, Josefina; Synthesis and properties of a novel alkylselenium substituted phthalocyanine; Pergamon-Elsevier Science Ltd; Tetrahedron Letters; 56; 26; 5-2015; 4047-4049
0040-4039
CONICET Digital
CONICET
url http://hdl.handle.net/11336/38726
identifier_str_mv Ezquerra Riega, Sergio Dario; Garcia Vior, María Cecilia; Awruch, Josefina; Synthesis and properties of a novel alkylselenium substituted phthalocyanine; Pergamon-Elsevier Science Ltd; Tetrahedron Letters; 56; 26; 5-2015; 4047-4049
0040-4039
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0040403915008369
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tetlet.2015.05.027
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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