Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption process

Autores
Pila, Matías Nicolás; Colasurdo, Diego Damián; Simonetti, Sandra Isabel; Dodero, Gabriela Alejandra; Allegretti, Patricia Ercilia; Ruiz, Danila Luján; Laurella, Sergio Luis
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Two carbonaceous adsorbents CAT and CARBOPAL were tested for reducing the concentration of the three herbicides in water: 2,4-D (2,4-dichlorophenoxyacetic acid), TCP (2,4,6-trichlorophenol) and metolachlor. Textural and chemical characterization of the adsorbents include nitrogen isotherms, FTIR, titration and thermogravimetric analyses. Adsorption was studied in discontinuous adsorption experiments at different pH values. The experimental adsorption isotherms data were fitted to four theoretical models. Adsorbent characterization reveals that CAT has higher micropore area, lower pore diameter and lower acidity than CARBOPAL. The adsorption is a second-order process and the isotherms best fitted to Sips model. The efficiency of the process depends mainly on the charge of the adsorbate for TCP and 2,4-D, but it depends on the charge of the surface for metolachlor. Adsorption capacity is higher on CAT for 2,4-D and TCP (small molecules), and it is higher on CARBOPAL for metolachlor (large molecules). Theoretical calculations clearly support this assumption.
Fil: Pila, Matías Nicolás. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina
Fil: Colasurdo, Diego Damián. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina
Fil: Simonetti, Sandra Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
Fil: Dodero, Gabriela Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
Fil: Allegretti, Patricia Ercilia. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Fil: Ruiz, Danila Luján. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina
Fil: Laurella, Sergio Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Materia
2
4-D
ACTIVATED CARBON
ADSORPTION
METOLACHLOR
TRICHLOROPHENOL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/221991
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption processPila, Matías NicolásColasurdo, Diego DamiánSimonetti, Sandra IsabelDodero, Gabriela AlejandraAllegretti, Patricia ErciliaRuiz, Danila LujánLaurella, Sergio Luis24-DACTIVATED CARBONADSORPTIONMETOLACHLORTRICHLOROPHENOLhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Two carbonaceous adsorbents CAT and CARBOPAL were tested for reducing the concentration of the three herbicides in water: 2,4-D (2,4-dichlorophenoxyacetic acid), TCP (2,4,6-trichlorophenol) and metolachlor. Textural and chemical characterization of the adsorbents include nitrogen isotherms, FTIR, titration and thermogravimetric analyses. Adsorption was studied in discontinuous adsorption experiments at different pH values. The experimental adsorption isotherms data were fitted to four theoretical models. Adsorbent characterization reveals that CAT has higher micropore area, lower pore diameter and lower acidity than CARBOPAL. The adsorption is a second-order process and the isotherms best fitted to Sips model. The efficiency of the process depends mainly on the charge of the adsorbate for TCP and 2,4-D, but it depends on the charge of the surface for metolachlor. Adsorption capacity is higher on CAT for 2,4-D and TCP (small molecules), and it is higher on CARBOPAL for metolachlor (large molecules). Theoretical calculations clearly support this assumption.Fil: Pila, Matías Nicolás. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; ArgentinaFil: Colasurdo, Diego Damián. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; ArgentinaFil: Simonetti, Sandra Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; ArgentinaFil: Dodero, Gabriela Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; ArgentinaFil: Allegretti, Patricia Ercilia. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; ArgentinaFil: Ruiz, Danila Luján. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; ArgentinaFil: Laurella, Sergio Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaKorean Institute of Chemical Engineers2023-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/221991Pila, Matías Nicolás; Colasurdo, Diego Damián; Simonetti, Sandra Isabel; Dodero, Gabriela Alejandra; Allegretti, Patricia Ercilia; et al.; Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption process; Korean Institute of Chemical Engineers; Korean Chemical Engineering Research; 61; 1; 2-2023; 97-1080304-128X2233-9558CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.9713/kcer.2023.61.1.97info:eu-repo/semantics/altIdentifier/url/http://koreascience.or.kr/article/JAKO202311772002706.pageinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:38:01Zoai:ri.conicet.gov.ar:11336/221991instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:38:02.227CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption process
title Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption process
spellingShingle Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption process
Pila, Matías Nicolás
2
4-D
ACTIVATED CARBON
ADSORPTION
METOLACHLOR
TRICHLOROPHENOL
title_short Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption process
title_full Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption process
