Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321

Autores
Colasurdo, Diego Damián; Carreras, Javier Gonzalo; Laurella, Sergio Luis
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A recent study on adsorption of metolachlor on activated carbons carried out by Gomis-Berenguer et al.has reported higher adsorption capacity for pure S-metolachlor compared with the adsorption capacityfor the racemic mixture of this pesticide. The authors claim that the adsorption is enantioselective, withthe activated carbon being more efficient for the adsorption of the S enantiomer compared with the Renantiomer. In this comment, we question this explanation (since the non-chiral surface of an activatedcarbon would never be selective towards one enantiomer instead of the other) and we offer somepossible answers supported by theoretical calculations.
Fil: Colasurdo, Diego Damián. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina
Fil: Carreras, Javier Gonzalo. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina
Fil: Laurella, Sergio Luis. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina
Materia
Metolachlor
Adsorción
Carbón
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/271596
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321Colasurdo, Diego DamiánCarreras, Javier GonzaloLaurella, Sergio LuisMetolachlorAdsorciónCarbónhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A recent study on adsorption of metolachlor on activated carbons carried out by Gomis-Berenguer et al.has reported higher adsorption capacity for pure S-metolachlor compared with the adsorption capacityfor the racemic mixture of this pesticide. The authors claim that the adsorption is enantioselective, withthe activated carbon being more efficient for the adsorption of the S enantiomer compared with the Renantiomer. In this comment, we question this explanation (since the non-chiral surface of an activatedcarbon would never be selective towards one enantiomer instead of the other) and we offer somepossible answers supported by theoretical calculations.Fil: Colasurdo, Diego Damián. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; ArgentinaFil: Carreras, Javier Gonzalo. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; ArgentinaFil: Laurella, Sergio Luis. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; ArgentinaRoyal Society of Chemistry2023-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/271596Colasurdo, Diego Damián; Carreras, Javier Gonzalo; Laurella, Sergio Luis; Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321; Royal Society of Chemistry; RSC Advances; 13; 15; 3-2023; 10349-103522046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://xlink.rsc.org/?DOI=D3RA00363Ainfo:eu-repo/semantics/altIdentifier/doi/10.1039/D3RA00363Ainfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:54:02Zoai:ri.conicet.gov.ar:11336/271596instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:54:02.555CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321
title Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321
spellingShingle Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321
Colasurdo, Diego Damián
Metolachlor
Adsorción
Carbón
title_short Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321
title_full Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321
title_fullStr Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321
title_full_unstemmed Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321
title_sort Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321
dc.creator.none.fl_str_mv Colasurdo, Diego Damián
Carreras, Javier Gonzalo
Laurella, Sergio Luis
author Colasurdo, Diego Damián
author_facet Colasurdo, Diego Damián
Carreras, Javier Gonzalo
Laurella, Sergio Luis
author_role author
author2 Carreras, Javier Gonzalo
Laurella, Sergio Luis
author2_role author
author
dc.subject.none.fl_str_mv Metolachlor
Adsorción
Carbón
topic Metolachlor
Adsorción
Carbón
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A recent study on adsorption of metolachlor on activated carbons carried out by Gomis-Berenguer et al.has reported higher adsorption capacity for pure S-metolachlor compared with the adsorption capacityfor the racemic mixture of this pesticide. The authors claim that the adsorption is enantioselective, withthe activated carbon being more efficient for the adsorption of the S enantiomer compared with the Renantiomer. In this comment, we question this explanation (since the non-chiral surface of an activatedcarbon would never be selective towards one enantiomer instead of the other) and we offer somepossible answers supported by theoretical calculations.
Fil: Colasurdo, Diego Damián. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina
Fil: Carreras, Javier Gonzalo. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química. Laboratorio de Estudio de Compuestos Orgánicos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina
Fil: Laurella, Sergio Luis. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata; Argentina
description A recent study on adsorption of metolachlor on activated carbons carried out by Gomis-Berenguer et al.has reported higher adsorption capacity for pure S-metolachlor compared with the adsorption capacityfor the racemic mixture of this pesticide. The authors claim that the adsorption is enantioselective, withthe activated carbon being more efficient for the adsorption of the S enantiomer compared with the Renantiomer. In this comment, we question this explanation (since the non-chiral surface of an activatedcarbon would never be selective towards one enantiomer instead of the other) and we offer somepossible answers supported by theoretical calculations.
publishDate 2023
dc.date.none.fl_str_mv 2023-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/271596
Colasurdo, Diego Damián; Carreras, Javier Gonzalo; Laurella, Sergio Luis; Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321; Royal Society of Chemistry; RSC Advances; 13; 15; 3-2023; 10349-10352
2046-2069
CONICET Digital
CONICET
url http://hdl.handle.net/11336/271596
identifier_str_mv Colasurdo, Diego Damián; Carreras, Javier Gonzalo; Laurella, Sergio Luis; Comment on Study of enantioselective metolachlor adsorption by activated carbons” by A. Gomis-Berenguer, I. Laidin, S. Rononcial and B. Cagnon, RSC Advances , 2020, 10 , 40321; Royal Society of Chemistry; RSC Advances; 13; 15; 3-2023; 10349-10352
2046-2069
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://xlink.rsc.org/?DOI=D3RA00363A
info:eu-repo/semantics/altIdentifier/doi/10.1039/D3RA00363A
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613644434800640
score 13.070432

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