Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur Batteries

Autores
Arias, Analía Natalí; Tesio, Alvaro Yamil; Flexer, Victoria
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Lithium-sulfur batteries are presented as a promising alternative for the operation of those devices, including electric vehicles,that require higher specific capacity than current lithium-ion technology. Unfortunately, lithium-sulfur batteries suffer from severallimitations that still produce a relatively fast capacity fading and poor utilization of active materials.In order to alleviate the disadvantages that arise at the cathode, several researchers have searched for new electrode materials. Becauseof the long standing tradition in the use of carbons in energy storage systems, carbonaceous cathodes have been the most popularchoice. Recently, however, there has been a trend for the study of non-carbonaceous materials as cathodes in lithium-sulfur systems.Materials such as polymers, metal oxides, metal carbides, amongst many others were reported, showing excellent properties whichmake them compete side by side with state of the art carbonaceous cathodes. Thesematerials have generally improved the conductivityof the conventional sulfur electrode, and have provided a 3D soft adsorbent porous structure, which efficiently traps polysulfides.These characteristics are reflected in an improved electrochemical performance, reaching, in some cases, capacity retention valuesclose to 1000 mA h g−1 after 100 cycles at high discharge rate. Here, we propose a review of these non-carbonaceous cathodes.
Fil: Arias, Analía Natalí. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; Argentina
Fil: Tesio, Alvaro Yamil. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; Argentina
Fil: Flexer, Victoria. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; Argentina
Materia
BATTERIES
LITHIUM
SULFUR
CATHODES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/101903
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/101903
network_acronym_str CONICETDig
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network_name_str CONICET Digital (CONICET)
spelling Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur BatteriesArias, Analía NatalíTesio, Alvaro YamilFlexer, VictoriaBATTERIESLITHIUMSULFURCATHODEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Lithium-sulfur batteries are presented as a promising alternative for the operation of those devices, including electric vehicles,that require higher specific capacity than current lithium-ion technology. Unfortunately, lithium-sulfur batteries suffer from severallimitations that still produce a relatively fast capacity fading and poor utilization of active materials.In order to alleviate the disadvantages that arise at the cathode, several researchers have searched for new electrode materials. Becauseof the long standing tradition in the use of carbons in energy storage systems, carbonaceous cathodes have been the most popularchoice. Recently, however, there has been a trend for the study of non-carbonaceous materials as cathodes in lithium-sulfur systems.Materials such as polymers, metal oxides, metal carbides, amongst many others were reported, showing excellent properties whichmake them compete side by side with state of the art carbonaceous cathodes. Thesematerials have generally improved the conductivityof the conventional sulfur electrode, and have provided a 3D soft adsorbent porous structure, which efficiently traps polysulfides.These characteristics are reflected in an improved electrochemical performance, reaching, in some cases, capacity retention valuesclose to 1000 mA h g−1 after 100 cycles at high discharge rate. Here, we propose a review of these non-carbonaceous cathodes.Fil: Arias, Analía Natalí. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; ArgentinaFil: Tesio, Alvaro Yamil. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; ArgentinaFil: Flexer, Victoria. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; ArgentinaElectrochemical Society2018-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/101903Arias, Analía Natalí; Tesio, Alvaro Yamil; Flexer, Victoria; Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur Batteries; Electrochemical Society; Journal of the Electrochemical Society; 165; 1-2018; 1-180013-4651CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1149/2.0181801jesinfo:eu-repo/semantics/altIdentifier/url/https://iopscience.iop.org/article/10.1149/2.0181801jesinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:45:19Zoai:ri.conicet.gov.ar:11336/101903instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:45:19.318CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur Batteries
title Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur Batteries
spellingShingle Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur Batteries
Arias, Analía Natalí
BATTERIES
LITHIUM
SULFUR
CATHODES
title_short Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur Batteries
title_full Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur Batteries
