Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalysts

Autores
Villaverde, María Magdalena; Marchi, Alberto Julio; Garetto, Teresita Francisca
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The liquid-phase transfer hydrogenation of furfural on Cu-based catalysts was studied. Catalysts were prepared by incipient wetness impregnation (Cu/SiO2) and co-precipitation (Cu–Mg–Al). The effect of metal-support interaction, hydrogen donor, copper loading and temperature on catalytic performance was evaluated. Small particles, strongly interacting with a spinel-like matrix, had higher capability for transferring hydrogen than large ones having low interaction with support. An important increase in reaction rate was observed when temperature was raised from 110 to 150 °C. Thus, it was possible to attain complete furfural conversion to furfuryl alcohol with Cu(40%)–Mg–Al after 6 h at 150 °C.
Fil: Villaverde, María Magdalena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Hydrogenation
Furfural
Furfuryl Alcohol
Copper-Based Catalysts
Hydrogen Donor
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/30916
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalystsVillaverde, María MagdalenaMarchi, Alberto JulioGaretto, Teresita FranciscaHydrogenationFurfuralFurfuryl AlcoholCopper-Based CatalystsHydrogen Donorhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The liquid-phase transfer hydrogenation of furfural on Cu-based catalysts was studied. Catalysts were prepared by incipient wetness impregnation (Cu/SiO2) and co-precipitation (Cu–Mg–Al). The effect of metal-support interaction, hydrogen donor, copper loading and temperature on catalytic performance was evaluated. Small particles, strongly interacting with a spinel-like matrix, had higher capability for transferring hydrogen than large ones having low interaction with support. An important increase in reaction rate was observed when temperature was raised from 110 to 150 °C. Thus, it was possible to attain complete furfural conversion to furfuryl alcohol with Cu(40%)–Mg–Al after 6 h at 150 °C.Fil: Villaverde, María Magdalena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaElsevier2014-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/30916Villaverde, María Magdalena; Marchi, Alberto Julio; Garetto, Teresita Francisca; Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalysts; Elsevier; Catalysis Communications; 58; 8-2014; 6-101566-7367CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1566736714003252info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2014.08.021info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:10:26Zoai:ri.conicet.gov.ar:11336/30916instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:10:27.279CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalysts
title Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalysts
spellingShingle Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalysts
Villaverde, María Magdalena
Hydrogenation
Furfural
Furfuryl Alcohol
Copper-Based Catalysts
Hydrogen Donor
title_short Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalysts
title_full Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalysts
title_fullStr Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalysts
title_full_unstemmed Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalysts
title_sort Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalysts
dc.creator.none.fl_str_mv Villaverde, María Magdalena
Marchi, Alberto Julio
Garetto, Teresita Francisca
author Villaverde, María Magdalena
author_facet Villaverde, María Magdalena
Marchi, Alberto Julio
Garetto, Teresita Francisca
author_role author
author2 Marchi, Alberto Julio
Garetto, Teresita Francisca
author2_role author
author
dc.subject.none.fl_str_mv Hydrogenation
Furfural
Furfuryl Alcohol
Copper-Based Catalysts
Hydrogen Donor
topic Hydrogenation
Furfural
Furfuryl Alcohol
Copper-Based Catalysts
Hydrogen Donor
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The liquid-phase transfer hydrogenation of furfural on Cu-based catalysts was studied. Catalysts were prepared by incipient wetness impregnation (Cu/SiO2) and co-precipitation (Cu–Mg–Al). The effect of metal-support interaction, hydrogen donor, copper loading and temperature on catalytic performance was evaluated. Small particles, strongly interacting with a spinel-like matrix, had higher capability for transferring hydrogen than large ones having low interaction with support. An important increase in reaction rate was observed when temperature was raised from 110 to 150 °C. Thus, it was possible to attain complete furfural conversion to furfuryl alcohol with Cu(40%)–Mg–Al after 6 h at 150 °C.
Fil: Villaverde, María Magdalena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Marchi, Alberto Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description The liquid-phase transfer hydrogenation of furfural on Cu-based catalysts was studied. Catalysts were prepared by incipient wetness impregnation (Cu/SiO2) and co-precipitation (Cu–Mg–Al). The effect of metal-support interaction, hydrogen donor, copper loading and temperature on catalytic performance was evaluated. Small particles, strongly interacting with a spinel-like matrix, had higher capability for transferring hydrogen than large ones having low interaction with support. An important increase in reaction rate was observed when temperature was raised from 110 to 150 °C. Thus, it was possible to attain complete furfural conversion to furfuryl alcohol with Cu(40%)–Mg–Al after 6 h at 150 °C.
publishDate 2014
dc.date.none.fl_str_mv 2014-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/30916
Villaverde, María Magdalena; Marchi, Alberto Julio; Garetto, Teresita Francisca; Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalysts; Elsevier; Catalysis Communications; 58; 8-2014; 6-10
1566-7367
CONICET Digital
CONICET
url http://hdl.handle.net/11336/30916
identifier_str_mv Villaverde, María Magdalena; Marchi, Alberto Julio; Garetto, Teresita Francisca; Liquid-phase transfer hydrogenation of furfural to furfuryl alcohol on Cu–Mg–Al catalysts; Elsevier; Catalysis Communications; 58; 8-2014; 6-10
1566-7367
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1566736714003252
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.catcom.2014.08.021
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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