Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and cellulose

Autores
Cyras, Viviana Paola; Commisso, María Soledad; Mauri, Adriana Noemi; Vázquez, Analía
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A novel biocomposites double‐layer films using polyhydroxybutyrate (PHB) and cellulose paper were produced. The biocomposites were prepared by the solvent‐casting method (with chloroform). Films of the blends were characterized by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron micrograph (SEM), Fourier transform infrared spectroscopy (FTIR), X‐ray (XR) and surface roughness measurements. Moisture absorption, water absorption and water vapor permeation of films has been investigated. The PHB impregnated the fibers of cellulose paper and it was on the valley of paper structure. The double‐layer films showed diminutions in the moisture absorption, in the water abortion, in water vapor permeation and in surface roughness. According to contact angle, surface free energies and the barrier properties of the films can be considered more hydrophobic. The experimentally observed tensile properties (modulus and tensile strength) of double‐layer films with different content of PHB were determined. Measurements show the tensile strength and modulus of cellulose paper increases with the percentage of PHB. SEM photomicrographs of the fractured films surfaces were also analyzed. It was possible to obtain a biodegradable material with little amount of PHB to improve the barrier and the mechanical properties of cellulose paper, taking advantage of the good properties of both materials.
Fil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Commisso, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Mauri, Adriana Noemi. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina
Fil: Vázquez, Analía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Polyhydroxybutyrate
Cellulose
Biodegradable composites
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/111465
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/111465
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and celluloseCyras, Viviana PaolaCommisso, María SoledadMauri, Adriana NoemiVázquez, AnalíaPolyhydroxybutyrateCelluloseBiodegradable compositeshttps://purl.org/becyt/ford/2.11https://purl.org/becyt/ford/2A novel biocomposites double‐layer films using polyhydroxybutyrate (PHB) and cellulose paper were produced. The biocomposites were prepared by the solvent‐casting method (with chloroform). Films of the blends were characterized by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron micrograph (SEM), Fourier transform infrared spectroscopy (FTIR), X‐ray (XR) and surface roughness measurements. Moisture absorption, water absorption and water vapor permeation of films has been investigated. The PHB impregnated the fibers of cellulose paper and it was on the valley of paper structure. The double‐layer films showed diminutions in the moisture absorption, in the water abortion, in water vapor permeation and in surface roughness. According to contact angle, surface free energies and the barrier properties of the films can be considered more hydrophobic. The experimentally observed tensile properties (modulus and tensile strength) of double‐layer films with different content of PHB were determined. Measurements show the tensile strength and modulus of cellulose paper increases with the percentage of PHB. SEM photomicrographs of the fractured films surfaces were also analyzed. It was possible to obtain a biodegradable material with little amount of PHB to improve the barrier and the mechanical properties of cellulose paper, taking advantage of the good properties of both materials.Fil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Commisso, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Mauri, Adriana Noemi. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; ArgentinaFil: Vázquez, Analía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaJohn Wiley & Sons Inc2007-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/111465Cyras, Viviana Paola; Commisso, María Soledad; Mauri, Adriana Noemi; Vázquez, Analía; Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and cellulose; John Wiley & Sons Inc; Journal of Applied Polymer Science; 106; 2; 10-2007; 749-7560021-89951097-4628CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/app.26663info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/app.26663info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:49Zoai:ri.conicet.gov.ar:11336/111465instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:49.854CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and cellulose
title Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and cellulose
spellingShingle Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and cellulose
Cyras, Viviana Paola
Polyhydroxybutyrate
Cellulose
Biodegradable composites
title_short Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and cellulose
title_full Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and cellulose
title_fullStr Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and cellulose
title_full_unstemmed Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and cellulose
title_sort Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and cellulose
dc.creator.none.fl_str_mv Cyras, Viviana Paola
Commisso, María Soledad
Mauri, Adriana Noemi
Vázquez, Analía
author Cyras, Viviana Paola
author_facet Cyras, Viviana Paola
Commisso, María Soledad
Mauri, Adriana Noemi
Vázquez, Analía
author_role author
author2 Commisso, María Soledad
Mauri, Adriana Noemi
Vázquez, Analía
author2_role author
author
author
dc.subject.none.fl_str_mv Polyhydroxybutyrate
Cellulose
Biodegradable composites
topic Polyhydroxybutyrate
Cellulose
Biodegradable composites
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.11
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A novel biocomposites double‐layer films using polyhydroxybutyrate (PHB) and cellulose paper were produced. The biocomposites were prepared by the solvent‐casting method (with chloroform). Films of the blends were characterized by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron micrograph (SEM), Fourier transform infrared spectroscopy (FTIR), X‐ray (XR) and surface roughness measurements. Moisture absorption, water absorption and water vapor permeation of films has been investigated. The PHB impregnated the fibers of cellulose paper and it was on the valley of paper structure. The double‐layer films showed diminutions in the moisture absorption, in the water abortion, in water vapor permeation and in surface roughness. According to contact angle, surface free energies and the barrier properties of the films can be considered more hydrophobic. The experimentally observed tensile properties (modulus and tensile strength) of double‐layer films with different content of PHB were determined. Measurements show the tensile strength and modulus of cellulose paper increases with the percentage of PHB. SEM photomicrographs of the fractured films surfaces were also analyzed. It was possible to obtain a biodegradable material with little amount of PHB to improve the barrier and the mechanical properties of cellulose paper, taking advantage of the good properties of both materials.
Fil: Cyras, Viviana Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Commisso, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Mauri, Adriana Noemi. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina
Fil: Vázquez, Analía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description A novel biocomposites double‐layer films using polyhydroxybutyrate (PHB) and cellulose paper were produced. The biocomposites were prepared by the solvent‐casting method (with chloroform). Films of the blends were characterized by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron micrograph (SEM), Fourier transform infrared spectroscopy (FTIR), X‐ray (XR) and surface roughness measurements. Moisture absorption, water absorption and water vapor permeation of films has been investigated. The PHB impregnated the fibers of cellulose paper and it was on the valley of paper structure. The double‐layer films showed diminutions in the moisture absorption, in the water abortion, in water vapor permeation and in surface roughness. According to contact angle, surface free energies and the barrier properties of the films can be considered more hydrophobic. The experimentally observed tensile properties (modulus and tensile strength) of double‐layer films with different content of PHB were determined. Measurements show the tensile strength and modulus of cellulose paper increases with the percentage of PHB. SEM photomicrographs of the fractured films surfaces were also analyzed. It was possible to obtain a biodegradable material with little amount of PHB to improve the barrier and the mechanical properties of cellulose paper, taking advantage of the good properties of both materials.
publishDate 2007
dc.date.none.fl_str_mv 2007-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/111465
Cyras, Viviana Paola; Commisso, María Soledad; Mauri, Adriana Noemi; Vázquez, Analía; Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and cellulose; John Wiley & Sons Inc; Journal of Applied Polymer Science; 106; 2; 10-2007; 749-756
0021-8995
1097-4628
CONICET Digital
CONICET
url http://hdl.handle.net/11336/111465
identifier_str_mv Cyras, Viviana Paola; Commisso, María Soledad; Mauri, Adriana Noemi; Vázquez, Analía; Biodegradable double-layer films based on biological resources: Polyhydroxybutyrate and cellulose; John Wiley & Sons Inc; Journal of Applied Polymer Science; 106; 2; 10-2007; 749-756
0021-8995
1097-4628
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/app.26663
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/app.26663
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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