Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures

Autores
Fornero, Esteban Luis; Sanguinetti, Pamela; Chiavassa, Dante Luis; Bonivardi, Adrian Lionel; Baltanas, Miguel Angel
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The synthesis of methanol via catalytic hydrogenation of carbon oxides was evaluated in two groups of Cu-GaOx/ZrO2 ternary catalysts containing 2 wt% Cu. Copper was incorporated in the first group either by incipient wetness (IW) or by ion exchange (IE), both on the pure oxides (Ga2O3 y ZrO2) and the x-Ga2O3/ZrO2 mixed oxides (where x = 1, 6 or 9 wt% Ga2O3). In a second group of materials galia was incorporated onto Cu-ZrO2 previously dried or dried/calcined. The catalytic evaluations were performed in a tubular microreactor at 3 MPa, 523 K, GHSV = 20000 h-1 using two different gas mixtures. The first mixture contained CO2 and CO (M1: H2/CO2/CO = 75/22/3), while in the second one carbon monoxide was replaced by He (M2: H2/CO2/He = 75/22/3). The yield to methanol was progressively higher with gallia loading, but the best catalyst tested had an intermediate loading of Ga2O3 deposited onto a dried and calcined Cu/ZrO2 precursor which was obtained, in turn, by ion exchanging copper nitrate to the zirconia. The catalysts for which gallium was added to the dried and calcined IE Cu/ZrO2 precursor were the most stable.
Fil: Fornero, Esteban Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
Fil: Sanguinetti, Pamela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
Fil: Chiavassa, Dante Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
Fil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
Fil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
Materia
Supported Copper
Carbon Dioxide
Zirconia
Galia
Metahnol
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/8684
Acceder
id CONICETDig_1c5542533bd7ea22f52dabd475c11460
oai_identifier_str oai:ri.conicet.gov.ar:11336/8684
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixturesFornero, Esteban LuisSanguinetti, PamelaChiavassa, Dante LuisBonivardi, Adrian LionelBaltanas, Miguel AngelSupported CopperCarbon DioxideZirconiaGaliaMetahnolhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The synthesis of methanol via catalytic hydrogenation of carbon oxides was evaluated in two groups of Cu-GaOx/ZrO2 ternary catalysts containing 2 wt% Cu. Copper was incorporated in the first group either by incipient wetness (IW) or by ion exchange (IE), both on the pure oxides (Ga2O3 y ZrO2) and the x-Ga2O3/ZrO2 mixed oxides (where x = 1, 6 or 9 wt% Ga2O3). In a second group of materials galia was incorporated onto Cu-ZrO2 previously dried or dried/calcined. The catalytic evaluations were performed in a tubular microreactor at 3 MPa, 523 K, GHSV = 20000 h-1 using two different gas mixtures. The first mixture contained CO2 and CO (M1: H2/CO2/CO = 75/22/3), while in the second one carbon monoxide was replaced by He (M2: H2/CO2/He = 75/22/3). The yield to methanol was progressively higher with gallia loading, but the best catalyst tested had an intermediate loading of Ga2O3 deposited onto a dried and calcined Cu/ZrO2 precursor which was obtained, in turn, by ion exchanging copper nitrate to the zirconia. The catalysts for which gallium was added to the dried and calcined IE Cu/ZrO2 precursor were the most stable.Fil: Fornero, Esteban Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); ArgentinaFil: Sanguinetti, Pamela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); ArgentinaFil: Chiavassa, Dante Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); ArgentinaFil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); ArgentinaFil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); ArgentinaElsevier Science2013-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/8684Fornero, Esteban Luis; Sanguinetti, Pamela; Chiavassa, Dante Luis; Bonivardi, Adrian Lionel; Baltanas, Miguel Angel; Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures; Elsevier Science; Catalysis Today; 213; 6-2013; 163-1700920-5861enginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2013.03.012info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0920586113001077info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:46:32Zoai:ri.conicet.gov.ar:11336/8684instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:46:33.25CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures
title Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures
spellingShingle Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures
Fornero, Esteban Luis
Supported Copper
Carbon Dioxide
Zirconia
Galia
Metahnol
