Effect of boron sources in the thermal behavior of a clay-based ceramics

Autores
Hernández, Maria Florencia; Lopez, Paula Virginia; Conconi, María Susana; Rendtorff Birrer, Nicolás Maximiliano
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Boron oxide sources as fluxing agents for clay-based materials have been a problem for the high solubility of these additives, however the dry milling-mixing-granulating route for clay based ceramics has been proposed and implemented with noticeable energetic advances. In the present study, the role of different boron oxide sources in the thermal behavior and sinterability of ceramic materials based on kaolinite clay was evaluated. Four boron sources were evaluated: Boric acid, borax, colemanite and ulexite. Four binary mixtures were made in a planetary mill to obtain uniform mixtures. For systematic comparison, the boron content added in all samples was 1 wt%. The thermal behavior evaluation of the mixtures was carried out by a multi-technique approach accompanied by textural, microstructural characterization complemented by a deep crystalline and non-crystalline phase evolution. Ulexite and borax presented the highest fluxing effect and colemanite has an even more moderate effect than boric acid. The observed microstructure was similar to other clay-based ceramics, with quartz grains, cristobalite and mullite embedded in the silica-based vitreous phase. The present study provides information for the additional design of clay-based materials with boron oxides as fluxing agents. The dry route alternative for using these agents was effective.
Fil: Hernández, Maria Florencia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
Fil: Lopez, Paula Virginia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
Fil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
Fil: Rendtorff Birrer, Nicolás Maximiliano. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
Materia
BORON SOURCES
CLAY BASED CERAMIC
DRY PROCESSING
PROCESSING AND PROPERTIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/210563
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effect of boron sources in the thermal behavior of a clay-based ceramicsHernández, Maria FlorenciaLopez, Paula VirginiaConconi, María SusanaRendtorff Birrer, Nicolás MaximilianoBORON SOURCESCLAY BASED CERAMICDRY PROCESSINGPROCESSING AND PROPERTIEShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Boron oxide sources as fluxing agents for clay-based materials have been a problem for the high solubility of these additives, however the dry milling-mixing-granulating route for clay based ceramics has been proposed and implemented with noticeable energetic advances. In the present study, the role of different boron oxide sources in the thermal behavior and sinterability of ceramic materials based on kaolinite clay was evaluated. Four boron sources were evaluated: Boric acid, borax, colemanite and ulexite. Four binary mixtures were made in a planetary mill to obtain uniform mixtures. For systematic comparison, the boron content added in all samples was 1 wt%. The thermal behavior evaluation of the mixtures was carried out by a multi-technique approach accompanied by textural, microstructural characterization complemented by a deep crystalline and non-crystalline phase evolution. Ulexite and borax presented the highest fluxing effect and colemanite has an even more moderate effect than boric acid. The observed microstructure was similar to other clay-based ceramics, with quartz grains, cristobalite and mullite embedded in the silica-based vitreous phase. The present study provides information for the additional design of clay-based materials with boron oxides as fluxing agents. The dry route alternative for using these agents was effective.Fil: Hernández, Maria Florencia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; ArgentinaFil: Lopez, Paula Virginia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; ArgentinaFil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; ArgentinaFil: Rendtorff Birrer, Nicolás Maximiliano. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; ArgentinaElsevier2022-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/210563Hernández, Maria Florencia; Lopez, Paula Virginia; Conconi, María Susana; Rendtorff Birrer, Nicolás Maximiliano; Effect of boron sources in the thermal behavior of a clay-based ceramics; Elsevier; Open Ceramics; 9; 3-2022; 1-92666-5395CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2666539522000104info:eu-repo/semantics/altIdentifier/doi/10.1016/j.oceram.2022.100227info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:51:24Zoai:ri.conicet.gov.ar:11336/210563instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:51:24.748CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effect of boron sources in the thermal behavior of a clay-based ceramics
title Effect of boron sources in the thermal behavior of a clay-based ceramics
spellingShingle Effect of boron sources in the thermal behavior of a clay-based ceramics
Hernández, Maria Florencia
BORON SOURCES
CLAY BASED CERAMIC
DRY PROCESSING
