Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformam...

Autores
Harvey, Miguel Angel; Suarez, Sebastian; Doctorovich, Fabio; Baggio, Ricardo Fortunato
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The isomorphous title compounds, [Tr(S4O6)(C 12H12N2)2]·2C 3H7NO (Tr = CdII and ZnII), consist of metal centres to which one tetrathionate and two 4,4′-dimethyl-2, 2′-bipyridine chelating ligands bind. The structures are completed by two symmetry-related dimethylformamide solvent molecules. Each metal-centred complex is bisected by a twofold axis running through the metal centre and halving the chelating tetrathionate dianion through the central S - S bond. The ancillary symmetry-related 4,4′-dimethyl-2,2′-bipyridine ligands act as chelates. This results in a distorted six-coordinate geometry, with similar Tr - O/N distances but central angles differing substantially from 90 and 180°. Both ligands are basically featureless from a geometric point of view, with torsion angles in both coordinated tetrathionate groups suggesting a trend linking metal size (covalent radius) and ligand 'openness'. Packing is directed by (C - H)aromatic⋯O bridges and π-π offset stacked interactions defining chains along [001], further linked by weaker (C - H)methyl⋯O bridges, some of them mediated by the dimethylformamide solvent molecules.
Fil: Harvey, Miguel Angel. Consejo Nacional de Invest.cientif.y Tecnicas. Centro Nacional Patagonico; Argentina. Universidad Nacional de la Patagonia "San Juan Bosco"; Argentina
Fil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Doctorovich, Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina
Materia
Isomorphous
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/840
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/840
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformamide disolvate and the zinc(II) analogueHarvey, Miguel AngelSuarez, SebastianDoctorovich, FabioBaggio, Ricardo FortunatoIsomorphoushttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The isomorphous title compounds, [Tr(S4O6)(C 12H12N2)2]·2C 3H7NO (Tr = CdII and ZnII), consist of metal centres to which one tetrathionate and two 4,4′-dimethyl-2, 2′-bipyridine chelating ligands bind. The structures are completed by two symmetry-related dimethylformamide solvent molecules. Each metal-centred complex is bisected by a twofold axis running through the metal centre and halving the chelating tetrathionate dianion through the central S - S bond. The ancillary symmetry-related 4,4′-dimethyl-2,2′-bipyridine ligands act as chelates. This results in a distorted six-coordinate geometry, with similar Tr - O/N distances but central angles differing substantially from 90 and 180°. Both ligands are basically featureless from a geometric point of view, with torsion angles in both coordinated tetrathionate groups suggesting a trend linking metal size (covalent radius) and ligand 'openness'. Packing is directed by (C - H)aromatic⋯O bridges and π-π offset stacked interactions defining chains along [001], further linked by weaker (C - H)methyl⋯O bridges, some of them mediated by the dimethylformamide solvent molecules.Fil: Harvey, Miguel Angel. Consejo Nacional de Invest.cientif.y Tecnicas. Centro Nacional Patagonico; Argentina. Universidad Nacional de la Patagonia "San Juan Bosco"; ArgentinaFil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Doctorovich, Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; ArgentinaWiley Blackwell Publishing, Inc2013-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/840Harvey, Miguel Angel; Suarez, Sebastian; Doctorovich, Fabio; Baggio, Ricardo Fortunato; Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformamide disolvate and the zinc(II) analogue; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 69; 7; 7-2013; 745-7490108-2701enginfo:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270113016521info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:05:18Zoai:ri.conicet.gov.ar:11336/840instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:05:19.14CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformamide disolvate and the zinc(II) analogue
title Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformamide disolvate and the zinc(II) analogue
spellingShingle Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformamide disolvate and the zinc(II) analogue
Harvey, Miguel Angel
Isomorphous
title_short Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformamide disolvate and the zinc(II) analogue
