Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix

Autores
Verón, María Gisela; Castañeda Trujillo, Lady Diana; Piro, Oscar Enrique; Guida, Jorge Alberto
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We report here the infrared and Raman spectra of [Re(CN)5NO]3- complex as guest diluted in the KCl crystal lattice. According to the chemical analysis, the anion concentration in the KCl host matrix is in excess of 2% (in mole). The solid state Raman spectrum of this complex is reported for the first time. The information obtained from the relative intensities of infrared and Raman bands affords a reexamination of vibration mode assignments. The observed bands splitting may be explained by the interactions of the guest complex with the host lattice, including the ways in which the K+ vacancies are distributed around [Re(CN)5NO]3- to achieve lattice charge neutrality.
Fil: Verón, María Gisela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Castañeda Trujillo, Lady Diana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Guida, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina. Universidad Nacional de Luján. Departamento de Ciencias Básicas; Argentina
Materia
Rhenium Nitrosyl Complex
Kcl Matrix
Infrared And Raman Spectroscopy
X-Ray Diffraction
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/24968
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/24968
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrixVerón, María GiselaCastañeda Trujillo, Lady DianaPiro, Oscar EnriqueGuida, Jorge AlbertoRhenium Nitrosyl ComplexKcl MatrixInfrared And Raman SpectroscopyX-Ray Diffractionhttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We report here the infrared and Raman spectra of [Re(CN)5NO]3- complex as guest diluted in the KCl crystal lattice. According to the chemical analysis, the anion concentration in the KCl host matrix is in excess of 2% (in mole). The solid state Raman spectrum of this complex is reported for the first time. The information obtained from the relative intensities of infrared and Raman bands affords a reexamination of vibration mode assignments. The observed bands splitting may be explained by the interactions of the guest complex with the host lattice, including the ways in which the K+ vacancies are distributed around [Re(CN)5NO]3- to achieve lattice charge neutrality.Fil: Verón, María Gisela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Castañeda Trujillo, Lady Diana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; ArgentinaFil: Guida, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina. Universidad Nacional de Luján. Departamento de Ciencias Básicas; ArgentinaElsevier Science2014-11-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/24968Verón, María Gisela; Castañeda Trujillo, Lady Diana; Piro, Oscar Enrique; Guida, Jorge Alberto; Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix; Elsevier Science; Journal of Molecular Structure; 1076; 5-11-2014; 160-1640022-2860CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.molstruc.2014.07.057info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022286014007935info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:17:59Zoai:ri.conicet.gov.ar:11336/24968instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:17:59.23CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix
title Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix
spellingShingle Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix
Verón, María Gisela
Rhenium Nitrosyl Complex
Kcl Matrix
Infrared And Raman Spectroscopy
X-Ray Diffraction
title_short Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix
title_full Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix
title_fullStr Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix
title_full_unstemmed Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix
title_sort Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix
dc.creator.none.fl_str_mv Verón, María Gisela
Castañeda Trujillo, Lady Diana
Piro, Oscar Enrique
Guida, Jorge Alberto
author Verón, María Gisela
author_facet Verón, María Gisela
Castañeda Trujillo, Lady Diana
Piro, Oscar Enrique
Guida, Jorge Alberto
author_role author
author2 Castañeda Trujillo, Lady Diana
Piro, Oscar Enrique
Guida, Jorge Alberto
author2_role author
author
author
dc.subject.none.fl_str_mv Rhenium Nitrosyl Complex
Kcl Matrix
Infrared And Raman Spectroscopy
X-Ray Diffraction
topic Rhenium Nitrosyl Complex
Kcl Matrix
Infrared And Raman Spectroscopy
X-Ray Diffraction
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We report here the infrared and Raman spectra of [Re(CN)5NO]3- complex as guest diluted in the KCl crystal lattice. According to the chemical analysis, the anion concentration in the KCl host matrix is in excess of 2% (in mole). The solid state Raman spectrum of this complex is reported for the first time. The information obtained from the relative intensities of infrared and Raman bands affords a reexamination of vibration mode assignments. The observed bands splitting may be explained by the interactions of the guest complex with the host lattice, including the ways in which the K+ vacancies are distributed around [Re(CN)5NO]3- to achieve lattice charge neutrality.
Fil: Verón, María Gisela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Castañeda Trujillo, Lady Diana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Piro, Oscar Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Física La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Física La Plata; Argentina
Fil: Guida, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina. Universidad Nacional de Luján. Departamento de Ciencias Básicas; Argentina
description We report here the infrared and Raman spectra of [Re(CN)5NO]3- complex as guest diluted in the KCl crystal lattice. According to the chemical analysis, the anion concentration in the KCl host matrix is in excess of 2% (in mole). The solid state Raman spectrum of this complex is reported for the first time. The information obtained from the relative intensities of infrared and Raman bands affords a reexamination of vibration mode assignments. The observed bands splitting may be explained by the interactions of the guest complex with the host lattice, including the ways in which the K+ vacancies are distributed around [Re(CN)5NO]3- to achieve lattice charge neutrality.
publishDate 2014
dc.date.none.fl_str_mv 2014-11-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/24968
Verón, María Gisela; Castañeda Trujillo, Lady Diana; Piro, Oscar Enrique; Guida, Jorge Alberto; Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix; Elsevier Science; Journal of Molecular Structure; 1076; 5-11-2014; 160-164
0022-2860
CONICET Digital
CONICET
url http://hdl.handle.net/11336/24968
identifier_str_mv Verón, María Gisela; Castañeda Trujillo, Lady Diana; Piro, Oscar Enrique; Guida, Jorge Alberto; Infrared and Raman spectra of [Re(CN)5NO]3- complex isolated in KCl matrix; Elsevier Science; Journal of Molecular Structure; 1076; 5-11-2014; 160-164
0022-2860
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.molstruc.2014.07.057
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022286014007935
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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