title_fullStr Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption process
title_full_unstemmed Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption process
title_sort Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption process
dc.creator.none.fl_str_mv Pila, Matías Nicolás
Colasurdo, Diego Damián
Simonetti, Sandra Isabel
Dodero, Gabriela Alejandra
Allegretti, Patricia Ercilia
Ruiz, Danila Luján
Laurella, Sergio Luis
author Pila, Matías Nicolás
author_facet Pila, Matías Nicolás
Colasurdo, Diego Damián
Simonetti, Sandra Isabel
Dodero, Gabriela Alejandra
Allegretti, Patricia Ercilia
Ruiz, Danila Luján
Laurella, Sergio Luis
author_role author
author2 Colasurdo, Diego Damián
Simonetti, Sandra Isabel
Dodero, Gabriela Alejandra
Allegretti, Patricia Ercilia
Ruiz, Danila Luján
Laurella, Sergio Luis
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv 2
4-D
ACTIVATED CARBON
ADSORPTION
METOLACHLOR
TRICHLOROPHENOL
topic 2
4-D
ACTIVATED CARBON
ADSORPTION
METOLACHLOR
TRICHLOROPHENOL
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Two carbonaceous adsorbents CAT and CARBOPAL were tested for reducing the concentration of the three herbicides in water: 2,4-D (2,4-dichlorophenoxyacetic acid), TCP (2,4,6-trichlorophenol) and metolachlor. Textural and chemical characterization of the adsorbents include nitrogen isotherms, FTIR, titration and thermogravimetric analyses. Adsorption was studied in discontinuous adsorption experiments at different pH values. The experimental adsorption isotherms data were fitted to four theoretical models. Adsorbent characterization reveals that CAT has higher micropore area, lower pore diameter and lower acidity than CARBOPAL. The adsorption is a second-order process and the isotherms best fitted to Sips model. The efficiency of the process depends mainly on the charge of the adsorbate for TCP and 2,4-D, but it depends on the charge of the surface for metolachlor. Adsorption capacity is higher on CAT for 2,4-D and TCP (small molecules), and it is higher on CARBOPAL for metolachlor (large molecules). Theoretical calculations clearly support this assumption.
Fil: Pila, Matías Nicolás. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina
Fil: Colasurdo, Diego Damián. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina
Fil: Simonetti, Sandra Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
Fil: Dodero, Gabriela Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Física del Sur. Universidad Nacional del Sur. Departamento de Física. Instituto de Física del Sur; Argentina
Fil: Allegretti, Patricia Ercilia. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina
Fil: Ruiz, Danila Luján. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina
Fil: Laurella, Sergio Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
description Two carbonaceous adsorbents CAT and CARBOPAL were tested for reducing the concentration of the three herbicides in water: 2,4-D (2,4-dichlorophenoxyacetic acid), TCP (2,4,6-trichlorophenol) and metolachlor. Textural and chemical characterization of the adsorbents include nitrogen isotherms, FTIR, titration and thermogravimetric analyses. Adsorption was studied in discontinuous adsorption experiments at different pH values. The experimental adsorption isotherms data were fitted to four theoretical models. Adsorbent characterization reveals that CAT has higher micropore area, lower pore diameter and lower acidity than CARBOPAL. The adsorption is a second-order process and the isotherms best fitted to Sips model. The efficiency of the process depends mainly on the charge of the adsorbate for TCP and 2,4-D, but it depends on the charge of the surface for metolachlor. Adsorption capacity is higher on CAT for 2,4-D and TCP (small molecules), and it is higher on CARBOPAL for metolachlor (large molecules). Theoretical calculations clearly support this assumption.
publishDate 2023
dc.date.none.fl_str_mv 2023-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/221991
Pila, Matías Nicolás; Colasurdo, Diego Damián; Simonetti, Sandra Isabel; Dodero, Gabriela Alejandra; Allegretti, Patricia Ercilia; et al.; Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption process; Korean Institute of Chemical Engineers; Korean Chemical Engineering Research; 61; 1; 2-2023; 97-108
0304-128X
2233-9558
CONICET Digital
CONICET
url http://hdl.handle.net/11336/221991
identifier_str_mv Pila, Matías Nicolás; Colasurdo, Diego Damián; Simonetti, Sandra Isabel; Dodero, Gabriela Alejandra; Allegretti, Patricia Ercilia; et al.; Adsorption of three chlorinated herbicides on two activated carbons: an example of the effect of surface charge, pore diameter and molecular size on the adsorption process; Korean Institute of Chemical Engineers; Korean Chemical Engineering Research; 61; 1; 2-2023; 97-108
0304-128X
2233-9558
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.9713/kcer.2023.61.1.97
info:eu-repo/semantics/altIdentifier/url/http://koreascience.or.kr/article/JAKO202311772002706.page
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Korean Institute of Chemical Engineers
publisher.none.fl_str_mv Korean Institute of Chemical Engineers
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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