Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approach
- Autores
- Silvero, María Jazmín; Peláez, Walter José; Garcia, Pablo Facundo; Arguello, Gerardo
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Background: in the last ten years, Photodynamic Antimicrobial Chemotherapy (PACT) has emerged as a reliable option to treat several bacterial and fungal infections. Tris(N,N-diimine)chromium(III) complexes are known for their potential as photosensitizers; however, synthesis is usually a very time consuming procedure. Results: with our novel methodology, [Cr(biim)3](NO3)3 was prepared in a few seconds as a powder and the yield of the reaction was improved compared with previously described syntheses, where obtaining crystals is complicated due to the acidity of the media. The precursors for the synthesis are also synthesized through fast and simple methods. Identification of intermediates and the final product was performed by melting point, infrared, UV-vis and NMR spectroscopy. Conclusions: this article describes a quick, easy and eco-friendly procedure to synthesize [Cr(biim)3](NO3)3 by employing microwave irradiation.
Fil: Silvero, María Jazmín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Peláez, Walter José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Garcia, Pablo Facundo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Arguello, Gerardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina - Materia
-
Syntesis
Microondas
Cromo
Fotosensitizador - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/26080
Ver los metadatos del registro completo
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oai:ri.conicet.gov.ar:11336/26080 |
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3498 |
network_name_str |
CONICET Digital (CONICET) |
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Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approachSilvero, María JazmínPeláez, Walter JoséGarcia, Pablo FacundoArguello, GerardoSyntesisMicroondasCromoFotosensitizadorhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Background: in the last ten years, Photodynamic Antimicrobial Chemotherapy (PACT) has emerged as a reliable option to treat several bacterial and fungal infections. Tris(N,N-diimine)chromium(III) complexes are known for their potential as photosensitizers; however, synthesis is usually a very time consuming procedure. Results: with our novel methodology, [Cr(biim)3](NO3)3 was prepared in a few seconds as a powder and the yield of the reaction was improved compared with previously described syntheses, where obtaining crystals is complicated due to the acidity of the media. The precursors for the synthesis are also synthesized through fast and simple methods. Identification of intermediates and the final product was performed by melting point, infrared, UV-vis and NMR spectroscopy. Conclusions: this article describes a quick, easy and eco-friendly procedure to synthesize [Cr(biim)3](NO3)3 by employing microwave irradiation.Fil: Silvero, María Jazmín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Peláez, Walter José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Garcia, Pablo Facundo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Arguello, Gerardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaRoyal Society of Chemistry2013-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/26080Silvero, María Jazmín; Peláez, Walter José; Garcia, Pablo Facundo; Arguello, Gerardo; Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approach; Royal Society of Chemistry; RSC Advances; 4; 30; 12-2013; 15507-155102046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/c3ra45842cinfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2014/RA/C3RA45842C#!divAbstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:09:09Zoai:ri.conicet.gov.ar:11336/26080instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:09:09.364CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approach |
title |
Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approach |
spellingShingle |
Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approach Silvero, María Jazmín Syntesis Microondas Cromo Fotosensitizador |
title_short |
Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approach |
title_full |
Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approach |
title_fullStr |
Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approach |
title_full_unstemmed |
Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approach |
title_sort |
Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approach |
dc.creator.none.fl_str_mv |
Silvero, María Jazmín Peláez, Walter José Garcia, Pablo Facundo Arguello, Gerardo |
author |
Silvero, María Jazmín |
author_facet |
Silvero, María Jazmín Peláez, Walter José Garcia, Pablo Facundo Arguello, Gerardo |
author_role |
author |
author2 |
Peláez, Walter José Garcia, Pablo Facundo Arguello, Gerardo |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Syntesis Microondas Cromo Fotosensitizador |
topic |
Syntesis Microondas Cromo Fotosensitizador |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Background: in the last ten years, Photodynamic Antimicrobial Chemotherapy (PACT) has emerged as a reliable option to treat several bacterial and fungal infections. Tris(N,N-diimine)chromium(III) complexes are known for their potential as photosensitizers; however, synthesis is usually a very time consuming procedure. Results: with our novel methodology, [Cr(biim)3](NO3)3 was prepared in a few seconds as a powder and the yield of the reaction was improved compared with previously described syntheses, where obtaining crystals is complicated due to the acidity of the media. The precursors for the synthesis are also synthesized through fast and simple methods. Identification of intermediates and the final product was performed by melting point, infrared, UV-vis and NMR spectroscopy. Conclusions: this article describes a quick, easy and eco-friendly procedure to synthesize [Cr(biim)3](NO3)3 by employing microwave irradiation. Fil: Silvero, María Jazmín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Peláez, Walter José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Garcia, Pablo Facundo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Arguello, Gerardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina |
description |
Background: in the last ten years, Photodynamic Antimicrobial Chemotherapy (PACT) has emerged as a reliable option to treat several bacterial and fungal infections. Tris(N,N-diimine)chromium(III) complexes are known for their potential as photosensitizers; however, synthesis is usually a very time consuming procedure. Results: with our novel methodology, [Cr(biim)3](NO3)3 was prepared in a few seconds as a powder and the yield of the reaction was improved compared with previously described syntheses, where obtaining crystals is complicated due to the acidity of the media. The precursors for the synthesis are also synthesized through fast and simple methods. Identification of intermediates and the final product was performed by melting point, infrared, UV-vis and NMR spectroscopy. Conclusions: this article describes a quick, easy and eco-friendly procedure to synthesize [Cr(biim)3](NO3)3 by employing microwave irradiation. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/26080 Silvero, María Jazmín; Peláez, Walter José; Garcia, Pablo Facundo; Arguello, Gerardo; Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approach; Royal Society of Chemistry; RSC Advances; 4; 30; 12-2013; 15507-15510 2046-2069 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/26080 |
identifier_str_mv |
Silvero, María Jazmín; Peláez, Walter José; Garcia, Pablo Facundo; Arguello, Gerardo; Fast synthesis of a tris(N,N-diimine)chromium(III) complex by a microwave-assisted approach; Royal Society of Chemistry; RSC Advances; 4; 30; 12-2013; 15507-15510 2046-2069 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1039/c3ra45842c info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2014/RA/C3RA45842C#!divAbstract |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Royal Society of Chemistry |
publisher.none.fl_str_mv |
Royal Society of Chemistry |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613966604533760 |
score |
13.070432 |