LaNi5 hydride powder flowability as a function of activation and hydrogen content

Autores
Melnichuk, Maximiliano; Cuscueta, Diego Javier; Silin, Nicolas
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Volume expansion of hydrogen absorbing materials, together with inter-particle friction can cause tension accumulation in hydride containers during absorption. When hydride particles absorb hydrogen there is an important volume increase, in the order of 25%. Particles have to accommodate to the container geometry but this movement is opposed by inter-particle friction. Under certain conditions tensions can build up, compromising the mechanical integrity of the container. This phenomenon needs to be addressed at the design stage to avoid mechanical failure of the container. Flow behavior of powder materials is a relevant technological field, usually addressed by means of qualitative or quantitative flowability measuring devices. The rotating drum technique, while mainly qualitative, is well established and can be modified into a completely sealed unit. To determine the flowability of a hydride under different activation stages and hydrogen content levels we developed a rotating drum device that can be pressurized with hydrogen or depressurized. We report particle size evolution and flowability measurements of a hydrogen absorbing material (LaNi5) at different stages of activation for both absorbed and desorbed states. The results of the present study show that the flowability of LaNi5 in more dependent on the degree of activation of the sample than on hydrogen absorption state.
Fil: Melnichuk, Maximiliano. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina
Fil: Cuscueta, Diego Javier. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional de Cuyo; Argentina
Fil: Silin, Nicolas. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional de Cuyo; Argentina
Materia
Container Stress
Dynamic Angle of Repose
Hydride Rheology
Powder Flowability
Rotating Drum
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/57889
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/57889
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling LaNi5 hydride powder flowability as a function of activation and hydrogen contentMelnichuk, MaximilianoCuscueta, Diego JavierSilin, NicolasContainer StressDynamic Angle of ReposeHydride RheologyPowder FlowabilityRotating Drumhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Volume expansion of hydrogen absorbing materials, together with inter-particle friction can cause tension accumulation in hydride containers during absorption. When hydride particles absorb hydrogen there is an important volume increase, in the order of 25%. Particles have to accommodate to the container geometry but this movement is opposed by inter-particle friction. Under certain conditions tensions can build up, compromising the mechanical integrity of the container. This phenomenon needs to be addressed at the design stage to avoid mechanical failure of the container. Flow behavior of powder materials is a relevant technological field, usually addressed by means of qualitative or quantitative flowability measuring devices. The rotating drum technique, while mainly qualitative, is well established and can be modified into a completely sealed unit. To determine the flowability of a hydride under different activation stages and hydrogen content levels we developed a rotating drum device that can be pressurized with hydrogen or depressurized. We report particle size evolution and flowability measurements of a hydrogen absorbing material (LaNi5) at different stages of activation for both absorbed and desorbed states. The results of the present study show that the flowability of LaNi5 in more dependent on the degree of activation of the sample than on hydrogen absorption state.Fil: Melnichuk, Maximiliano. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; ArgentinaFil: Cuscueta, Diego Javier. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional de Cuyo; ArgentinaFil: Silin, Nicolas. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional de Cuyo; ArgentinaPergamon-Elsevier Science Ltd2017-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/57889Melnichuk, Maximiliano; Cuscueta, Diego Javier; Silin, Nicolas; LaNi5 hydride powder flowability as a function of activation and hydrogen content; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 42; 24; 6-2017; 15799-158070360-3199CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2017.02.164info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0360319917307346info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:48:38Zoai:ri.conicet.gov.ar:11336/57889instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:48:38.863CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv LaNi5 hydride powder flowability as a function of activation and hydrogen content
title LaNi5 hydride powder flowability as a function of activation and hydrogen content
spellingShingle LaNi5 hydride powder flowability as a function of activation and hydrogen content
Melnichuk, Maximiliano
Container Stress
Dynamic Angle of Repose
Hydride Rheology
Powder Flowability
Rotating Drum
title_short LaNi5 hydride powder flowability as a function of activation and hydrogen content
title_full LaNi5 hydride powder flowability as a function of activation and hydrogen content
title_fullStr LaNi5 hydride powder flowability as a function of activation and hydrogen content
title_full_unstemmed LaNi5 hydride powder flowability as a function of activation and hydrogen content
title_sort LaNi5 hydride powder flowability as a function of activation and hydrogen content
dc.creator.none.fl_str_mv Melnichuk, Maximiliano
Cuscueta, Diego Javier
Silin, Nicolas
author Melnichuk, Maximiliano
author_facet Melnichuk, Maximiliano
Cuscueta, Diego Javier
Silin, Nicolas
author_role author
author2 Cuscueta, Diego Javier
Silin, Nicolas
author2_role author
author
dc.subject.none.fl_str_mv Container Stress
Dynamic Angle of Repose
Hydride Rheology
Powder Flowability
Rotating Drum
topic Container Stress
Dynamic Angle of Repose
Hydride Rheology
Powder Flowability
Rotating Drum
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Volume expansion of hydrogen absorbing materials, together with inter-particle friction can cause tension accumulation in hydride containers during absorption. When hydride particles absorb hydrogen there is an important volume increase, in the order of 25%. Particles have to accommodate to the container geometry but this movement is opposed by inter-particle friction. Under certain conditions tensions can build up, compromising the mechanical integrity of the container. This phenomenon needs to be addressed at the design stage to avoid mechanical failure of the container. Flow behavior of powder materials is a relevant technological field, usually addressed by means of qualitative or quantitative flowability measuring devices. The rotating drum technique, while mainly qualitative, is well established and can be modified into a completely sealed unit. To determine the flowability of a hydride under different activation stages and hydrogen content levels we developed a rotating drum device that can be pressurized with hydrogen or depressurized. We report particle size evolution and flowability measurements of a hydrogen absorbing material (LaNi5) at different stages of activation for both absorbed and desorbed states. The results of the present study show that the flowability of LaNi5 in more dependent on the degree of activation of the sample than on hydrogen absorption state.
Fil: Melnichuk, Maximiliano. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentina
Fil: Cuscueta, Diego Javier. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional de Cuyo; Argentina
Fil: Silin, Nicolas. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina. Universidad Nacional de Cuyo; Argentina
description Volume expansion of hydrogen absorbing materials, together with inter-particle friction can cause tension accumulation in hydride containers during absorption. When hydride particles absorb hydrogen there is an important volume increase, in the order of 25%. Particles have to accommodate to the container geometry but this movement is opposed by inter-particle friction. Under certain conditions tensions can build up, compromising the mechanical integrity of the container. This phenomenon needs to be addressed at the design stage to avoid mechanical failure of the container. Flow behavior of powder materials is a relevant technological field, usually addressed by means of qualitative or quantitative flowability measuring devices. The rotating drum technique, while mainly qualitative, is well established and can be modified into a completely sealed unit. To determine the flowability of a hydride under different activation stages and hydrogen content levels we developed a rotating drum device that can be pressurized with hydrogen or depressurized. We report particle size evolution and flowability measurements of a hydrogen absorbing material (LaNi5) at different stages of activation for both absorbed and desorbed states. The results of the present study show that the flowability of LaNi5 in more dependent on the degree of activation of the sample than on hydrogen absorption state.
publishDate 2017
dc.date.none.fl_str_mv 2017-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/57889
Melnichuk, Maximiliano; Cuscueta, Diego Javier; Silin, Nicolas; LaNi5 hydride powder flowability as a function of activation and hydrogen content; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 42; 24; 6-2017; 15799-15807
0360-3199
CONICET Digital
CONICET
url http://hdl.handle.net/11336/57889
identifier_str_mv Melnichuk, Maximiliano; Cuscueta, Diego Javier; Silin, Nicolas; LaNi5 hydride powder flowability as a function of activation and hydrogen content; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 42; 24; 6-2017; 15799-15807
0360-3199
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijhydene.2017.02.164
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0360319917307346
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
publisher.none.fl_str_mv Pergamon-Elsevier Science Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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