Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review

Autores
Bordoni, Andrea Veronica; Lombardo, Maria Veronica; Wolosiuk, Alejandro
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Although known for more than 40 years in the polymer chemistry field, the photochemical radical thiol?ene addition (PRTEA) has been recently recognized as a chemical reaction with click characteristics. Photoinitiation enables spatial and temporal control of this highly efficient reaction, bridging simple organic chemistry with high-end materials synthesis and surfaces functionalization. In this minireview, we focus on the latest contributions based on the PRTEA for the synthesis of chemical precursors for silica and transition metal oxides (TMO) based materials. We summarize the mechanism of the PRTEA, the development of new families of photoinitiators and how this extremely simple approach has spilled over into the materials science arena with clear success. In particular, PRTEA adds to the collective efforts for building a reliable and straightforward chemical toolbox for surface modification and the production of sol?gel precursors, nanoparticles and thin films. The excellent perspectives for simple molecular and supramolecular building block synthesis opens up a rational synthetic route for the design and integration of these components in multipurpose platforms.
Fil: Bordoni, Andrea Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Lombardo, Maria Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Wolosiuk, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina
Materia
CLICK CHEMISTRY
FUNCTIONALIZATION
SILICA
METAL OXIDES
THIOL-ENE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/114835
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-reviewBordoni, Andrea VeronicaLombardo, Maria VeronicaWolosiuk, AlejandroCLICK CHEMISTRYFUNCTIONALIZATIONSILICAMETAL OXIDESTHIOL-ENEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Although known for more than 40 years in the polymer chemistry field, the photochemical radical thiol?ene addition (PRTEA) has been recently recognized as a chemical reaction with click characteristics. Photoinitiation enables spatial and temporal control of this highly efficient reaction, bridging simple organic chemistry with high-end materials synthesis and surfaces functionalization. In this minireview, we focus on the latest contributions based on the PRTEA for the synthesis of chemical precursors for silica and transition metal oxides (TMO) based materials. We summarize the mechanism of the PRTEA, the development of new families of photoinitiators and how this extremely simple approach has spilled over into the materials science arena with clear success. In particular, PRTEA adds to the collective efforts for building a reliable and straightforward chemical toolbox for surface modification and the production of sol?gel precursors, nanoparticles and thin films. The excellent perspectives for simple molecular and supramolecular building block synthesis opens up a rational synthetic route for the design and integration of these components in multipurpose platforms.Fil: Bordoni, Andrea Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Lombardo, Maria Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Wolosiuk, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); ArgentinaRoyal Society of Chemistry2016-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/114835Bordoni, Andrea Veronica; Lombardo, Maria Veronica; Wolosiuk, Alejandro; Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review; Royal Society of Chemistry; RSC Advances; 6; 81; 8-2016; 77410-774262046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra10388j#!divAbstractinfo:eu-repo/semantics/altIdentifier/doi/10.1039/c6ra10388jinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:03:05Zoai:ri.conicet.gov.ar:11336/114835instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:03:06.103CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review
title Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review
spellingShingle Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review
Bordoni, Andrea Veronica
CLICK CHEMISTRY
FUNCTIONALIZATION
SILICA
METAL OXIDES
THIOL-ENE
title_short Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review
title_full Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review
title_fullStr Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review
title_full_unstemmed Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review
title_sort Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review
dc.creator.none.fl_str_mv Bordoni, Andrea Veronica
Lombardo, Maria Veronica
Wolosiuk, Alejandro
author Bordoni, Andrea Veronica
author_facet Bordoni, Andrea Veronica
Lombardo, Maria Veronica
Wolosiuk, Alejandro
author_role author
author2 Lombardo, Maria Veronica
Wolosiuk, Alejandro
author2_role author
author
dc.subject.none.fl_str_mv CLICK CHEMISTRY
FUNCTIONALIZATION
SILICA
METAL OXIDES
THIOL-ENE
topic CLICK CHEMISTRY
FUNCTIONALIZATION
SILICA
METAL OXIDES
THIOL-ENE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Although known for more than 40 years in the polymer chemistry field, the photochemical radical thiol?ene addition (PRTEA) has been recently recognized as a chemical reaction with click characteristics. Photoinitiation enables spatial and temporal control of this highly efficient reaction, bridging simple organic chemistry with high-end materials synthesis and surfaces functionalization. In this minireview, we focus on the latest contributions based on the PRTEA for the synthesis of chemical precursors for silica and transition metal oxides (TMO) based materials. We summarize the mechanism of the PRTEA, the development of new families of photoinitiators and how this extremely simple approach has spilled over into the materials science arena with clear success. In particular, PRTEA adds to the collective efforts for building a reliable and straightforward chemical toolbox for surface modification and the production of sol?gel precursors, nanoparticles and thin films. The excellent perspectives for simple molecular and supramolecular building block synthesis opens up a rational synthetic route for the design and integration of these components in multipurpose platforms.
Fil: Bordoni, Andrea Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Lombardo, Maria Veronica. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Wolosiuk, Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentina
description Although known for more than 40 years in the polymer chemistry field, the photochemical radical thiol?ene addition (PRTEA) has been recently recognized as a chemical reaction with click characteristics. Photoinitiation enables spatial and temporal control of this highly efficient reaction, bridging simple organic chemistry with high-end materials synthesis and surfaces functionalization. In this minireview, we focus on the latest contributions based on the PRTEA for the synthesis of chemical precursors for silica and transition metal oxides (TMO) based materials. We summarize the mechanism of the PRTEA, the development of new families of photoinitiators and how this extremely simple approach has spilled over into the materials science arena with clear success. In particular, PRTEA adds to the collective efforts for building a reliable and straightforward chemical toolbox for surface modification and the production of sol?gel precursors, nanoparticles and thin films. The excellent perspectives for simple molecular and supramolecular building block synthesis opens up a rational synthetic route for the design and integration of these components in multipurpose platforms.
publishDate 2016
dc.date.none.fl_str_mv 2016-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/114835
Bordoni, Andrea Veronica; Lombardo, Maria Veronica; Wolosiuk, Alejandro; Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review; Royal Society of Chemistry; RSC Advances; 6; 81; 8-2016; 77410-77426
2046-2069
CONICET Digital
CONICET
url http://hdl.handle.net/11336/114835
identifier_str_mv Bordoni, Andrea Veronica; Lombardo, Maria Veronica; Wolosiuk, Alejandro; Photochemical radical thiol-ene click-based methodologies for silica and transition metal oxides materials chemical modification: A mini-review; Royal Society of Chemistry; RSC Advances; 6; 81; 8-2016; 77410-77426
2046-2069
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
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info:eu-repo/semantics/altIdentifier/doi/10.1039/c6ra10388j
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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