Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review
- Autores
- Bordoni, Andrea Veronica; Lombardo, Maria Veronica; Wolosiuk, Alejandro
- Año de publicación
- 2016
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Although known for more than 40 years in the polymer chemistry field, the photochemical radical thiol?ene addition (PRTEA) has been recently recognized as a chemical reaction with click characteristics. Photoinitiation enables spatial and temporal control of this highly efficient reaction, bridging simple organic chemistry with high-end materials synthesis and surfaces functionalization. In this minireview, we focus on the latest contributions based on the PRTEA for the synthesis of chemical precursors for silica and transition metal oxides (TMO) based materials. We summarize the mechanism of the PRTEA, the development of new families of photoinitiators and how this extremely simple approach has spilled over into the materials science arena with clear success. In particular, PRTEA adds to the collective efforts for building a reliable and straightforward chemical toolbox for surface modification and the production of sol?gel precursors, nanoparticles and thin films. The excellent perspectives for simple molecular and supramolecular building block synthesis opens up a rational synthetic route for the design and integration of these components in multipurpose platforms.
Fil: Bordoni, Andrea Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Lombardo, Maria Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Wolosiuk, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina - Materia
-
CLICK CHEMISTRY
FUNCTIONALIZATION
SILICA
METAL OXIDES
THIOL-ENE - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/114835
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Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-reviewBordoni, Andrea VeronicaLombardo, Maria VeronicaWolosiuk, AlejandroCLICK CHEMISTRYFUNCTIONALIZATIONSILICAMETAL OXIDESTHIOL-ENEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Although known for more than 40 years in the polymer chemistry field, the photochemical radical thiol?ene addition (PRTEA) has been recently recognized as a chemical reaction with click characteristics. Photoinitiation enables spatial and temporal control of this highly efficient reaction, bridging simple organic chemistry with high-end materials synthesis and surfaces functionalization. In this minireview, we focus on the latest contributions based on the PRTEA for the synthesis of chemical precursors for silica and transition metal oxides (TMO) based materials. We summarize the mechanism of the PRTEA, the development of new families of photoinitiators and how this extremely simple approach has spilled over into the materials science arena with clear success. In particular, PRTEA adds to the collective efforts for building a reliable and straightforward chemical toolbox for surface modification and the production of sol?gel precursors, nanoparticles and thin films. The excellent perspectives for simple molecular and supramolecular building block synthesis opens up a rational synthetic route for the design and integration of these components in multipurpose platforms.Fil: Bordoni, Andrea Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Lombardo, Maria Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Wolosiuk, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); ArgentinaRoyal Society of Chemistry2016-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/114835Bordoni, Andrea Veronica; Lombardo, Maria Veronica; Wolosiuk, Alejandro; Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review; Royal Society of Chemistry; RSC Advances; 6; 81; 8-2016; 77410-774262046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra10388j#!divAbstractinfo:eu-repo/semantics/altIdentifier/doi/10.1039/c6ra10388jinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:35:04Zoai:ri.conicet.gov.ar:11336/114835instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:35:04.81CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review |
title |
Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review |
spellingShingle |
Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review Bordoni, Andrea Veronica CLICK CHEMISTRY FUNCTIONALIZATION SILICA METAL OXIDES THIOL-ENE |
title_short |
Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review |
title_full |
Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review |
title_fullStr |
Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review |
title_full_unstemmed |
Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review |
title_sort |
Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review |
dc.creator.none.fl_str_mv |
Bordoni, Andrea Veronica Lombardo, Maria Veronica Wolosiuk, Alejandro |
author |
Bordoni, Andrea Veronica |
author_facet |
Bordoni, Andrea Veronica Lombardo, Maria Veronica Wolosiuk, Alejandro |
author_role |
author |
author2 |
Lombardo, Maria Veronica Wolosiuk, Alejandro |
author2_role |
author author |
dc.subject.none.fl_str_mv |
CLICK CHEMISTRY FUNCTIONALIZATION SILICA METAL OXIDES THIOL-ENE |
topic |
CLICK CHEMISTRY FUNCTIONALIZATION SILICA METAL OXIDES THIOL-ENE |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Although known for more than 40 years in the polymer chemistry field, the photochemical radical thiol?ene addition (PRTEA) has been recently recognized as a chemical reaction with click characteristics. Photoinitiation enables spatial and temporal control of this highly efficient reaction, bridging simple organic chemistry with high-end materials synthesis and surfaces functionalization. In this minireview, we focus on the latest contributions based on the PRTEA for the synthesis of chemical precursors for silica and transition metal oxides (TMO) based materials. We summarize the mechanism of the PRTEA, the development of new families of photoinitiators and how this extremely simple approach has spilled over into the materials science arena with clear success. In particular, PRTEA adds to the collective efforts for building a reliable and straightforward chemical toolbox for surface modification and the production of sol?gel precursors, nanoparticles and thin films. The excellent perspectives for simple molecular and supramolecular building block synthesis opens up a rational synthetic route for the design and integration of these components in multipurpose platforms. Fil: Bordoni, Andrea Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Lombardo, Maria Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Wolosiuk, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina |
description |
Although known for more than 40 years in the polymer chemistry field, the photochemical radical thiol?ene addition (PRTEA) has been recently recognized as a chemical reaction with click characteristics. Photoinitiation enables spatial and temporal control of this highly efficient reaction, bridging simple organic chemistry with high-end materials synthesis and surfaces functionalization. In this minireview, we focus on the latest contributions based on the PRTEA for the synthesis of chemical precursors for silica and transition metal oxides (TMO) based materials. We summarize the mechanism of the PRTEA, the development of new families of photoinitiators and how this extremely simple approach has spilled over into the materials science arena with clear success. In particular, PRTEA adds to the collective efforts for building a reliable and straightforward chemical toolbox for surface modification and the production of sol?gel precursors, nanoparticles and thin films. The excellent perspectives for simple molecular and supramolecular building block synthesis opens up a rational synthetic route for the design and integration of these components in multipurpose platforms. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016-08 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/114835 Bordoni, Andrea Veronica; Lombardo, Maria Veronica; Wolosiuk, Alejandro; Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review; Royal Society of Chemistry; RSC Advances; 6; 81; 8-2016; 77410-77426 2046-2069 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/114835 |
identifier_str_mv |
Bordoni, Andrea Veronica; Lombardo, Maria Veronica; Wolosiuk, Alejandro; Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review; Royal Society of Chemistry; RSC Advances; 6; 81; 8-2016; 77410-77426 2046-2069 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra10388j#!divAbstract info:eu-repo/semantics/altIdentifier/doi/10.1039/c6ra10388j |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Royal Society of Chemistry |
publisher.none.fl_str_mv |
Royal Society of Chemistry |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |