Development of Dense Films from Melia Azedarach Polysaccharides

Autores
Masuelli, Martin Alberto; Garcia, Maria Guadalupe; Marchese, Jose; Ochoa, Nelio Ariel
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this work was to prepare dense films from polysaccharides extracted from Melia azedarach (MA) to be used e.g. in agricultural industry. Crosslinking of MA films with glutaraldehyde (Glu) through immersion method were performed. Structural features of films were elucidated by FTIR and XRD analysis. The influence of crosslinking in mechanical properties, water uptake and water vapor permeation was evaluated. Results showed neat Melia azedarach film presented high elongation and elastic modulus. Hydroxyl functional groups present in MA were reacted with glutaraldheyde to render a crosslinked matrix. It was observed through FTIR analysis that OH band reduces intensity due to the formation of acetal linkage, as the crosslinking time increases. XRD evidenced structural changes in MA arrangement with the crosslinking time. Chemical crosslinking during 12 h and 24 h rendered insoluble but less deformable films. Water uptake and water vapor permeability were reduced as the crosslinking time increased.
Fil: Masuelli, Martin Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina
Fil: Garcia, Maria Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina
Fil: Marchese, Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina
Fil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina
Materia
Crosslinking
Mechanical Properties
Polysaccharides
Spectroscopy
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5694
Acceder
id CONICETDig_ecae320f1f77f02641440468a86b4dba
oai_identifier_str oai:ri.conicet.gov.ar:11336/5694
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Development of Dense Films from Melia Azedarach PolysaccharidesMasuelli, Martin AlbertoGarcia, Maria GuadalupeMarchese, JoseOchoa, Nelio ArielCrosslinkingMechanical PropertiesPolysaccharidesSpectroscopyhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.9https://purl.org/becyt/ford/2The aim of this work was to prepare dense films from polysaccharides extracted from Melia azedarach (MA) to be used e.g. in agricultural industry. Crosslinking of MA films with glutaraldehyde (Glu) through immersion method were performed. Structural features of films were elucidated by FTIR and XRD analysis. The influence of crosslinking in mechanical properties, water uptake and water vapor permeation was evaluated. Results showed neat Melia azedarach film presented high elongation and elastic modulus. Hydroxyl functional groups present in MA were reacted with glutaraldheyde to render a crosslinked matrix. It was observed through FTIR analysis that OH band reduces intensity due to the formation of acetal linkage, as the crosslinking time increases. XRD evidenced structural changes in MA arrangement with the crosslinking time. Chemical crosslinking during 12 h and 24 h rendered insoluble but less deformable films. Water uptake and water vapor permeability were reduced as the crosslinking time increased.Fil: Masuelli, Martin Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; ArgentinaFil: Garcia, Maria Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; ArgentinaFil: Marchese, Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; ArgentinaFil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; ArgentinaWiley2014-11-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5694Masuelli, Martin Alberto; Garcia, Maria Guadalupe; Marchese, Jose; Ochoa, Nelio Ariel; Development of Dense Films from Melia Azedarach Polysaccharides; Wiley; Journal of Applied Polymer Science; 132; 11; 1-11-2014; 41624-416240021-8995enginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/wol1/doi/10.1002/app.41624/abstractinfo:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/doi/10.1002/app.41624info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:02:07Zoai:ri.conicet.gov.ar:11336/5694instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:02:07.49CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Development of Dense Films from Melia Azedarach Polysaccharides
title Development of Dense Films from Melia Azedarach Polysaccharides
spellingShingle Development of Dense Films from Melia Azedarach Polysaccharides
Masuelli, Martin Alberto
Crosslinking
Mechanical Properties
Polysaccharides
Spectroscopy
title_short Development of Dense Films from Melia Azedarach Polysaccharides
title_full Development of Dense Films from Melia Azedarach Polysaccharides
title_fullStr Development of Dense Films from Melia Azedarach Polysaccharides
title_full_unstemmed Development of Dense Films from Melia Azedarach Polysaccharides
title_sort Development of Dense Films from Melia Azedarach Polysaccharides
dc.creator.none.fl_str_mv Masuelli, Martin Alberto
Garcia, Maria Guadalupe
Marchese, Jose
Ochoa, Nelio Ariel
author Masuelli, Martin Alberto
author_facet Masuelli, Martin Alberto
Garcia, Maria Guadalupe
Marchese, Jose
Ochoa, Nelio Ariel
author_role author
author2 Garcia, Maria Guadalupe
Marchese, Jose
Ochoa, Nelio Ariel
author2_role author
author
author
dc.subject.none.fl_str_mv Crosslinking
Mechanical Properties
Polysaccharides
Spectroscopy
topic Crosslinking
Mechanical Properties
Polysaccharides
Spectroscopy
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/2.9
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The aim of this work was to prepare dense films from polysaccharides extracted from Melia azedarach (MA) to be used e.g. in agricultural industry. Crosslinking of MA films with glutaraldehyde (Glu) through immersion method were performed. Structural features of films were elucidated by FTIR and XRD analysis. The influence of crosslinking in mechanical properties, water uptake and water vapor permeation was evaluated. Results showed neat Melia azedarach film presented high elongation and elastic modulus. Hydroxyl functional groups present in MA were reacted with glutaraldheyde to render a crosslinked matrix. It was observed through FTIR analysis that OH band reduces intensity due to the formation of acetal linkage, as the crosslinking time increases. XRD evidenced structural changes in MA arrangement with the crosslinking time. Chemical crosslinking during 12 h and 24 h rendered insoluble but less deformable films. Water uptake and water vapor permeability were reduced as the crosslinking time increased.
Fil: Masuelli, Martin Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina
Fil: Garcia, Maria Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina
Fil: Marchese, Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina
Fil: Ochoa, Nelio Ariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico San Luis. Instituto de Física Aplicada; Argentina
description The aim of this work was to prepare dense films from polysaccharides extracted from Melia azedarach (MA) to be used e.g. in agricultural industry. Crosslinking of MA films with glutaraldehyde (Glu) through immersion method were performed. Structural features of films were elucidated by FTIR and XRD analysis. The influence of crosslinking in mechanical properties, water uptake and water vapor permeation was evaluated. Results showed neat Melia azedarach film presented high elongation and elastic modulus. Hydroxyl functional groups present in MA were reacted with glutaraldheyde to render a crosslinked matrix. It was observed through FTIR analysis that OH band reduces intensity due to the formation of acetal linkage, as the crosslinking time increases. XRD evidenced structural changes in MA arrangement with the crosslinking time. Chemical crosslinking during 12 h and 24 h rendered insoluble but less deformable films. Water uptake and water vapor permeability were reduced as the crosslinking time increased.
publishDate 2014
dc.date.none.fl_str_mv 2014-11-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5694
Masuelli, Martin Alberto; Garcia, Maria Guadalupe; Marchese, Jose; Ochoa, Nelio Ariel; Development of Dense Films from Melia Azedarach Polysaccharides; Wiley; Journal of Applied Polymer Science; 132; 11; 1-11-2014; 41624-41624
0021-8995
url http://hdl.handle.net/11336/5694
identifier_str_mv Masuelli, Martin Alberto; Garcia, Maria Guadalupe; Marchese, Jose; Ochoa, Nelio Ariel; Development of Dense Films from Melia Azedarach Polysaccharides; Wiley; Journal of Applied Polymer Science; 132; 11; 1-11-2014; 41624-41624
0021-8995
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/wol1/doi/10.1002/app.41624/abstract
info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/doi/10.1002/app.41624
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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