Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells

Autores
Fernandez, Jose Luis; Raghuveer, Vadari; Manthiram, Arumugam; Bard, Allen J.
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Fuel cells are appealing for a variety of energy needs, but the high materials and manufacturing costs have hampered their commercialization. The limited availability and the high cost of the currently used platinum catalysts, however, pose a serious problem in their practical application. We report here non-platinum electrocatalyst systems, such as Pd-Co-Au and Pd-Ti, that are proposed from simple thermodynamic guidelines and selecting by a rapid screening technique, which show electrochemical performance in proton exchange membrane fuel cells (PEMFC) similar to that found with commercial platinum catalysts. This finding opens up a new avenue to develop potentially less expensive electrocatalysts.
Fil: Fernandez, Jose Luis. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Raghuveer, Vadari. University of Texas at Austin; Estados Unidos
Fil: Manthiram, Arumugam. University of Texas at Austin; Estados Unidos
Fil: Bard, Allen J.. University of Texas at Austin; Estados Unidos
Materia
Pd-Ti and Pd-Co-Au Electrocatalysts
Proton Exchange
Membrane Fuel Cells
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/102564

id CONICETDig_eb6d2c317770d033994c48e2f1e1fd9c
oai_identifier_str oai:ri.conicet.gov.ar:11336/102564
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel CellsFernandez, Jose LuisRaghuveer, VadariManthiram, ArumugamBard, Allen J.Pd-Ti and Pd-Co-Au ElectrocatalystsProton ExchangeMembrane Fuel Cellshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Fuel cells are appealing for a variety of energy needs, but the high materials and manufacturing costs have hampered their commercialization. The limited availability and the high cost of the currently used platinum catalysts, however, pose a serious problem in their practical application. We report here non-platinum electrocatalyst systems, such as Pd-Co-Au and Pd-Ti, that are proposed from simple thermodynamic guidelines and selecting by a rapid screening technique, which show electrochemical performance in proton exchange membrane fuel cells (PEMFC) similar to that found with commercial platinum catalysts. This finding opens up a new avenue to develop potentially less expensive electrocatalysts.Fil: Fernandez, Jose Luis. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; ArgentinaFil: Raghuveer, Vadari. University of Texas at Austin; Estados UnidosFil: Manthiram, Arumugam. University of Texas at Austin; Estados UnidosFil: Bard, Allen J.. University of Texas at Austin; Estados UnidosAmerican Chemical Society2005-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/102564Fernandez, Jose Luis; Raghuveer, Vadari; Manthiram, Arumugam; Bard, Allen J.; Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells; American Chemical Society; Journal of the American Chemical Society; 127; 38; 9-2005; 13100-131010002-7863CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/ja0534710info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:14:49Zoai:ri.conicet.gov.ar:11336/102564instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:14:49.704CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells
title Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells
spellingShingle Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells
Fernandez, Jose Luis
Pd-Ti and Pd-Co-Au Electrocatalysts
Proton Exchange
Membrane Fuel Cells
title_short Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells
title_full Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells
title_fullStr Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells
title_full_unstemmed Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells
title_sort Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells
dc.creator.none.fl_str_mv Fernandez, Jose Luis
Raghuveer, Vadari
Manthiram, Arumugam
Bard, Allen J.
author Fernandez, Jose Luis
author_facet Fernandez, Jose Luis
Raghuveer, Vadari
Manthiram, Arumugam
Bard, Allen J.
author_role author
author2 Raghuveer, Vadari
Manthiram, Arumugam
Bard, Allen J.
author2_role author
author
author
dc.subject.none.fl_str_mv Pd-Ti and Pd-Co-Au Electrocatalysts
Proton Exchange
Membrane Fuel Cells
topic Pd-Ti and Pd-Co-Au Electrocatalysts
Proton Exchange
Membrane Fuel Cells
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Fuel cells are appealing for a variety of energy needs, but the high materials and manufacturing costs have hampered their commercialization. The limited availability and the high cost of the currently used platinum catalysts, however, pose a serious problem in their practical application. We report here non-platinum electrocatalyst systems, such as Pd-Co-Au and Pd-Ti, that are proposed from simple thermodynamic guidelines and selecting by a rapid screening technique, which show electrochemical performance in proton exchange membrane fuel cells (PEMFC) similar to that found with commercial platinum catalysts. This finding opens up a new avenue to develop potentially less expensive electrocatalysts.
Fil: Fernandez, Jose Luis. Universidad Nacional del Litoral. Instituto de Química Aplicada del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Química Aplicada del Litoral.; Argentina
Fil: Raghuveer, Vadari. University of Texas at Austin; Estados Unidos
Fil: Manthiram, Arumugam. University of Texas at Austin; Estados Unidos
Fil: Bard, Allen J.. University of Texas at Austin; Estados Unidos
description Fuel cells are appealing for a variety of energy needs, but the high materials and manufacturing costs have hampered their commercialization. The limited availability and the high cost of the currently used platinum catalysts, however, pose a serious problem in their practical application. We report here non-platinum electrocatalyst systems, such as Pd-Co-Au and Pd-Ti, that are proposed from simple thermodynamic guidelines and selecting by a rapid screening technique, which show electrochemical performance in proton exchange membrane fuel cells (PEMFC) similar to that found with commercial platinum catalysts. This finding opens up a new avenue to develop potentially less expensive electrocatalysts.
publishDate 2005
dc.date.none.fl_str_mv 2005-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/102564
Fernandez, Jose Luis; Raghuveer, Vadari; Manthiram, Arumugam; Bard, Allen J.; Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells; American Chemical Society; Journal of the American Chemical Society; 127; 38; 9-2005; 13100-13101
0002-7863
CONICET Digital
CONICET
url http://hdl.handle.net/11336/102564
identifier_str_mv Fernandez, Jose Luis; Raghuveer, Vadari; Manthiram, Arumugam; Bard, Allen J.; Pd−Ti and Pd−Co−Au Electrocatalysts as a Replacement for Platinum for Oxygen Reduction in Proton Exchange Membrane Fuel Cells; American Chemical Society; Journal of the American Chemical Society; 127; 38; 9-2005; 13100-13101
0002-7863
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/ja0534710
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614079656755200
score 13.070432