title_short Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures
title_full Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures
title_fullStr Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures
title_full_unstemmed Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures
title_sort Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures
dc.creator.none.fl_str_mv Fornero, Esteban Luis
Sanguinetti, Pamela
Chiavassa, Dante Luis
Bonivardi, Adrian Lionel
Baltanas, Miguel Angel
author Fornero, Esteban Luis
author_facet Fornero, Esteban Luis
Sanguinetti, Pamela
Chiavassa, Dante Luis
Bonivardi, Adrian Lionel
Baltanas, Miguel Angel
author_role author
author2 Sanguinetti, Pamela
Chiavassa, Dante Luis
Bonivardi, Adrian Lionel
Baltanas, Miguel Angel
author2_role author
author
author
author
dc.subject.none.fl_str_mv Supported Copper
Carbon Dioxide
Zirconia
Galia
Metahnol
topic Supported Copper
Carbon Dioxide
Zirconia
Galia
Metahnol
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The synthesis of methanol via catalytic hydrogenation of carbon oxides was evaluated in two groups of Cu-GaOx/ZrO2 ternary catalysts containing 2 wt% Cu. Copper was incorporated in the first group either by incipient wetness (IW) or by ion exchange (IE), both on the pure oxides (Ga2O3 y ZrO2) and the x-Ga2O3/ZrO2 mixed oxides (where x = 1, 6 or 9 wt% Ga2O3). In a second group of materials galia was incorporated onto Cu-ZrO2 previously dried or dried/calcined. The catalytic evaluations were performed in a tubular microreactor at 3 MPa, 523 K, GHSV = 20000 h-1 using two different gas mixtures. The first mixture contained CO2 and CO (M1: H2/CO2/CO = 75/22/3), while in the second one carbon monoxide was replaced by He (M2: H2/CO2/He = 75/22/3). The yield to methanol was progressively higher with gallia loading, but the best catalyst tested had an intermediate loading of Ga2O3 deposited onto a dried and calcined Cu/ZrO2 precursor which was obtained, in turn, by ion exchanging copper nitrate to the zirconia. The catalysts for which gallium was added to the dried and calcined IE Cu/ZrO2 precursor were the most stable.
Fil: Fornero, Esteban Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
Fil: Sanguinetti, Pamela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
Fil: Chiavassa, Dante Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
Fil: Bonivardi, Adrian Lionel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
Fil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo Tecnológico Para la Industria Química (i); Argentina
description The synthesis of methanol via catalytic hydrogenation of carbon oxides was evaluated in two groups of Cu-GaOx/ZrO2 ternary catalysts containing 2 wt% Cu. Copper was incorporated in the first group either by incipient wetness (IW) or by ion exchange (IE), both on the pure oxides (Ga2O3 y ZrO2) and the x-Ga2O3/ZrO2 mixed oxides (where x = 1, 6 or 9 wt% Ga2O3). In a second group of materials galia was incorporated onto Cu-ZrO2 previously dried or dried/calcined. The catalytic evaluations were performed in a tubular microreactor at 3 MPa, 523 K, GHSV = 20000 h-1 using two different gas mixtures. The first mixture contained CO2 and CO (M1: H2/CO2/CO = 75/22/3), while in the second one carbon monoxide was replaced by He (M2: H2/CO2/He = 75/22/3). The yield to methanol was progressively higher with gallia loading, but the best catalyst tested had an intermediate loading of Ga2O3 deposited onto a dried and calcined Cu/ZrO2 precursor which was obtained, in turn, by ion exchanging copper nitrate to the zirconia. The catalysts for which gallium was added to the dried and calcined IE Cu/ZrO2 precursor were the most stable.
publishDate 2013
dc.date.none.fl_str_mv 2013-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/8684
Fornero, Esteban Luis; Sanguinetti, Pamela; Chiavassa, Dante Luis; Bonivardi, Adrian Lionel; Baltanas, Miguel Angel; Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures; Elsevier Science; Catalysis Today; 213; 6-2013; 163-170
0920-5861
url http://hdl.handle.net/11336/8684
identifier_str_mv Fornero, Esteban Luis; Sanguinetti, Pamela; Chiavassa, Dante Luis; Bonivardi, Adrian Lionel; Baltanas, Miguel Angel; Performance of ternary Cu-Ga2O3-ZrO2 catalysts in the synthesis of methanol using CO2-rich gas mixtures; Elsevier Science; Catalysis Today; 213; 6-2013; 163-170
0920-5861
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2013.03.012
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0920586113001077
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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