H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranes

Autores
Farjoo, Afrooz; Avila, Adolfo María; Kuznicki, Steven
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Disk membranes machined from high-purity natural clinoptilolite rocks demonstrated promising hydrogen separation efficiency. However, these membranes cannot be adequately scaled up. To overcome this and provide process flexibility, mixed matrix membranes are required pairing small particles of natural zeolite with a binder system. A novel approach was determined to use metals as binders and was tested by comparing natural clinoptilolite compact disk membranes with and without powdered copper metal. The phase composition and morphology of the disks were characterized and gas separation performance was evaluated using single gas permeation tests. Membrane performance was improved by applying metallic copper and copper oxide filling a portion of the inter-particle spaces and creating adhesion with the zeolite particles.
Fil: Farjoo, Afrooz. University of Alberta; Canadá
Fil: Avila, Adolfo María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
Fil: Kuznicki, Steven. University of Alberta; Canadá
Materia
Hydrogen Separation
Composite Membranes
Copper
Natural Zeolites
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/77756
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/77756
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network_name_str CONICET Digital (CONICET)
spelling H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranesFarjoo, AfroozAvila, Adolfo MaríaKuznicki, StevenHydrogen SeparationComposite MembranesCopperNatural Zeoliteshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Disk membranes machined from high-purity natural clinoptilolite rocks demonstrated promising hydrogen separation efficiency. However, these membranes cannot be adequately scaled up. To overcome this and provide process flexibility, mixed matrix membranes are required pairing small particles of natural zeolite with a binder system. A novel approach was determined to use metals as binders and was tested by comparing natural clinoptilolite compact disk membranes with and without powdered copper metal. The phase composition and morphology of the disks were characterized and gas separation performance was evaluated using single gas permeation tests. Membrane performance was improved by applying metallic copper and copper oxide filling a portion of the inter-particle spaces and creating adhesion with the zeolite particles.Fil: Farjoo, Afrooz. University of Alberta; CanadáFil: Avila, Adolfo María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; ArgentinaFil: Kuznicki, Steven. University of Alberta; CanadáJohn Wiley & Sons Inc2017-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/77756Farjoo, Afrooz; Avila, Adolfo María; Kuznicki, Steven ; H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranes; John Wiley & Sons Inc; The Canadian Journal Of Chemical Engineering; 95; 3; 3-2017; 500-5070008-4034CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/epdf/10.1002/cjce.22683info:eu-repo/semantics/altIdentifier/doi/10.1002/cjce.22683info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:43:42Zoai:ri.conicet.gov.ar:11336/77756instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:43:43.161CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranes
title H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranes
spellingShingle H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranes
Farjoo, Afrooz
Hydrogen Separation
Composite Membranes
Copper
Natural Zeolites
title_short H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranes
title_full H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranes
title_fullStr H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranes
title_full_unstemmed H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranes
title_sort H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranes
dc.creator.none.fl_str_mv Farjoo, Afrooz
Avila, Adolfo María
Kuznicki, Steven
author Farjoo, Afrooz
author_facet Farjoo, Afrooz
Avila, Adolfo María
Kuznicki, Steven
author_role author
author2 Avila, Adolfo María
Kuznicki, Steven
author2_role author
author
dc.subject.none.fl_str_mv Hydrogen Separation
Composite Membranes
Copper
Natural Zeolites
topic Hydrogen Separation
Composite Membranes
Copper
Natural Zeolites
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Disk membranes machined from high-purity natural clinoptilolite rocks demonstrated promising hydrogen separation efficiency. However, these membranes cannot be adequately scaled up. To overcome this and provide process flexibility, mixed matrix membranes are required pairing small particles of natural zeolite with a binder system. A novel approach was determined to use metals as binders and was tested by comparing natural clinoptilolite compact disk membranes with and without powdered copper metal. The phase composition and morphology of the disks were characterized and gas separation performance was evaluated using single gas permeation tests. Membrane performance was improved by applying metallic copper and copper oxide filling a portion of the inter-particle spaces and creating adhesion with the zeolite particles.
Fil: Farjoo, Afrooz. University of Alberta; Canadá
Fil: Avila, Adolfo María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
Fil: Kuznicki, Steven. University of Alberta; Canadá
description Disk membranes machined from high-purity natural clinoptilolite rocks demonstrated promising hydrogen separation efficiency. However, these membranes cannot be adequately scaled up. To overcome this and provide process flexibility, mixed matrix membranes are required pairing small particles of natural zeolite with a binder system. A novel approach was determined to use metals as binders and was tested by comparing natural clinoptilolite compact disk membranes with and without powdered copper metal. The phase composition and morphology of the disks were characterized and gas separation performance was evaluated using single gas permeation tests. Membrane performance was improved by applying metallic copper and copper oxide filling a portion of the inter-particle spaces and creating adhesion with the zeolite particles.
publishDate 2017
dc.date.none.fl_str_mv 2017-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/77756
Farjoo, Afrooz; Avila, Adolfo María; Kuznicki, Steven ; H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranes; John Wiley & Sons Inc; The Canadian Journal Of Chemical Engineering; 95; 3; 3-2017; 500-507
0008-4034
CONICET Digital
CONICET
url http://hdl.handle.net/11336/77756
identifier_str_mv Farjoo, Afrooz; Avila, Adolfo María; Kuznicki, Steven ; H2 separation using pressed clinoptilolite and mixed copper-clinoptilolite disk membranes; John Wiley & Sons Inc; The Canadian Journal Of Chemical Engineering; 95; 3; 3-2017; 500-507
0008-4034
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/epdf/10.1002/cjce.22683
info:eu-repo/semantics/altIdentifier/doi/10.1002/cjce.22683
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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