Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials

Autores
Tarutani, Naoki; Tokudome, Yasuaki; Jobbagy, Matias; Viva, Federico Andrés; Soler Illia, Galo Juan de Avila Arturo; Takahashi, Masahide
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A study demonstrated a simple synthesis approach toward single-nanometer-sized crystals that work as nanobuilding blocks (NBBs) to form a great variety of mesoporous hydroxides and derived phases. The nanocrystals with diverse chemical compositions low-valence metal hydroxides, α-M(OH)2 (M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II)), and other (hydr)oxides composed of Al(III), Cr(III), Fe(III), Zr(IV), and Sn(IV)) were prepared in an aqueous ethanol solution. The nanocrystal formation was achieved by inducing a high supersaturation via the epoxidemediated alkalinization in a concentrated metal salt solution. A variety of carboxylic acids were used as growth controlling agents, permitting to finely control the size of low-valence metal hydroxide nanocrystals and to attain high stability against aggregation.
Fil: Tarutani, Naoki. Osaka Prefecture University; Japón
Fil: Tokudome, Yasuaki. Osaka Prefecture University; Japón
Fil: Jobbagy, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Viva, Federico Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina
Fil: Takahashi, Masahide. Osaka Prefecture University; Japón
Materia
METAL OXIDES
LAYERED DOUBLE HYDROXIDE
MESOPOROUS MATERIAL
SUPERCAPACITOR
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/77953
Acceder
id CONICETDig_9a009f77e6f3024fa9810817321368b6
oai_identifier_str oai:ri.conicet.gov.ar:11336/77953
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous MaterialsTarutani, NaokiTokudome, YasuakiJobbagy, MatiasViva, Federico AndrésSoler Illia, Galo Juan de Avila ArturoTakahashi, MasahideMETAL OXIDESLAYERED DOUBLE HYDROXIDEMESOPOROUS MATERIALSUPERCAPACITORhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A study demonstrated a simple synthesis approach toward single-nanometer-sized crystals that work as nanobuilding blocks (NBBs) to form a great variety of mesoporous hydroxides and derived phases. The nanocrystals with diverse chemical compositions low-valence metal hydroxides, α-M(OH)2 (M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II)), and other (hydr)oxides composed of Al(III), Cr(III), Fe(III), Zr(IV), and Sn(IV)) were prepared in an aqueous ethanol solution. The nanocrystal formation was achieved by inducing a high supersaturation via the epoxidemediated alkalinization in a concentrated metal salt solution. A variety of carboxylic acids were used as growth controlling agents, permitting to finely control the size of low-valence metal hydroxide nanocrystals and to attain high stability against aggregation.Fil: Tarutani, Naoki. Osaka Prefecture University; JapónFil: Tokudome, Yasuaki. Osaka Prefecture University; JapónFil: Jobbagy, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Viva, Federico Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaFil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; ArgentinaFil: Takahashi, Masahide. Osaka Prefecture University; JapónAmerican Chemical Society2016-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/77953Tarutani, Naoki; Tokudome, Yasuaki; Jobbagy, Matias; Viva, Federico Andrés; Soler Illia, Galo Juan de Avila Arturo; et al.; Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials; American Chemical Society; Chemistry Of Materials; 28; 16; 12-2016; 5606-56100897-4756CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.chemmater.6b02510info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.chemmater.6b02510info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:32:26Zoai:ri.conicet.gov.ar:11336/77953instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:32:26.447CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials
title Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials
spellingShingle Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials
Tarutani, Naoki
METAL OXIDES
LAYERED DOUBLE HYDROXIDE
MESOPOROUS MATERIAL
SUPERCAPACITOR
title_short Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials
title_full Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials
title_fullStr Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials
title_full_unstemmed Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials
title_sort Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials
dc.creator.none.fl_str_mv Tarutani, Naoki
Tokudome, Yasuaki
Jobbagy, Matias
Viva, Federico Andrés
Soler Illia, Galo Juan de Avila Arturo
Takahashi, Masahide
author Tarutani, Naoki
author_facet Tarutani, Naoki
Tokudome, Yasuaki
Jobbagy, Matias
Viva, Federico Andrés
Soler Illia, Galo Juan de Avila Arturo
Takahashi, Masahide
author_role author
author2 Tokudome, Yasuaki
Jobbagy, Matias
Viva, Federico Andrés
Soler Illia, Galo Juan de Avila Arturo
Takahashi, Masahide
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv METAL OXIDES
LAYERED DOUBLE HYDROXIDE
MESOPOROUS MATERIAL
SUPERCAPACITOR
topic METAL OXIDES
LAYERED DOUBLE HYDROXIDE
MESOPOROUS MATERIAL
SUPERCAPACITOR
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A study demonstrated a simple synthesis approach toward single-nanometer-sized crystals that work as nanobuilding blocks (NBBs) to form a great variety of mesoporous hydroxides and derived phases. The nanocrystals with diverse chemical compositions low-valence metal hydroxides, α-M(OH)2 (M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II)), and other (hydr)oxides composed of Al(III), Cr(III), Fe(III), Zr(IV), and Sn(IV)) were prepared in an aqueous ethanol solution. The nanocrystal formation was achieved by inducing a high supersaturation via the epoxidemediated alkalinization in a concentrated metal salt solution. A variety of carboxylic acids were used as growth controlling agents, permitting to finely control the size of low-valence metal hydroxide nanocrystals and to attain high stability against aggregation.
Fil: Tarutani, Naoki. Osaka Prefecture University; Japón
Fil: Tokudome, Yasuaki. Osaka Prefecture University; Japón
Fil: Jobbagy, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Viva, Federico Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Soler Illia, Galo Juan de Avila Arturo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de San Martin. Instituto de Nanosistemas; Argentina
Fil: Takahashi, Masahide. Osaka Prefecture University; Japón
description A study demonstrated a simple synthesis approach toward single-nanometer-sized crystals that work as nanobuilding blocks (NBBs) to form a great variety of mesoporous hydroxides and derived phases. The nanocrystals with diverse chemical compositions low-valence metal hydroxides, α-M(OH)2 (M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II)), and other (hydr)oxides composed of Al(III), Cr(III), Fe(III), Zr(IV), and Sn(IV)) were prepared in an aqueous ethanol solution. The nanocrystal formation was achieved by inducing a high supersaturation via the epoxidemediated alkalinization in a concentrated metal salt solution. A variety of carboxylic acids were used as growth controlling agents, permitting to finely control the size of low-valence metal hydroxide nanocrystals and to attain high stability against aggregation.
publishDate 2016
dc.date.none.fl_str_mv 2016-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/77953
Tarutani, Naoki; Tokudome, Yasuaki; Jobbagy, Matias; Viva, Federico Andrés; Soler Illia, Galo Juan de Avila Arturo; et al.; Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials; American Chemical Society; Chemistry Of Materials; 28; 16; 12-2016; 5606-5610
0897-4756
CONICET Digital
CONICET
url http://hdl.handle.net/11336/77953
identifier_str_mv Tarutani, Naoki; Tokudome, Yasuaki; Jobbagy, Matias; Viva, Federico Andrés; Soler Illia, Galo Juan de Avila Arturo; et al.; Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials; American Chemical Society; Chemistry Of Materials; 28; 16; 12-2016; 5606-5610
0897-4756
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.chemmater.6b02510
info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.chemmater.6b02510
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614337838186496
score 13.070432

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