Relative importance of ozone energy transfer processes in the middle and upper atmosphere

Autores
Fernandez, Rafael Pedro; Kaufmann, Martin; Toselli, Beatriz Margarita
Año de publicación
2009
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The relative importance of different processes and transitions in the appearance of non-LTE populations for the fundamental levels of ozone was studied by quantifying the kinetic law of every process and transition that affect each level population. The vibrational temperatures and the relative contribution of every transition are presented as a function of altitude. The results show that the appearance of non-LTE populations for the fundamental levels is not produced by a direct imbalance between absorption and emission but as a consequence of imbalanced collisional transitions provoked by the overpopulation of O3(0 v2 0) levels. This fact confirms that the relaxation cascade drives through the bending mode ν2. © 2009 Elsevier Ltd. All rights reserved.
Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Kaufmann, Martin. Institute for Chemistry and Dynamics of the Geosphere; Alemania
Fil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
Collisional Vt Rate Constants
Non-Lte
Ozone Vibrational Temperatures
Vibrational Energy Transfer
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/72574
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/72574
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Relative importance of ozone energy transfer processes in the middle and upper atmosphereFernandez, Rafael PedroKaufmann, MartinToselli, Beatriz MargaritaCollisional Vt Rate ConstantsNon-LteOzone Vibrational TemperaturesVibrational Energy Transferhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The relative importance of different processes and transitions in the appearance of non-LTE populations for the fundamental levels of ozone was studied by quantifying the kinetic law of every process and transition that affect each level population. The vibrational temperatures and the relative contribution of every transition are presented as a function of altitude. The results show that the appearance of non-LTE populations for the fundamental levels is not produced by a direct imbalance between absorption and emission but as a consequence of imbalanced collisional transitions provoked by the overpopulation of O3(0 v2 0) levels. This fact confirms that the relaxation cascade drives through the bending mode ν2. © 2009 Elsevier Ltd. All rights reserved.Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Kaufmann, Martin. Institute for Chemistry and Dynamics of the Geosphere; AlemaniaFil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaElsevier2009-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/72574Fernandez, Rafael Pedro; Kaufmann, Martin; Toselli, Beatriz Margarita; Relative importance of ozone energy transfer processes in the middle and upper atmosphere; Elsevier; Journal of Atmospheric and Solar-Terrestrial Physics; 71; 8-9; 6-2009; 805-8151364-6826CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jastp.2009.03.004info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S1364682609000534info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:32:51Zoai:ri.conicet.gov.ar:11336/72574instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:32:51.542CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Relative importance of ozone energy transfer processes in the middle and upper atmosphere
title Relative importance of ozone energy transfer processes in the middle and upper atmosphere
spellingShingle Relative importance of ozone energy transfer processes in the middle and upper atmosphere
Fernandez, Rafael Pedro
Collisional Vt Rate Constants
Non-Lte
Ozone Vibrational Temperatures
Vibrational Energy Transfer
title_short Relative importance of ozone energy transfer processes in the middle and upper atmosphere
title_full Relative importance of ozone energy transfer processes in the middle and upper atmosphere
title_fullStr Relative importance of ozone energy transfer processes in the middle and upper atmosphere
title_full_unstemmed Relative importance of ozone energy transfer processes in the middle and upper atmosphere
title_sort Relative importance of ozone energy transfer processes in the middle and upper atmosphere
dc.creator.none.fl_str_mv Fernandez, Rafael Pedro
Kaufmann, Martin
Toselli, Beatriz Margarita
author Fernandez, Rafael Pedro
author_facet Fernandez, Rafael Pedro
Kaufmann, Martin
Toselli, Beatriz Margarita
author_role author
author2 Kaufmann, Martin
Toselli, Beatriz Margarita
author2_role author
author
dc.subject.none.fl_str_mv Collisional Vt Rate Constants
Non-Lte
Ozone Vibrational Temperatures
Vibrational Energy Transfer
topic Collisional Vt Rate Constants
Non-Lte
Ozone Vibrational Temperatures
Vibrational Energy Transfer
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The relative importance of different processes and transitions in the appearance of non-LTE populations for the fundamental levels of ozone was studied by quantifying the kinetic law of every process and transition that affect each level population. The vibrational temperatures and the relative contribution of every transition are presented as a function of altitude. The results show that the appearance of non-LTE populations for the fundamental levels is not produced by a direct imbalance between absorption and emission but as a consequence of imbalanced collisional transitions provoked by the overpopulation of O3(0 v2 0) levels. This fact confirms that the relaxation cascade drives through the bending mode ν2. © 2009 Elsevier Ltd. All rights reserved.
Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Kaufmann, Martin. Institute for Chemistry and Dynamics of the Geosphere; Alemania
Fil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description The relative importance of different processes and transitions in the appearance of non-LTE populations for the fundamental levels of ozone was studied by quantifying the kinetic law of every process and transition that affect each level population. The vibrational temperatures and the relative contribution of every transition are presented as a function of altitude. The results show that the appearance of non-LTE populations for the fundamental levels is not produced by a direct imbalance between absorption and emission but as a consequence of imbalanced collisional transitions provoked by the overpopulation of O3(0 v2 0) levels. This fact confirms that the relaxation cascade drives through the bending mode ν2. © 2009 Elsevier Ltd. All rights reserved.
publishDate 2009
dc.date.none.fl_str_mv 2009-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/72574
Fernandez, Rafael Pedro; Kaufmann, Martin; Toselli, Beatriz Margarita; Relative importance of ozone energy transfer processes in the middle and upper atmosphere; Elsevier; Journal of Atmospheric and Solar-Terrestrial Physics; 71; 8-9; 6-2009; 805-815
1364-6826
CONICET Digital
CONICET
url http://hdl.handle.net/11336/72574
identifier_str_mv Fernandez, Rafael Pedro; Kaufmann, Martin; Toselli, Beatriz Margarita; Relative importance of ozone energy transfer processes in the middle and upper atmosphere; Elsevier; Journal of Atmospheric and Solar-Terrestrial Physics; 71; 8-9; 6-2009; 805-815
1364-6826
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jastp.2009.03.004
info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S1364682609000534
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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