title_full Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformamide disolvate and the zinc(II) analogue
title_fullStr Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformamide disolvate and the zinc(II) analogue
title_full_unstemmed Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformamide disolvate and the zinc(II) analogue
title_sort Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformamide disolvate and the zinc(II) analogue
dc.creator.none.fl_str_mv Harvey, Miguel Angel
Suarez, Sebastian
Doctorovich, Fabio
Baggio, Ricardo Fortunato
author Harvey, Miguel Angel
author_facet Harvey, Miguel Angel
Suarez, Sebastian
Doctorovich, Fabio
Baggio, Ricardo Fortunato
author_role author
author2 Suarez, Sebastian
Doctorovich, Fabio
Baggio, Ricardo Fortunato
author2_role author
author
author
dc.subject.none.fl_str_mv Isomorphous
topic Isomorphous
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The isomorphous title compounds, [Tr(S4O6)(C 12H12N2)2]·2C 3H7NO (Tr = CdII and ZnII), consist of metal centres to which one tetrathionate and two 4,4′-dimethyl-2, 2′-bipyridine chelating ligands bind. The structures are completed by two symmetry-related dimethylformamide solvent molecules. Each metal-centred complex is bisected by a twofold axis running through the metal centre and halving the chelating tetrathionate dianion through the central S - S bond. The ancillary symmetry-related 4,4′-dimethyl-2,2′-bipyridine ligands act as chelates. This results in a distorted six-coordinate geometry, with similar Tr - O/N distances but central angles differing substantially from 90 and 180°. Both ligands are basically featureless from a geometric point of view, with torsion angles in both coordinated tetrathionate groups suggesting a trend linking metal size (covalent radius) and ligand 'openness'. Packing is directed by (C - H)aromatic⋯O bridges and π-π offset stacked interactions defining chains along [001], further linked by weaker (C - H)methyl⋯O bridges, some of them mediated by the dimethylformamide solvent molecules.
Fil: Harvey, Miguel Angel. Consejo Nacional de Invest.cientif.y Tecnicas. Centro Nacional Patagonico; Argentina. Universidad Nacional de la Patagonia "San Juan Bosco"; Argentina
Fil: Suarez, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Doctorovich, Fabio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina
description The isomorphous title compounds, [Tr(S4O6)(C 12H12N2)2]·2C 3H7NO (Tr = CdII and ZnII), consist of metal centres to which one tetrathionate and two 4,4′-dimethyl-2, 2′-bipyridine chelating ligands bind. The structures are completed by two symmetry-related dimethylformamide solvent molecules. Each metal-centred complex is bisected by a twofold axis running through the metal centre and halving the chelating tetrathionate dianion through the central S - S bond. The ancillary symmetry-related 4,4′-dimethyl-2,2′-bipyridine ligands act as chelates. This results in a distorted six-coordinate geometry, with similar Tr - O/N distances but central angles differing substantially from 90 and 180°. Both ligands are basically featureless from a geometric point of view, with torsion angles in both coordinated tetrathionate groups suggesting a trend linking metal size (covalent radius) and ligand 'openness'. Packing is directed by (C - H)aromatic⋯O bridges and π-π offset stacked interactions defining chains along [001], further linked by weaker (C - H)methyl⋯O bridges, some of them mediated by the dimethylformamide solvent molecules.
publishDate 2013
dc.date.none.fl_str_mv 2013-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/840
Harvey, Miguel Angel; Suarez, Sebastian; Doctorovich, Fabio; Baggio, Ricardo Fortunato; Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformamide disolvate and the zinc(II) analogue; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 69; 7; 7-2013; 745-749
0108-2701
url http://hdl.handle.net/11336/840
identifier_str_mv Harvey, Miguel Angel; Suarez, Sebastian; Doctorovich, Fabio; Baggio, Ricardo Fortunato; Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: Bis(4,4′-dimethyl-2,2′-bipyridine- κ2 N,N′)(tetrathionato-κ2 S,S′)cadmium(II) dimethylformamide disolvate and the zinc(II) analogue; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 69; 7; 7-2013; 745-749
0108-2701
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270113016521
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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