Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agent

Autores
Lopes, Christian Wittee; Villarroel Rocha, Jhonny; Silva, Bernardo Araldi Da; Mignoni, Marcelo Luis; Pergher, Sibele Berenice Castellã
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, the synthesis of zeolites using 1-butyl-3-methylimidazolium chloride [C4MI]Cl as a structure-directing agent was investigated. The organic cation shows effectiveness and selectivity for the syntheses of TON zeolites under different reaction conditions compared to the traditional structure-directing agent, 1,8-diaminooctane. The 1-butyl-3-methylimidazolium cation lead to highly crystalline materials and its role as OSDA in our synthesis conditions has been confirmed by characterization techniques. ICP-OES confirms the presence of Al in the samples and 27Al MAS NMR analysis indicated that aluminum atoms were incorporated in tetrahedral coordination. Scanning electron microscopy indicated that changing the crystallization condition (static or stirring), zeolites with different crystal size were obtained, which consequently affects the textural properties of the zeolites. Moreover, varying some synthesis parameters MFI zeolite can also be obtained.
Fil: Lopes, Christian Wittee. Universidade Federal do Rio Grande do Norte; Brasil
Fil: Villarroel Rocha, Jhonny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Silva, Bernardo Araldi Da. Universidade Regional Integrada; Brasil
Fil: Mignoni, Marcelo Luis. Universidade Regional Integrada; Brasil
Fil: Pergher, Sibele Berenice Castellã. Universidade Federal do Rio Grande do Norte; Brasil
Materia
1-BUTYL-3-METHYLIMIDAZOLIUM
TON ZEOLITE
ZEOLITE SYNTHESIS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/60600
Acceder
id CONICETDig_f638c602533fc574dbd538a9c604149f
oai_identifier_str oai:ri.conicet.gov.ar:11336/60600
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agentLopes, Christian WitteeVillarroel Rocha, JhonnySilva, Bernardo Araldi DaMignoni, Marcelo LuisPergher, Sibele Berenice Castellã1-BUTYL-3-METHYLIMIDAZOLIUMTON ZEOLITEZEOLITE SYNTHESIShttps://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this work, the synthesis of zeolites using 1-butyl-3-methylimidazolium chloride [C4MI]Cl as a structure-directing agent was investigated. The organic cation shows effectiveness and selectivity for the syntheses of TON zeolites under different reaction conditions compared to the traditional structure-directing agent, 1,8-diaminooctane. The 1-butyl-3-methylimidazolium cation lead to highly crystalline materials and its role as OSDA in our synthesis conditions has been confirmed by characterization techniques. ICP-OES confirms the presence of Al in the samples and 27Al MAS NMR analysis indicated that aluminum atoms were incorporated in tetrahedral coordination. Scanning electron microscopy indicated that changing the crystallization condition (static or stirring), zeolites with different crystal size were obtained, which consequently affects the textural properties of the zeolites. Moreover, varying some synthesis parameters MFI zeolite can also be obtained.Fil: Lopes, Christian Wittee. Universidade Federal do Rio Grande do Norte; BrasilFil: Villarroel Rocha, Jhonny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; ArgentinaFil: Silva, Bernardo Araldi Da. Universidade Regional Integrada; BrasilFil: Mignoni, Marcelo Luis. Universidade Regional Integrada; BrasilFil: Pergher, Sibele Berenice Castellã. Universidade Federal do Rio Grande do Norte; BrasilUniversidade Federal de São Carlos2016-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/60600Lopes, Christian Wittee; Villarroel Rocha, Jhonny; Silva, Bernardo Araldi Da; Mignoni, Marcelo Luis; Pergher, Sibele Berenice Castellã; Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agent; Universidade Federal de São Carlos; Materials Research; 19; 6; 11-2016; 1461-14681516-14391980-5373CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1590/1980-5373-mr-2016-0041info:eu-repo/semantics/altIdentifier/url/http://ref.scielo.org/tmz2x4info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:31:48Zoai:ri.conicet.gov.ar:11336/60600instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:31:48.874CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agent
title Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agent
spellingShingle Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agent
Lopes, Christian Wittee
1-BUTYL-3-METHYLIMIDAZOLIUM
TON ZEOLITE
ZEOLITE SYNTHESIS
title_short Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agent
