Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceria
- Autores
- Poggio Fraccari, Eduardo Arístides; Rozenblit, Abigail; Mariño, Fernando Javier
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Proton-exchange membrane fuel cells are of great interest for vehicular applications. A highly pure, sustainably obtained H2 stream is desirable to use as the cell feed. In the water gas shift (WGS) process, large amounts of CO, which is a poison for the cell anode, are removed from a bioalcohol-derived H2 stream before it enters the cell. In this study, Cu–Ni catalysts supported on La-doped ceria were analyzed and studied in the WGS reaction. The supports were prepared by the urea thermal decomposition method with different percentages of La as a promoter of ceria. The metal phase was incorporated by incipient wet impregnation. Many characterization techniques were employed in this work (BET, XRD, SEM, ICP, TPR, OSC), and the relationship between the resulting properties and catalytic performance was investigated to determine the effect of La. A mixture of Cu and Ni was found to be the most effective active phase, having considerable activity and selectivity towards the desired reaction. Low degrees of La doping in ceria enhance oxygen mobility in the lattice. A commercial Ce salt containing La as its main impurity (ca. 2 %) is a convenient precursor, given its good performance and low cost compared to a high-purity salt.
Fil: Poggio Fraccari, Eduardo Arístides. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina
Fil: Rozenblit, Abigail. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina
Fil: Mariño, Fernando Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina - Materia
-
CERIUM
COPPER
HETEROGENEOUS CATALYSIS
LANTHANUM
NICKEL
SUPPORTED CATALYSTS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/113416
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Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceriaPoggio Fraccari, Eduardo ArístidesRozenblit, AbigailMariño, Fernando JavierCERIUMCOPPERHETEROGENEOUS CATALYSISLANTHANUMNICKELSUPPORTED CATALYSTShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Proton-exchange membrane fuel cells are of great interest for vehicular applications. A highly pure, sustainably obtained H2 stream is desirable to use as the cell feed. In the water gas shift (WGS) process, large amounts of CO, which is a poison for the cell anode, are removed from a bioalcohol-derived H2 stream before it enters the cell. In this study, Cu–Ni catalysts supported on La-doped ceria were analyzed and studied in the WGS reaction. The supports were prepared by the urea thermal decomposition method with different percentages of La as a promoter of ceria. The metal phase was incorporated by incipient wet impregnation. Many characterization techniques were employed in this work (BET, XRD, SEM, ICP, TPR, OSC), and the relationship between the resulting properties and catalytic performance was investigated to determine the effect of La. A mixture of Cu and Ni was found to be the most effective active phase, having considerable activity and selectivity towards the desired reaction. Low degrees of La doping in ceria enhance oxygen mobility in the lattice. A commercial Ce salt containing La as its main impurity (ca. 2 %) is a convenient precursor, given its good performance and low cost compared to a high-purity salt.Fil: Poggio Fraccari, Eduardo Arístides. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; ArgentinaFil: Rozenblit, Abigail. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; ArgentinaFil: Mariño, Fernando Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; ArgentinaWiley VCH Verlag2018-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/113416Poggio Fraccari, Eduardo Arístides; Rozenblit, Abigail; Mariño, Fernando Javier; Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceria; Wiley VCH Verlag; European Journal of Inorganic Chemistry; 2018; 24; 5-2018; 2865-28731434-1948CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201800048info:eu-repo/semantics/altIdentifier/doi/10.1002/ejic.201800048info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:55:07Zoai:ri.conicet.gov.ar:11336/113416instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:55:07.378CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceria |
title |
Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceria |
spellingShingle |
Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceria Poggio Fraccari, Eduardo Arístides CERIUM COPPER HETEROGENEOUS CATALYSIS LANTHANUM NICKEL SUPPORTED CATALYSTS |
title_short |
Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceria |
