Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidation

Autores
Musante, R.L.; Grau, Ricardo José Antonio; Baltanas, Miguel Angel
Año de publicación
2000
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A heterogeneous kinetic model which takes into account the complete physicochemical interaction of reactive species in a polar liquid phase with an ion-exchange resin acting both as selective sorbent and heterogeneous catalyst has been employed to analyze the peracetic acid synthesis from acetic acid and hydrogen peroxide in an aqueous solution. Model parameters were estimated using uncoupled data from phase equilibria, polymer sorption, chemical equilibrium and reaction kinetics. Activities rather than molar concentrations in the polymer phase and specific (dry weight of catalyst basis) rather than volume-based expressions were found to give the best constitutive equations for the heterogeneous reaction rate.
Fil: Musante, R.L.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Grau, Ricardo José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Materia
Acidic Resins;
Heterogeneous Models;
Vegetable Oil Epoxidation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/27703
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidationMusante, R.L.Grau, Ricardo José AntonioBaltanas, Miguel AngelAcidic Resins;Heterogeneous Models;Vegetable Oil Epoxidationhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A heterogeneous kinetic model which takes into account the complete physicochemical interaction of reactive species in a polar liquid phase with an ion-exchange resin acting both as selective sorbent and heterogeneous catalyst has been employed to analyze the peracetic acid synthesis from acetic acid and hydrogen peroxide in an aqueous solution. Model parameters were estimated using uncoupled data from phase equilibria, polymer sorption, chemical equilibrium and reaction kinetics. Activities rather than molar concentrations in the polymer phase and specific (dry weight of catalyst basis) rather than volume-based expressions were found to give the best constitutive equations for the heterogeneous reaction rate.Fil: Musante, R.L.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Grau, Ricardo José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaElsevier Science2000-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/mswordapplication/pdfhttp://hdl.handle.net/11336/27703Musante, R.L.; Grau, Ricardo José Antonio; Baltanas, Miguel Angel; Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidation; Elsevier Science; Applied Catalysis A: General; 197; 5-2000; 165-1730926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/S0926-860X(99)00547-5info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:35:40Zoai:ri.conicet.gov.ar:11336/27703instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:35:40.721CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidation
title Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidation
spellingShingle Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidation
Musante, R.L.
Acidic Resins;
Heterogeneous Models;
Vegetable Oil Epoxidation
title_short Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidation
title_full Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidation
title_fullStr Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidation
title_full_unstemmed Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidation
title_sort Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidation
dc.creator.none.fl_str_mv Musante, R.L.
Grau, Ricardo José Antonio
Baltanas, Miguel Angel
author Musante, R.L.
author_facet Musante, R.L.
Grau, Ricardo José Antonio
Baltanas, Miguel Angel
author_role author
author2 Grau, Ricardo José Antonio
Baltanas, Miguel Angel
author2_role author
author
dc.subject.none.fl_str_mv Acidic Resins;
Heterogeneous Models;
Vegetable Oil Epoxidation
topic Acidic Resins;
Heterogeneous Models;
Vegetable Oil Epoxidation
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv A heterogeneous kinetic model which takes into account the complete physicochemical interaction of reactive species in a polar liquid phase with an ion-exchange resin acting both as selective sorbent and heterogeneous catalyst has been employed to analyze the peracetic acid synthesis from acetic acid and hydrogen peroxide in an aqueous solution. Model parameters were estimated using uncoupled data from phase equilibria, polymer sorption, chemical equilibrium and reaction kinetics. Activities rather than molar concentrations in the polymer phase and specific (dry weight of catalyst basis) rather than volume-based expressions were found to give the best constitutive equations for the heterogeneous reaction rate.
Fil: Musante, R.L.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Grau, Ricardo José Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Baltanas, Miguel Angel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description A heterogeneous kinetic model which takes into account the complete physicochemical interaction of reactive species in a polar liquid phase with an ion-exchange resin acting both as selective sorbent and heterogeneous catalyst has been employed to analyze the peracetic acid synthesis from acetic acid and hydrogen peroxide in an aqueous solution. Model parameters were estimated using uncoupled data from phase equilibria, polymer sorption, chemical equilibrium and reaction kinetics. Activities rather than molar concentrations in the polymer phase and specific (dry weight of catalyst basis) rather than volume-based expressions were found to give the best constitutive equations for the heterogeneous reaction rate.
publishDate 2000
dc.date.none.fl_str_mv 2000-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/27703
Musante, R.L.; Grau, Ricardo José Antonio; Baltanas, Miguel Angel; Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidation; Elsevier Science; Applied Catalysis A: General; 197; 5-2000; 165-173
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/27703
identifier_str_mv Musante, R.L.; Grau, Ricardo José Antonio; Baltanas, Miguel Angel; Kinetic of liquid-phase reactions catalyzed by acidic resins: The formation of peracetic acid for vegetable oil epoxidation; Elsevier Science; Applied Catalysis A: General; 197; 5-2000; 165-173
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/S0926-860X(99)00547-5
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/msword
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083482227310592
score 13.22299

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