Enhancement of synthesis of ZSM-11 zeolite by microwave irradiation

Autores
Azzolina Jury, Federico; Polaert, Isabelle; Estel, Lionel; Pierella, Liliana Beatriz
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A novel and complete description for ZSM-11 zeolite microwave-assisted synthesis is provided. The time required for the synthesis of ZSM-11 zeolite was remarkably reduced down to 3–4 days instead of 14 days under classical conditions, without the use of seed crystals and of any pretreatment step such as aging time. The crystallinity degree of ZSM-11 zeolites synthesized under microwave irradiation is considerably improved (39% higher) with respect to the crystallinity of conventional ZSM-11 zeolites. According to SEM images, the particle sizes of ZSM-11 zeolites synthesized by both methods are identical and a new morphology is observed when microwave irradiation is used. The surface area and microporous volume values for both synthesis methods are similar. In this work, the synthesis of ZSM-11 zeolite has been successfully intensified by using microwave irradiation. Energy consumption and synthesis time are considerably reduced.
Fil: Azzolina Jury, Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Institut National des Sciences Appliquées; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Polaert, Isabelle. Institut National des Sciences Appliquées; Francia
Fil: Estel, Lionel. Institut National des Sciences Appliquées; Francia
Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Zsm-11
Synthesis
Microwave
Characterization
Zeolites
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/34750
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/34750
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Enhancement of synthesis of ZSM-11 zeolite by microwave irradiationAzzolina Jury, FedericoPolaert, IsabelleEstel, LionelPierella, Liliana BeatrizZsm-11SynthesisMicrowaveCharacterizationZeoliteshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A novel and complete description for ZSM-11 zeolite microwave-assisted synthesis is provided. The time required for the synthesis of ZSM-11 zeolite was remarkably reduced down to 3–4 days instead of 14 days under classical conditions, without the use of seed crystals and of any pretreatment step such as aging time. The crystallinity degree of ZSM-11 zeolites synthesized under microwave irradiation is considerably improved (39% higher) with respect to the crystallinity of conventional ZSM-11 zeolites. According to SEM images, the particle sizes of ZSM-11 zeolites synthesized by both methods are identical and a new morphology is observed when microwave irradiation is used. The surface area and microporous volume values for both synthesis methods are similar. In this work, the synthesis of ZSM-11 zeolite has been successfully intensified by using microwave irradiation. Energy consumption and synthesis time are considerably reduced.Fil: Azzolina Jury, Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Institut National des Sciences Appliquées; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Polaert, Isabelle. Institut National des Sciences Appliquées; FranciaFil: Estel, Lionel. Institut National des Sciences Appliquées; FranciaFil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier Inc2014-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/34750Azzolina Jury, Federico; Polaert, Isabelle; Estel, Lionel; Pierella, Liliana Beatriz; Enhancement of synthesis of ZSM-11 zeolite by microwave irradiation; Elsevier Inc; Microporous and Mesoporous Materials; 198; 7-2014; 22-281387-1811CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2014.07.006info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1387181114003564info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:05:49Zoai:ri.conicet.gov.ar:11336/34750instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:05:49.842CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Enhancement of synthesis of ZSM-11 zeolite by microwave irradiation
title Enhancement of synthesis of ZSM-11 zeolite by microwave irradiation
spellingShingle Enhancement of synthesis of ZSM-11 zeolite by microwave irradiation
Azzolina Jury, Federico
Zsm-11
Synthesis
Microwave
Characterization
Zeolites
title_short Enhancement of synthesis of ZSM-11 zeolite by microwave irradiation
title_full Enhancement of synthesis of ZSM-11 zeolite by microwave irradiation
title_fullStr Enhancement of synthesis of ZSM-11 zeolite by microwave irradiation
title_full_unstemmed Enhancement of synthesis of ZSM-11 zeolite by microwave irradiation
title_sort Enhancement of synthesis of ZSM-11 zeolite by microwave irradiation
dc.creator.none.fl_str_mv Azzolina Jury, Federico
Polaert, Isabelle
Estel, Lionel
Pierella, Liliana Beatriz
author Azzolina Jury, Federico
author_facet Azzolina Jury, Federico
Polaert, Isabelle
Estel, Lionel
Pierella, Liliana Beatriz
author_role author
author2 Polaert, Isabelle
Estel, Lionel
Pierella, Liliana Beatriz
author2_role author
author
author
dc.subject.none.fl_str_mv Zsm-11
Synthesis
Microwave
Characterization
Zeolites
topic Zsm-11
Synthesis
Microwave
Characterization
Zeolites
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A novel and complete description for ZSM-11 zeolite microwave-assisted synthesis is provided. The time required for the synthesis of ZSM-11 zeolite was remarkably reduced down to 3–4 days instead of 14 days under classical conditions, without the use of seed crystals and of any pretreatment step such as aging time. The crystallinity degree of ZSM-11 zeolites synthesized under microwave irradiation is considerably improved (39% higher) with respect to the crystallinity of conventional ZSM-11 zeolites. According to SEM images, the particle sizes of ZSM-11 zeolites synthesized by both methods are identical and a new morphology is observed when microwave irradiation is used. The surface area and microporous volume values for both synthesis methods are similar. In this work, the synthesis of ZSM-11 zeolite has been successfully intensified by using microwave irradiation. Energy consumption and synthesis time are considerably reduced.
Fil: Azzolina Jury, Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Institut National des Sciences Appliquées; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Polaert, Isabelle. Institut National des Sciences Appliquées; Francia
Fil: Estel, Lionel. Institut National des Sciences Appliquées; Francia
Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description A novel and complete description for ZSM-11 zeolite microwave-assisted synthesis is provided. The time required for the synthesis of ZSM-11 zeolite was remarkably reduced down to 3–4 days instead of 14 days under classical conditions, without the use of seed crystals and of any pretreatment step such as aging time. The crystallinity degree of ZSM-11 zeolites synthesized under microwave irradiation is considerably improved (39% higher) with respect to the crystallinity of conventional ZSM-11 zeolites. According to SEM images, the particle sizes of ZSM-11 zeolites synthesized by both methods are identical and a new morphology is observed when microwave irradiation is used. The surface area and microporous volume values for both synthesis methods are similar. In this work, the synthesis of ZSM-11 zeolite has been successfully intensified by using microwave irradiation. Energy consumption and synthesis time are considerably reduced.
publishDate 2014
dc.date.none.fl_str_mv 2014-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/34750
Azzolina Jury, Federico; Polaert, Isabelle; Estel, Lionel; Pierella, Liliana Beatriz; Enhancement of synthesis of ZSM-11 zeolite by microwave irradiation; Elsevier Inc; Microporous and Mesoporous Materials; 198; 7-2014; 22-28
1387-1811
CONICET Digital
CONICET
url http://hdl.handle.net/11336/34750
identifier_str_mv Azzolina Jury, Federico; Polaert, Isabelle; Estel, Lionel; Pierella, Liliana Beatriz; Enhancement of synthesis of ZSM-11 zeolite by microwave irradiation; Elsevier Inc; Microporous and Mesoporous Materials; 198; 7-2014; 22-28
1387-1811
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.micromeso.2014.07.006
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1387181114003564
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Inc
publisher.none.fl_str_mv Elsevier Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613898866524160
score 13.070432

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