Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation
- Autores
- Sanguineti, Pamela Beatriz; Baltanas, Miguel Angel; Bonivardi, Adrian Lionel
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The impact of the interaction between copper and gallia was studied over a selected set of supported(2 wt%) Cu on Ga2O3, ZrO2and Ga2O3–ZrO2catalysts, which were employed in the methanol synthesisfrom CO2and CO mixtures. The higher initial rate of methanol production on the Cu/ZrO2catalyst wasaccompanied by an activity loss of ~35% after 5 h on stream. However, all the gallated catalysts werenotoriously more stable (and selective) than copper on pure zirconia was. Temperature-programmedreduction in H2, X-ray photoelectron spectroscopy and infrared spectroscopy of adsorbed CO resultsproved that temperatures higher than 553 K are needed to completely reduced Cu2+to metallic Cu parti-cles in the gallia-containing catalysts, which was attributed to the formation of a CuGa2O4nanospinel. Theternary Cu–Ga2O3–ZrO2catalysts showed an intermediate behavior, quite dependent on the preparationprotocol, which emphasizes the need for tuning the degree of Cu–oxides interactions. It is suggested thatjust a moderate copper–gallia interaction is beneficial in terms of both activity and selectivity but, also,that a detrimental loss of ‘active’ copper should be avoided.
Fil: Sanguineti, Pamela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Fil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina
Fil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina - Materia
-
Gallia Promotion
Co2 Recycling
Copper Gallate
Cu+
Ftir - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/10041
Ver los metadatos del registro completo
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Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenationSanguineti, Pamela BeatrizBaltanas, Miguel AngelBonivardi, Adrian LionelGallia PromotionCo2 RecyclingCopper GallateCu+Ftirhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The impact of the interaction between copper and gallia was studied over a selected set of supported(2 wt%) Cu on Ga2O3, ZrO2and Ga2O3–ZrO2catalysts, which were employed in the methanol synthesisfrom CO2and CO mixtures. The higher initial rate of methanol production on the Cu/ZrO2catalyst wasaccompanied by an activity loss of ~35% after 5 h on stream. However, all the gallated catalysts werenotoriously more stable (and selective) than copper on pure zirconia was. Temperature-programmedreduction in H2, X-ray photoelectron spectroscopy and infrared spectroscopy of adsorbed CO resultsproved that temperatures higher than 553 K are needed to completely reduced Cu2+to metallic Cu parti-cles in the gallia-containing catalysts, which was attributed to the formation of a CuGa2O4nanospinel. Theternary Cu–Ga2O3–ZrO2catalysts showed an intermediate behavior, quite dependent on the preparationprotocol, which emphasizes the need for tuning the degree of Cu–oxides interactions. It is suggested thatjust a moderate copper–gallia interaction is beneficial in terms of both activity and selectivity but, also,that a detrimental loss of ‘active’ copper should be avoided.Fil: Sanguineti, Pamela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); ArgentinaFil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); ArgentinaFil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); ArgentinaElsevier Science2015-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/10041Sanguineti, Pamela Beatriz; Baltanas, Miguel Angel; Bonivardi, Adrian Lionel; Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation; Elsevier Science; Applied Catalysis A: General; 504; 9-2015; 476-4810926-860Xenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2014.11.021info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926860X14007273info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:04:39Zoai:ri.conicet.gov.ar:11336/10041instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:04:39.528CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation |
title |
Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation |
spellingShingle |
Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation Sanguineti, Pamela Beatriz Gallia Promotion Co2 Recycling Copper Gallate Cu+ Ftir |
title_short |
Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation |
title_full |
Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation |
title_fullStr |
Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation |
title_full_unstemmed |
Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation |
title_sort |
Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation |
dc.creator.none.fl_str_mv |
Sanguineti, Pamela Beatriz Baltanas, Miguel Angel Bonivardi, Adrian Lionel |
author |
Sanguineti, Pamela Beatriz |
author_facet |
Sanguineti, Pamela Beatriz Baltanas, Miguel Angel Bonivardi, Adrian Lionel |
author_role |
author |
author2 |
Baltanas, Miguel Angel Bonivardi, Adrian Lionel |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Gallia Promotion Co2 Recycling Copper Gallate Cu+ Ftir |
topic |
Gallia Promotion Co2 Recycling Copper Gallate Cu+ Ftir |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The impact of the interaction between copper and gallia was studied over a selected set of supported(2 wt%) Cu on Ga2O3, ZrO2and Ga2O3–ZrO2catalysts, which were employed in the methanol synthesisfrom CO2and CO mixtures. The higher initial rate of methanol production on the Cu/ZrO2catalyst wasaccompanied by an activity loss of ~35% after 5 h on stream. However, all the gallated catalysts werenotoriously more stable (and selective) than copper on pure zirconia was. Temperature-programmedreduction in H2, X-ray photoelectron spectroscopy and infrared spectroscopy of adsorbed CO resultsproved that temperatures higher than 553 K are needed to completely reduced Cu2+to metallic Cu parti-cles in the gallia-containing catalysts, which was attributed to the formation of a CuGa2O4nanospinel. Theternary Cu–Ga2O3–ZrO2catalysts showed an intermediate behavior, quite dependent on the preparationprotocol, which emphasizes the need for tuning the degree of Cu–oxides interactions. It is suggested thatjust a moderate copper–gallia interaction is beneficial in terms of both activity and selectivity but, also,that a detrimental loss of ‘active’ copper should be avoided. Fil: Sanguineti, Pamela Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina Fil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina Fil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química (i); Argentina |
description |
The impact of the interaction between copper and gallia was studied over a selected set of supported(2 wt%) Cu on Ga2O3, ZrO2and Ga2O3–ZrO2catalysts, which were employed in the methanol synthesisfrom CO2and CO mixtures. The higher initial rate of methanol production on the Cu/ZrO2catalyst wasaccompanied by an activity loss of ~35% after 5 h on stream. However, all the gallated catalysts werenotoriously more stable (and selective) than copper on pure zirconia was. Temperature-programmedreduction in H2, X-ray photoelectron spectroscopy and infrared spectroscopy of adsorbed CO resultsproved that temperatures higher than 553 K are needed to completely reduced Cu2+to metallic Cu parti-cles in the gallia-containing catalysts, which was attributed to the formation of a CuGa2O4nanospinel. Theternary Cu–Ga2O3–ZrO2catalysts showed an intermediate behavior, quite dependent on the preparationprotocol, which emphasizes the need for tuning the degree of Cu–oxides interactions. It is suggested thatjust a moderate copper–gallia interaction is beneficial in terms of both activity and selectivity but, also,that a detrimental loss of ‘active’ copper should be avoided. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-09 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/10041 Sanguineti, Pamela Beatriz; Baltanas, Miguel Angel; Bonivardi, Adrian Lionel; Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation; Elsevier Science; Applied Catalysis A: General; 504; 9-2015; 476-481 0926-860X |
url |
http://hdl.handle.net/11336/10041 |
identifier_str_mv |
Sanguineti, Pamela Beatriz; Baltanas, Miguel Angel; Bonivardi, Adrian Lionel; Copper-gallia interaction in Cu-Ga2O3-ZrO2 catalysts for methanol production from carbon oxide(s) hydrogenation; Elsevier Science; Applied Catalysis A: General; 504; 9-2015; 476-481 0926-860X |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2014.11.021 info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926860X14007273 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613874529075200 |
score |
13.070432 |