title_full Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agent
title_fullStr Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agent
title_full_unstemmed Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agent
title_sort Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agent
dc.creator.none.fl_str_mv Lopes, Christian Wittee
Villarroel Rocha, Jhonny
Silva, Bernardo Araldi Da
Mignoni, Marcelo Luis
Pergher, Sibele Berenice Castellã
author Lopes, Christian Wittee
author_facet Lopes, Christian Wittee
Villarroel Rocha, Jhonny
Silva, Bernardo Araldi Da
Mignoni, Marcelo Luis
Pergher, Sibele Berenice Castellã
author_role author
author2 Villarroel Rocha, Jhonny
Silva, Bernardo Araldi Da
Mignoni, Marcelo Luis
Pergher, Sibele Berenice Castellã
author2_role author
author
author
author
dc.subject.none.fl_str_mv 1-BUTYL-3-METHYLIMIDAZOLIUM
TON ZEOLITE
ZEOLITE SYNTHESIS
topic 1-BUTYL-3-METHYLIMIDAZOLIUM
TON ZEOLITE
ZEOLITE SYNTHESIS
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.10
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work, the synthesis of zeolites using 1-butyl-3-methylimidazolium chloride [C4MI]Cl as a structure-directing agent was investigated. The organic cation shows effectiveness and selectivity for the syntheses of TON zeolites under different reaction conditions compared to the traditional structure-directing agent, 1,8-diaminooctane. The 1-butyl-3-methylimidazolium cation lead to highly crystalline materials and its role as OSDA in our synthesis conditions has been confirmed by characterization techniques. ICP-OES confirms the presence of Al in the samples and 27Al MAS NMR analysis indicated that aluminum atoms were incorporated in tetrahedral coordination. Scanning electron microscopy indicated that changing the crystallization condition (static or stirring), zeolites with different crystal size were obtained, which consequently affects the textural properties of the zeolites. Moreover, varying some synthesis parameters MFI zeolite can also be obtained.
Fil: Lopes, Christian Wittee. Universidade Federal do Rio Grande do Norte; Brasil
Fil: Villarroel Rocha, Jhonny. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
Fil: Silva, Bernardo Araldi Da. Universidade Regional Integrada; Brasil
Fil: Mignoni, Marcelo Luis. Universidade Regional Integrada; Brasil
Fil: Pergher, Sibele Berenice Castellã. Universidade Federal do Rio Grande do Norte; Brasil
description In this work, the synthesis of zeolites using 1-butyl-3-methylimidazolium chloride [C4MI]Cl as a structure-directing agent was investigated. The organic cation shows effectiveness and selectivity for the syntheses of TON zeolites under different reaction conditions compared to the traditional structure-directing agent, 1,8-diaminooctane. The 1-butyl-3-methylimidazolium cation lead to highly crystalline materials and its role as OSDA in our synthesis conditions has been confirmed by characterization techniques. ICP-OES confirms the presence of Al in the samples and 27Al MAS NMR analysis indicated that aluminum atoms were incorporated in tetrahedral coordination. Scanning electron microscopy indicated that changing the crystallization condition (static or stirring), zeolites with different crystal size were obtained, which consequently affects the textural properties of the zeolites. Moreover, varying some synthesis parameters MFI zeolite can also be obtained.
publishDate 2016
dc.date.none.fl_str_mv 2016-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/60600
Lopes, Christian Wittee; Villarroel Rocha, Jhonny; Silva, Bernardo Araldi Da; Mignoni, Marcelo Luis; Pergher, Sibele Berenice Castellã; Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agent; Universidade Federal de São Carlos; Materials Research; 19; 6; 11-2016; 1461-1468
1516-1439
1980-5373
CONICET Digital
CONICET
url http://hdl.handle.net/11336/60600
identifier_str_mv Lopes, Christian Wittee; Villarroel Rocha, Jhonny; Silva, Bernardo Araldi Da; Mignoni, Marcelo Luis; Pergher, Sibele Berenice Castellã; Synthesis and characterization of Al-TON zeolite using a Dialkylimizadolium as structure-directing agent; Universidade Federal de São Carlos; Materials Research; 19; 6; 11-2016; 1461-1468
1516-1439
1980-5373
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1590/1980-5373-mr-2016-0041
info:eu-repo/semantics/altIdentifier/url/http://ref.scielo.org/tmz2x4
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de São Carlos
publisher.none.fl_str_mv Universidade Federal de São Carlos
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083453013983232
score 13.22299

Publicaciones similares