NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterization
- Autores
- Milt, Viviana Guadalupe; Ulla, Maria Alicia del H.; Miro, Eduardo Ernesto
- Año de publicación
- 2005
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The BaCoO3-y perovskite-type mixed oxide is studied for both trapping of NOx and combustion of diesel soot. The starting material consists of a stoichiometric mixture of Ba and Co nitrates. Different crystalline phases are obtained when the solids are calcined at different temperatures (ranging from 400 to 1000°C). After 400°C calcination Ba(NO3)2 and Co3O4 crystalline phases are formed, while after calcination at 700°C the BaCoO3 stoichiometric perovskite is obtained. However, when the temperature is increased to 1000°C, the structure loses oxygen and perovskite BaCoO 2.74 is formed. The solids calcined at 700 and 1000°C show high NOx adsorption capacity, the latter being more effective. This solid shows weak IR bands in the 800 cm-1 frequency region associated with the perovskite structure. After the catalyst interacts with NOx, new bands associated with bulk nitrates and surface NO3- species are observed. Signals associated with surface N-bounded species of the OBaNO2 type could be masked by the intense Ba(NO3) 2 signals. LRS characterization is in agreement with XRD and FTIR results. The Raman signal at 716 cm-1 is associated with the BaCoO2.74 structure while a broad signal at 607 cm-1 appears in samples containing BaCoO3 and BaCoO2.94 phases. Nitrates formed upon NO + O2 treatments show high thermal stability under He atmosphere up to 490°C. However, reductive treatments either under H2 atmosphere or with soot particles cause decomposition of the nitrates at temperatures lower than 400°C. A reaction scheme is proposed involving the participation of perovskite structures, Co3O 4, Ba(NO3)2, BaO and metallic Co particles. The catalyst under study favors the reaction between the soot particles and the trapped NOx species making this system promising for the simultaneous abatement of both contaminants. The addition of K decreases the soot combustion temperature.
Fil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Ulla, Maria Alicia del H.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina - Materia
-
BACOO3-Y PEROVSKITE
CATALYTIC TRAP
DIESEL POLLUTANTS
NOX TRAPPING
SOOT COMBUSTION - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/73021
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CONICET Digital (CONICET) |
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NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterizationMilt, Viviana GuadalupeUlla, Maria Alicia del H.Miro, Eduardo ErnestoBACOO3-Y PEROVSKITECATALYTIC TRAPDIESEL POLLUTANTSNOX TRAPPINGSOOT COMBUSTIONhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The BaCoO3-y perovskite-type mixed oxide is studied for both trapping of NOx and combustion of diesel soot. The starting material consists of a stoichiometric mixture of Ba and Co nitrates. Different crystalline phases are obtained when the solids are calcined at different temperatures (ranging from 400 to 1000°C). After 400°C calcination Ba(NO3)2 and Co3O4 crystalline phases are formed, while after calcination at 700°C the BaCoO3 stoichiometric perovskite is obtained. However, when the temperature is increased to 1000°C, the structure loses oxygen and perovskite BaCoO 2.74 is formed. The solids calcined at 700 and 1000°C show high NOx adsorption capacity, the latter being more effective. This solid shows weak IR bands in the 800 cm-1 frequency region associated with the perovskite structure. After the catalyst interacts with NOx, new bands associated with bulk nitrates and surface NO3- species are observed. Signals associated with surface N-bounded species of the OBaNO2 type could be masked by the intense Ba(NO3) 2 signals. LRS characterization is in agreement with XRD and FTIR results. The Raman signal at 716 cm-1 is associated with the BaCoO2.74 structure while a broad signal at 607 cm-1 appears in samples containing BaCoO3 and BaCoO2.94 phases. Nitrates formed upon NO + O2 treatments show high thermal stability under He atmosphere up to 490°C. However, reductive treatments either under H2 atmosphere or with soot particles cause decomposition of the nitrates at temperatures lower than 400°C. A reaction scheme is proposed involving the participation of perovskite structures, Co3O 4, Ba(NO3)2, BaO and metallic Co particles. The catalyst under study favors the reaction between the soot particles and the trapped NOx species making this system promising for the simultaneous abatement of both contaminants. The addition of K decreases the soot combustion temperature.Fil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Ulla, Maria Alicia del H.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2005-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/73021Milt, Viviana Guadalupe; Ulla, Maria Alicia del H.; Miro, Eduardo Ernesto; NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterization; Elsevier Science; Applied Catalysis B: Environmental; 57; 1; 4-2005; 13-210926-3373CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2004.09.022info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:26:44Zoai:ri.conicet.gov.ar:11336/73021instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:26:44.346CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterization |
title |
NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterization |
spellingShingle |
NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterization Milt, Viviana Guadalupe BACOO3-Y PEROVSKITE CATALYTIC TRAP DIESEL POLLUTANTS NOX TRAPPING SOOT COMBUSTION |
title_short |
NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterization |
title_full |
NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterization |
title_fullStr |
NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterization |
title_full_unstemmed |
NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterization |
title_sort |
NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterization |
dc.creator.none.fl_str_mv |
Milt, Viviana Guadalupe Ulla, Maria Alicia del H. Miro, Eduardo Ernesto |
author |
Milt, Viviana Guadalupe |
author_facet |
Milt, Viviana Guadalupe Ulla, Maria Alicia del H. Miro, Eduardo Ernesto |
author_role |
author |
author2 |
Ulla, Maria Alicia del H. Miro, Eduardo Ernesto |
author2_role |
author author |
dc.subject.none.fl_str_mv |
BACOO3-Y PEROVSKITE CATALYTIC TRAP DIESEL POLLUTANTS NOX TRAPPING SOOT COMBUSTION |
topic |
BACOO3-Y PEROVSKITE CATALYTIC TRAP DIESEL POLLUTANTS NOX TRAPPING SOOT COMBUSTION |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The BaCoO3-y perovskite-type mixed oxide is studied for both trapping of NOx and combustion of diesel soot. The starting material consists of a stoichiometric mixture of Ba and Co nitrates. Different crystalline phases are obtained when the solids are calcined at different temperatures (ranging from 400 to 1000°C). After 400°C calcination Ba(NO3)2 and Co3O4 crystalline phases are formed, while after calcination at 700°C the BaCoO3 stoichiometric perovskite is obtained. However, when the temperature is increased to 1000°C, the structure loses oxygen and perovskite BaCoO 2.74 is formed. The solids calcined at 700 and 1000°C show high NOx adsorption capacity, the latter being more effective. This solid shows weak IR bands in the 800 cm-1 frequency region associated with the perovskite structure. After the catalyst interacts with NOx, new bands associated with bulk nitrates and surface NO3- species are observed. Signals associated with surface N-bounded species of the OBaNO2 type could be masked by the intense Ba(NO3) 2 signals. LRS characterization is in agreement with XRD and FTIR results. The Raman signal at 716 cm-1 is associated with the BaCoO2.74 structure while a broad signal at 607 cm-1 appears in samples containing BaCoO3 and BaCoO2.94 phases. Nitrates formed upon NO + O2 treatments show high thermal stability under He atmosphere up to 490°C. However, reductive treatments either under H2 atmosphere or with soot particles cause decomposition of the nitrates at temperatures lower than 400°C. A reaction scheme is proposed involving the participation of perovskite structures, Co3O 4, Ba(NO3)2, BaO and metallic Co particles. The catalyst under study favors the reaction between the soot particles and the trapped NOx species making this system promising for the simultaneous abatement of both contaminants. The addition of K decreases the soot combustion temperature. Fil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Ulla, Maria Alicia del H.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina |
description |
The BaCoO3-y perovskite-type mixed oxide is studied for both trapping of NOx and combustion of diesel soot. The starting material consists of a stoichiometric mixture of Ba and Co nitrates. Different crystalline phases are obtained when the solids are calcined at different temperatures (ranging from 400 to 1000°C). After 400°C calcination Ba(NO3)2 and Co3O4 crystalline phases are formed, while after calcination at 700°C the BaCoO3 stoichiometric perovskite is obtained. However, when the temperature is increased to 1000°C, the structure loses oxygen and perovskite BaCoO 2.74 is formed. The solids calcined at 700 and 1000°C show high NOx adsorption capacity, the latter being more effective. This solid shows weak IR bands in the 800 cm-1 frequency region associated with the perovskite structure. After the catalyst interacts with NOx, new bands associated with bulk nitrates and surface NO3- species are observed. Signals associated with surface N-bounded species of the OBaNO2 type could be masked by the intense Ba(NO3) 2 signals. LRS characterization is in agreement with XRD and FTIR results. The Raman signal at 716 cm-1 is associated with the BaCoO2.74 structure while a broad signal at 607 cm-1 appears in samples containing BaCoO3 and BaCoO2.94 phases. Nitrates formed upon NO + O2 treatments show high thermal stability under He atmosphere up to 490°C. However, reductive treatments either under H2 atmosphere or with soot particles cause decomposition of the nitrates at temperatures lower than 400°C. A reaction scheme is proposed involving the participation of perovskite structures, Co3O 4, Ba(NO3)2, BaO and metallic Co particles. The catalyst under study favors the reaction between the soot particles and the trapped NOx species making this system promising for the simultaneous abatement of both contaminants. The addition of K decreases the soot combustion temperature. |
publishDate |
2005 |
dc.date.none.fl_str_mv |
2005-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/73021 Milt, Viviana Guadalupe; Ulla, Maria Alicia del H.; Miro, Eduardo Ernesto; NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterization; Elsevier Science; Applied Catalysis B: Environmental; 57; 1; 4-2005; 13-21 0926-3373 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/73021 |
identifier_str_mv |
Milt, Viviana Guadalupe; Ulla, Maria Alicia del H.; Miro, Eduardo Ernesto; NOx trapping and soot combustion on BaCoO3-y perovskite: LRS and FTIR characterization; Elsevier Science; Applied Catalysis B: Environmental; 57; 1; 4-2005; 13-21 0926-3373 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcatb.2004.09.022 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844614268549332992 |
score |
13.070432 |