title_full |
Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceria |
title_fullStr |
Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceria |
title_full_unstemmed |
Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceria |
title_sort |
Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceria |
dc.creator.none.fl_str_mv |
Poggio Fraccari, Eduardo Arístides Rozenblit, Abigail Mariño, Fernando Javier |
author |
Poggio Fraccari, Eduardo Arístides |
author_facet |
Poggio Fraccari, Eduardo Arístides Rozenblit, Abigail Mariño, Fernando Javier |
author_role |
author |
author2 |
Rozenblit, Abigail Mariño, Fernando Javier |
author2_role |
author author |
dc.subject.none.fl_str_mv |
CERIUM COPPER HETEROGENEOUS CATALYSIS LANTHANUM NICKEL SUPPORTED CATALYSTS |
topic |
CERIUM COPPER HETEROGENEOUS CATALYSIS LANTHANUM NICKEL SUPPORTED CATALYSTS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Proton-exchange membrane fuel cells are of great interest for vehicular applications. A highly pure, sustainably obtained H2 stream is desirable to use as the cell feed. In the water gas shift (WGS) process, large amounts of CO, which is a poison for the cell anode, are removed from a bioalcohol-derived H2 stream before it enters the cell. In this study, Cu–Ni catalysts supported on La-doped ceria were analyzed and studied in the WGS reaction. The supports were prepared by the urea thermal decomposition method with different percentages of La as a promoter of ceria. The metal phase was incorporated by incipient wet impregnation. Many characterization techniques were employed in this work (BET, XRD, SEM, ICP, TPR, OSC), and the relationship between the resulting properties and catalytic performance was investigated to determine the effect of La. A mixture of Cu and Ni was found to be the most effective active phase, having considerable activity and selectivity towards the desired reaction. Low degrees of La doping in ceria enhance oxygen mobility in the lattice. A commercial Ce salt containing La as its main impurity (ca. 2 %) is a convenient precursor, given its good performance and low cost compared to a high-purity salt. Fil: Poggio Fraccari, Eduardo Arístides. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina Fil: Rozenblit, Abigail. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina Fil: Mariño, Fernando Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías del Hidrogeno y Energias Sostenibles; Argentina |
description |
Proton-exchange membrane fuel cells are of great interest for vehicular applications. A highly pure, sustainably obtained H2 stream is desirable to use as the cell feed. In the water gas shift (WGS) process, large amounts of CO, which is a poison for the cell anode, are removed from a bioalcohol-derived H2 stream before it enters the cell. In this study, Cu–Ni catalysts supported on La-doped ceria were analyzed and studied in the WGS reaction. The supports were prepared by the urea thermal decomposition method with different percentages of La as a promoter of ceria. The metal phase was incorporated by incipient wet impregnation. Many characterization techniques were employed in this work (BET, XRD, SEM, ICP, TPR, OSC), and the relationship between the resulting properties and catalytic performance was investigated to determine the effect of La. A mixture of Cu and Ni was found to be the most effective active phase, having considerable activity and selectivity towards the desired reaction. Low degrees of La doping in ceria enhance oxygen mobility in the lattice. A commercial Ce salt containing La as its main impurity (ca. 2 %) is a convenient precursor, given its good performance and low cost compared to a high-purity salt. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/113416 Poggio Fraccari, Eduardo Arístides; Rozenblit, Abigail; Mariño, Fernando Javier; Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceria; Wiley VCH Verlag; European Journal of Inorganic Chemistry; 2018; 24; 5-2018; 2865-2873 1434-1948 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/113416 |
identifier_str_mv |
Poggio Fraccari, Eduardo Arístides; Rozenblit, Abigail; Mariño, Fernando Javier; Low cost catalysts for Water Gas Shift reaction based on CuNi over La promoted ceria; Wiley VCH Verlag; European Journal of Inorganic Chemistry; 2018; 24; 5-2018; 2865-2873 1434-1948 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201800048 info:eu-repo/semantics/altIdentifier/doi/10.1002/ejic.201800048 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley VCH Verlag |
publisher.none.fl_str_mv |
Wiley VCH Verlag |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613663336431616 |
score |
13.070432 |