Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures
- Autores
- Fernandez, Rafael Pedro; Kaufmann, Martín; Toselli, Beatriz Margarita
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A description of the non-LTE intramolecular ozone relaxation cascade considering the relative importance of different transitions on the O3(v1v2v3) vibrational levels has been studied by quantifying the kinetic law of every process and transition that affect each level population. The analysis considers the inclusion for the first-time of bending-to-stretching (k2D) transitions in the energy relaxation cascade of ozone after it is formed by three-body recombination. In this way, the vibrational temperatures and the relative contribution of every transition are presented as a function of altitude. The results show that the inclusion of the bending-to-stretching transitions in the O3 non-LTE relaxation scheme decreases the ν2-mode overpopulation and therefore the stretching levels' population increases, as required for a correct radiance simulation of the 4.8γm ozone emission in the upper atmosphere.
Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Kaufmann, Martín. Research Center Julich, Institute for Chemistry and Dynamics of the Geosphere; Alemania
Fil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina - Materia
-
Bending-To-Stretching K2d Transitions
Collisional Kvt Rate Constants
Ozone Non-Lte
Ssh Theory
Vibrational Energy Transfer - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/69740
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Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperaturesFernandez, Rafael PedroKaufmann, MartínToselli, Beatriz MargaritaBending-To-Stretching K2d TransitionsCollisional Kvt Rate ConstantsOzone Non-LteSsh TheoryVibrational Energy Transferhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A description of the non-LTE intramolecular ozone relaxation cascade considering the relative importance of different transitions on the O3(v1v2v3) vibrational levels has been studied by quantifying the kinetic law of every process and transition that affect each level population. The analysis considers the inclusion for the first-time of bending-to-stretching (k2D) transitions in the energy relaxation cascade of ozone after it is formed by three-body recombination. In this way, the vibrational temperatures and the relative contribution of every transition are presented as a function of altitude. The results show that the inclusion of the bending-to-stretching transitions in the O3 non-LTE relaxation scheme decreases the ν2-mode overpopulation and therefore the stretching levels' population increases, as required for a correct radiance simulation of the 4.8γm ozone emission in the upper atmosphere.Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Kaufmann, Martín. Research Center Julich, Institute for Chemistry and Dynamics of the Geosphere; AlemaniaFil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaElsevier2010-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/69740Fernandez, Rafael Pedro; Kaufmann, Martín; Toselli, Beatriz Margarita; Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures; Elsevier; Journal of Atmospheric and Solar-Terrestrial Physics; 72; 11-12; 7-2010; 890-8991364-6826CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jastp.2010.05.005info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1364682610001483info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:26:46Zoai:ri.conicet.gov.ar:11336/69740instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:26:46.886CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures |
title |
Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures |
spellingShingle |
Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures Fernandez, Rafael Pedro Bending-To-Stretching K2d Transitions Collisional Kvt Rate Constants Ozone Non-Lte Ssh Theory Vibrational Energy Transfer |
title_short |
Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures |
title_full |
Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures |
title_fullStr |
Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures |
title_full_unstemmed |
Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures |
title_sort |
Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures |
dc.creator.none.fl_str_mv |
Fernandez, Rafael Pedro Kaufmann, Martín Toselli, Beatriz Margarita |
author |
Fernandez, Rafael Pedro |
author_facet |
Fernandez, Rafael Pedro Kaufmann, Martín Toselli, Beatriz Margarita |
author_role |
author |
author2 |
Kaufmann, Martín Toselli, Beatriz Margarita |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Bending-To-Stretching K2d Transitions Collisional Kvt Rate Constants Ozone Non-Lte Ssh Theory Vibrational Energy Transfer |
topic |
Bending-To-Stretching K2d Transitions Collisional Kvt Rate Constants Ozone Non-Lte Ssh Theory Vibrational Energy Transfer |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
A description of the non-LTE intramolecular ozone relaxation cascade considering the relative importance of different transitions on the O3(v1v2v3) vibrational levels has been studied by quantifying the kinetic law of every process and transition that affect each level population. The analysis considers the inclusion for the first-time of bending-to-stretching (k2D) transitions in the energy relaxation cascade of ozone after it is formed by three-body recombination. In this way, the vibrational temperatures and the relative contribution of every transition are presented as a function of altitude. The results show that the inclusion of the bending-to-stretching transitions in the O3 non-LTE relaxation scheme decreases the ν2-mode overpopulation and therefore the stretching levels' population increases, as required for a correct radiance simulation of the 4.8γm ozone emission in the upper atmosphere. Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Kaufmann, Martín. Research Center Julich, Institute for Chemistry and Dynamics of the Geosphere; Alemania Fil: Toselli, Beatriz Margarita. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina |
description |
A description of the non-LTE intramolecular ozone relaxation cascade considering the relative importance of different transitions on the O3(v1v2v3) vibrational levels has been studied by quantifying the kinetic law of every process and transition that affect each level population. The analysis considers the inclusion for the first-time of bending-to-stretching (k2D) transitions in the energy relaxation cascade of ozone after it is formed by three-body recombination. In this way, the vibrational temperatures and the relative contribution of every transition are presented as a function of altitude. The results show that the inclusion of the bending-to-stretching transitions in the O3 non-LTE relaxation scheme decreases the ν2-mode overpopulation and therefore the stretching levels' population increases, as required for a correct radiance simulation of the 4.8γm ozone emission in the upper atmosphere. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-07 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/69740 Fernandez, Rafael Pedro; Kaufmann, Martín; Toselli, Beatriz Margarita; Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures; Elsevier; Journal of Atmospheric and Solar-Terrestrial Physics; 72; 11-12; 7-2010; 890-899 1364-6826 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/69740 |
identifier_str_mv |
Fernandez, Rafael Pedro; Kaufmann, Martín; Toselli, Beatriz Margarita; Effects of the inclusion of bending-to-stretching transitions in the non-LTE modeling of ozone vibrational temperatures; Elsevier; Journal of Atmospheric and Solar-Terrestrial Physics; 72; 11-12; 7-2010; 890-899 1364-6826 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jastp.2010.05.005 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S1364682610001483 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614269136535552 |
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13.070432 |