Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate

Autores
Perec, Mireille; Baggio, Ricardo Fortunato
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title copper complex, [Cu(H2P2O 7)(C15H11N3)]2·4. 5H2O, consists of two very similar independent Cu(Tpy)H 2P2O7 monomeric units (Tpy is 2,2′:6′,2″-terpyridine) plus four and a half water mol-ecules of hydration, some of which are disordered. Tpy units bind through the usual triple bite via their N atoms, and the H2P2O7 2- anions coordinate through two O atoms from two different phosphate units. Each independent CuN3O2 chromophore can be described as a slightly deformed square pyramid, with one of them having a sixth, semicoordinated, O atom from a centrosymmetrically related CuN 3O2 unit in a weakly bound second apical position suggesting an octa-hedral environment for the cation and weak dimerization of the molecule. The two independent complex molecules are connected via two strong O - H⋯O inter-actions between the phosphate groups to form hydrogen-bonded dinuclear units, further linked into [111] columns, resulting in a very complex three-dimensional supra-molecular structure through a variety of classical and nonclassical hydrogen bonds, as well as π-π interactions. © 2011 International Union of Crystallography.
Fil: Perec, Mireille. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/71996
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydratePerec, MireilleBaggio, Ricardo Fortunatohttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The title copper complex, [Cu(H2P2O 7)(C15H11N3)]2·4. 5H2O, consists of two very similar independent Cu(Tpy)H 2P2O7 monomeric units (Tpy is 2,2′:6′,2″-terpyridine) plus four and a half water mol-ecules of hydration, some of which are disordered. Tpy units bind through the usual triple bite via their N atoms, and the H2P2O7 2- anions coordinate through two O atoms from two different phosphate units. Each independent CuN3O2 chromophore can be described as a slightly deformed square pyramid, with one of them having a sixth, semicoordinated, O atom from a centrosymmetrically related CuN 3O2 unit in a weakly bound second apical position suggesting an octa-hedral environment for the cation and weak dimerization of the molecule. The two independent complex molecules are connected via two strong O - H⋯O inter-actions between the phosphate groups to form hydrogen-bonded dinuclear units, further linked into [111] columns, resulting in a very complex three-dimensional supra-molecular structure through a variety of classical and nonclassical hydrogen bonds, as well as π-π interactions. © 2011 International Union of Crystallography.Fil: Perec, Mireille. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; ArgentinaFil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaWiley Blackwell Publishing, Inc2011-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/71996Perec, Mireille; Baggio, Ricardo Fortunato; Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 67; 5; 5-2011; 140-1440108-2701CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270111012121info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S0108270111012121info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:11:55Zoai:ri.conicet.gov.ar:11336/71996instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:11:55.558CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate
title Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate
spellingShingle Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate
Perec, Mireille
title_short Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate
title_full Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate
title_fullStr Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate
title_full_unstemmed Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate
title_sort Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate
dc.creator.none.fl_str_mv Perec, Mireille
Baggio, Ricardo Fortunato
author Perec, Mireille
author_facet Perec, Mireille
Baggio, Ricardo Fortunato
author_role author
author2 Baggio, Ricardo Fortunato
author2_role author
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The title copper complex, [Cu(H2P2O 7)(C15H11N3)]2·4. 5H2O, consists of two very similar independent Cu(Tpy)H 2P2O7 monomeric units (Tpy is 2,2′:6′,2″-terpyridine) plus four and a half water mol-ecules of hydration, some of which are disordered. Tpy units bind through the usual triple bite via their N atoms, and the H2P2O7 2- anions coordinate through two O atoms from two different phosphate units. Each independent CuN3O2 chromophore can be described as a slightly deformed square pyramid, with one of them having a sixth, semicoordinated, O atom from a centrosymmetrically related CuN 3O2 unit in a weakly bound second apical position suggesting an octa-hedral environment for the cation and weak dimerization of the molecule. The two independent complex molecules are connected via two strong O - H⋯O inter-actions between the phosphate groups to form hydrogen-bonded dinuclear units, further linked into [111] columns, resulting in a very complex three-dimensional supra-molecular structure through a variety of classical and nonclassical hydrogen bonds, as well as π-π interactions. © 2011 International Union of Crystallography.
Fil: Perec, Mireille. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
description The title copper complex, [Cu(H2P2O 7)(C15H11N3)]2·4. 5H2O, consists of two very similar independent Cu(Tpy)H 2P2O7 monomeric units (Tpy is 2,2′:6′,2″-terpyridine) plus four and a half water mol-ecules of hydration, some of which are disordered. Tpy units bind through the usual triple bite via their N atoms, and the H2P2O7 2- anions coordinate through two O atoms from two different phosphate units. Each independent CuN3O2 chromophore can be described as a slightly deformed square pyramid, with one of them having a sixth, semicoordinated, O atom from a centrosymmetrically related CuN 3O2 unit in a weakly bound second apical position suggesting an octa-hedral environment for the cation and weak dimerization of the molecule. The two independent complex molecules are connected via two strong O - H⋯O inter-actions between the phosphate groups to form hydrogen-bonded dinuclear units, further linked into [111] columns, resulting in a very complex three-dimensional supra-molecular structure through a variety of classical and nonclassical hydrogen bonds, as well as π-π interactions. © 2011 International Union of Crystallography.
publishDate 2011
dc.date.none.fl_str_mv 2011-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/71996
Perec, Mireille; Baggio, Ricardo Fortunato; Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 67; 5; 5-2011; 140-144
0108-2701
CONICET Digital
CONICET
url http://hdl.handle.net/11336/71996
identifier_str_mv Perec, Mireille; Baggio, Ricardo Fortunato; Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section C-Crystal Structure Communications; 67; 5; 5-2011; 140-144
0108-2701
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270111012121
info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S0108270111012121
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
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eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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