title_fullStr Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur Batteries
title_full_unstemmed Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur Batteries
title_sort Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur Batteries
dc.creator.none.fl_str_mv Arias, Analía Natalí
Tesio, Alvaro Yamil
Flexer, Victoria
author Arias, Analía Natalí
author_facet Arias, Analía Natalí
Tesio, Alvaro Yamil
Flexer, Victoria
author_role author
author2 Tesio, Alvaro Yamil
Flexer, Victoria
author2_role author
author
dc.subject.none.fl_str_mv BATTERIES
LITHIUM
SULFUR
CATHODES
topic BATTERIES
LITHIUM
SULFUR
CATHODES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Lithium-sulfur batteries are presented as a promising alternative for the operation of those devices, including electric vehicles,that require higher specific capacity than current lithium-ion technology. Unfortunately, lithium-sulfur batteries suffer from severallimitations that still produce a relatively fast capacity fading and poor utilization of active materials.In order to alleviate the disadvantages that arise at the cathode, several researchers have searched for new electrode materials. Becauseof the long standing tradition in the use of carbons in energy storage systems, carbonaceous cathodes have been the most popularchoice. Recently, however, there has been a trend for the study of non-carbonaceous materials as cathodes in lithium-sulfur systems.Materials such as polymers, metal oxides, metal carbides, amongst many others were reported, showing excellent properties whichmake them compete side by side with state of the art carbonaceous cathodes. Thesematerials have generally improved the conductivityof the conventional sulfur electrode, and have provided a 3D soft adsorbent porous structure, which efficiently traps polysulfides.These characteristics are reflected in an improved electrochemical performance, reaching, in some cases, capacity retention valuesclose to 1000 mA h g−1 after 100 cycles at high discharge rate. Here, we propose a review of these non-carbonaceous cathodes.
Fil: Arias, Analía Natalí. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; Argentina
Fil: Tesio, Alvaro Yamil. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; Argentina
Fil: Flexer, Victoria. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Universidad Nacional de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy. - Gobierno de la Provincia de Jujuy. Centro de Investigacion y Desarrollo En Materiales Avanzados y Almacenamiento de Energia de Jujuy; Argentina
description Lithium-sulfur batteries are presented as a promising alternative for the operation of those devices, including electric vehicles,that require higher specific capacity than current lithium-ion technology. Unfortunately, lithium-sulfur batteries suffer from severallimitations that still produce a relatively fast capacity fading and poor utilization of active materials.In order to alleviate the disadvantages that arise at the cathode, several researchers have searched for new electrode materials. Becauseof the long standing tradition in the use of carbons in energy storage systems, carbonaceous cathodes have been the most popularchoice. Recently, however, there has been a trend for the study of non-carbonaceous materials as cathodes in lithium-sulfur systems.Materials such as polymers, metal oxides, metal carbides, amongst many others were reported, showing excellent properties whichmake them compete side by side with state of the art carbonaceous cathodes. Thesematerials have generally improved the conductivityof the conventional sulfur electrode, and have provided a 3D soft adsorbent porous structure, which efficiently traps polysulfides.These characteristics are reflected in an improved electrochemical performance, reaching, in some cases, capacity retention valuesclose to 1000 mA h g−1 after 100 cycles at high discharge rate. Here, we propose a review of these non-carbonaceous cathodes.
publishDate 2018
dc.date.none.fl_str_mv 2018-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/101903
Arias, Analía Natalí; Tesio, Alvaro Yamil; Flexer, Victoria; Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur Batteries; Electrochemical Society; Journal of the Electrochemical Society; 165; 1-2018; 1-18
0013-4651
CONICET Digital
CONICET
url http://hdl.handle.net/11336/101903
identifier_str_mv Arias, Analía Natalí; Tesio, Alvaro Yamil; Flexer, Victoria; Review- Non-Carbonaceous Materials as Cathodes for Lithium-Sulfur Batteries; Electrochemical Society; Journal of the Electrochemical Society; 165; 1-2018; 1-18
0013-4651
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1149/2.0181801jes
info:eu-repo/semantics/altIdentifier/url/https://iopscience.iop.org/article/10.1149/2.0181801jes
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Electrochemical Society
publisher.none.fl_str_mv Electrochemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842268722551586816
score 13.13397

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