Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures

Autores
Fernandez, Rafael Pedro; Kaufmann, Martín; Toselli, Beatriz Margarita
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A description of the non-LTE intramolecular ozone relaxation cascade considering the relative importance of different transitions on the O3(v1v2v3) vibrational levels has been studied by quantifying the kinetic law of every process and transition that affect each level population. The analysis considers the inclusion for the first-time of bending-to-stretching (k2D) transitions in the energy relaxation cascade of ozone after it is formed by three-body recombination. In this way, the vibrational temperatures and the relative contribution of every transition are presented as a function of altitude. The results show that the inclusion of the bending-to-stretching transitions in the O3 non-LTE relaxation scheme decreases the ν2-mode overpopulation and therefore the stretching levels' population increases, as required for a correct radiance simulation of the 4.8γm ozone emission in the upper atmosphere.
Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Kaufmann, Martín. Research Center Julich, Institute for Chemistry and Dynamics of the Geosphere; Alemania
Fil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Materia
Bending-To-Stretching K2d Transitions
Collisional Kvt Rate Constants
Ozone Non-Lte
Ssh Theory
Vibrational Energy Transfer
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/69740

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network_name_str CONICET Digital (CONICET)
spelling Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperaturesFernandez, Rafael PedroKaufmann, MartínToselli, Beatriz MargaritaBending-To-Stretching K2d TransitionsCollisional Kvt Rate ConstantsOzone Non-LteSsh TheoryVibrational Energy Transferhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A description of the non-LTE intramolecular ozone relaxation cascade considering the relative importance of different transitions on the O3(v1v2v3) vibrational levels has been studied by quantifying the kinetic law of every process and transition that affect each level population. The analysis considers the inclusion for the first-time of bending-to-stretching (k2D) transitions in the energy relaxation cascade of ozone after it is formed by three-body recombination. In this way, the vibrational temperatures and the relative contribution of every transition are presented as a function of altitude. The results show that the inclusion of the bending-to-stretching transitions in the O3 non-LTE relaxation scheme decreases the ν2-mode overpopulation and therefore the stretching levels' population increases, as required for a correct radiance simulation of the 4.8γm ozone emission in the upper atmosphere.Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Kaufmann, Martín. Research Center Julich, Institute for Chemistry and Dynamics of the Geosphere; AlemaniaFil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaElsevier2010-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/69740Fernandez, Rafael Pedro; Kaufmann, Martín; Toselli, Beatriz Margarita; Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures; Elsevier; Journal of Atmospheric and Solar-Terrestrial Physics; 72; 11-12; 7-2010; 890-8991364-6826CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jastp.2010.05.005info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1364682610001483info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:26:46Zoai:ri.conicet.gov.ar:11336/69740instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:26:46.886CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures
title Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures
spellingShingle Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures
Fernandez, Rafael Pedro
Bending-To-Stretching K2d Transitions
Collisional Kvt Rate Constants
Ozone Non-Lte
Ssh Theory
Vibrational Energy Transfer
title_short Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures
title_full Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures
title_fullStr Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures
title_full_unstemmed Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures
title_sort Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures
dc.creator.none.fl_str_mv Fernandez, Rafael Pedro
Kaufmann, Martín
Toselli, Beatriz Margarita
author Fernandez, Rafael Pedro
author_facet Fernandez, Rafael Pedro
Kaufmann, Martín
Toselli, Beatriz Margarita
author_role author
author2 Kaufmann, Martín
Toselli, Beatriz Margarita
author2_role author
author
dc.subject.none.fl_str_mv Bending-To-Stretching K2d Transitions
Collisional Kvt Rate Constants
Ozone Non-Lte
Ssh Theory
Vibrational Energy Transfer
topic Bending-To-Stretching K2d Transitions
Collisional Kvt Rate Constants
Ozone Non-Lte
Ssh Theory
Vibrational Energy Transfer
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A description of the non-LTE intramolecular ozone relaxation cascade considering the relative importance of different transitions on the O3(v1v2v3) vibrational levels has been studied by quantifying the kinetic law of every process and transition that affect each level population. The analysis considers the inclusion for the first-time of bending-to-stretching (k2D) transitions in the energy relaxation cascade of ozone after it is formed by three-body recombination. In this way, the vibrational temperatures and the relative contribution of every transition are presented as a function of altitude. The results show that the inclusion of the bending-to-stretching transitions in the O3 non-LTE relaxation scheme decreases the ν2-mode overpopulation and therefore the stretching levels' population increases, as required for a correct radiance simulation of the 4.8γm ozone emission in the upper atmosphere.
Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Kaufmann, Martín. Research Center Julich, Institute for Chemistry and Dynamics of the Geosphere; Alemania
Fil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
description A description of the non-LTE intramolecular ozone relaxation cascade considering the relative importance of different transitions on the O3(v1v2v3) vibrational levels has been studied by quantifying the kinetic law of every process and transition that affect each level population. The analysis considers the inclusion for the first-time of bending-to-stretching (k2D) transitions in the energy relaxation cascade of ozone after it is formed by three-body recombination. In this way, the vibrational temperatures and the relative contribution of every transition are presented as a function of altitude. The results show that the inclusion of the bending-to-stretching transitions in the O3 non-LTE relaxation scheme decreases the ν2-mode overpopulation and therefore the stretching levels' population increases, as required for a correct radiance simulation of the 4.8γm ozone emission in the upper atmosphere.
publishDate 2010
dc.date.none.fl_str_mv 2010-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/69740
Fernandez, Rafael Pedro; Kaufmann, Martín; Toselli, Beatriz Margarita; Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures; Elsevier; Journal of Atmospheric and Solar-Terrestrial Physics; 72; 11-12; 7-2010; 890-899
1364-6826
CONICET Digital
CONICET
url http://hdl.handle.net/11336/69740
identifier_str_mv Fernandez, Rafael Pedro; Kaufmann, Martín; Toselli, Beatriz Margarita; Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures; Elsevier; Journal of Atmospheric and Solar-Terrestrial Physics; 72; 11-12; 7-2010; 890-899
1364-6826
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jastp.2010.05.005
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1364682610001483
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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