PROCESSING AND PROPERTIES
title_short Effect of boron sources in the thermal behavior of a clay-based ceramics
title_full Effect of boron sources in the thermal behavior of a clay-based ceramics
title_fullStr Effect of boron sources in the thermal behavior of a clay-based ceramics
title_full_unstemmed Effect of boron sources in the thermal behavior of a clay-based ceramics
title_sort Effect of boron sources in the thermal behavior of a clay-based ceramics
dc.creator.none.fl_str_mv Hernández, Maria Florencia
Lopez, Paula Virginia
Conconi, María Susana
Rendtorff Birrer, Nicolás Maximiliano
author Hernández, Maria Florencia
author_facet Hernández, Maria Florencia
Lopez, Paula Virginia
Conconi, María Susana
Rendtorff Birrer, Nicolás Maximiliano
author_role author
author2 Lopez, Paula Virginia
Conconi, María Susana
Rendtorff Birrer, Nicolás Maximiliano
author2_role author
author
author
dc.subject.none.fl_str_mv BORON SOURCES
CLAY BASED CERAMIC
DRY PROCESSING
PROCESSING AND PROPERTIES
topic BORON SOURCES
CLAY BASED CERAMIC
DRY PROCESSING
PROCESSING AND PROPERTIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Boron oxide sources as fluxing agents for clay-based materials have been a problem for the high solubility of these additives, however the dry milling-mixing-granulating route for clay based ceramics has been proposed and implemented with noticeable energetic advances. In the present study, the role of different boron oxide sources in the thermal behavior and sinterability of ceramic materials based on kaolinite clay was evaluated. Four boron sources were evaluated: Boric acid, borax, colemanite and ulexite. Four binary mixtures were made in a planetary mill to obtain uniform mixtures. For systematic comparison, the boron content added in all samples was 1 wt%. The thermal behavior evaluation of the mixtures was carried out by a multi-technique approach accompanied by textural, microstructural characterization complemented by a deep crystalline and non-crystalline phase evolution. Ulexite and borax presented the highest fluxing effect and colemanite has an even more moderate effect than boric acid. The observed microstructure was similar to other clay-based ceramics, with quartz grains, cristobalite and mullite embedded in the silica-based vitreous phase. The present study provides information for the additional design of clay-based materials with boron oxides as fluxing agents. The dry route alternative for using these agents was effective.
Fil: Hernández, Maria Florencia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
Fil: Lopez, Paula Virginia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
Fil: Conconi, María Susana. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
Fil: Rendtorff Birrer, Nicolás Maximiliano. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina
description Boron oxide sources as fluxing agents for clay-based materials have been a problem for the high solubility of these additives, however the dry milling-mixing-granulating route for clay based ceramics has been proposed and implemented with noticeable energetic advances. In the present study, the role of different boron oxide sources in the thermal behavior and sinterability of ceramic materials based on kaolinite clay was evaluated. Four boron sources were evaluated: Boric acid, borax, colemanite and ulexite. Four binary mixtures were made in a planetary mill to obtain uniform mixtures. For systematic comparison, the boron content added in all samples was 1 wt%. The thermal behavior evaluation of the mixtures was carried out by a multi-technique approach accompanied by textural, microstructural characterization complemented by a deep crystalline and non-crystalline phase evolution. Ulexite and borax presented the highest fluxing effect and colemanite has an even more moderate effect than boric acid. The observed microstructure was similar to other clay-based ceramics, with quartz grains, cristobalite and mullite embedded in the silica-based vitreous phase. The present study provides information for the additional design of clay-based materials with boron oxides as fluxing agents. The dry route alternative for using these agents was effective.
publishDate 2022
dc.date.none.fl_str_mv 2022-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/210563
Hernández, Maria Florencia; Lopez, Paula Virginia; Conconi, María Susana; Rendtorff Birrer, Nicolás Maximiliano; Effect of boron sources in the thermal behavior of a clay-based ceramics; Elsevier; Open Ceramics; 9; 3-2022; 1-9
2666-5395
CONICET Digital
CONICET
url http://hdl.handle.net/11336/210563
identifier_str_mv Hernández, Maria Florencia; Lopez, Paula Virginia; Conconi, María Susana; Rendtorff Birrer, Nicolás Maximiliano; Effect of boron sources in the thermal behavior of a clay-based ceramics; Elsevier; Open Ceramics; 9; 3-2022; 1-9
2666-5395
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S2666539522000104
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.oceram.2022.100227
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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