Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing

Autores
Chinga Carrasco, Gary; Ehman, Nanci Vanesa; Pettersson, Jennifer; Vallejos, María Evangelina; Felissia, Fernando Esteban; Hakansson, Joakim; Area, Maria Cristina
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Bagasse is an underutilized agro-industrial residue with great potential as raw material for the production of cellulose nanofibrils (CNF) for a range of applications. In this study, we have assessed the suitability of bagasse for production of CNF for three-dimensional (3D) printing. First, pulp fibers were obtained from the bagasse raw material using two fractionation methods, i.e. soda and hydrothermal treatment combined with soda. Second, the pulp fibers were pretreated by TEMPO-mediated oxidation using two levels of oxidation for comparison purposes. Finally, the CNF were characterized in detail and assessed as inks for 3D printing. The results show that CNF produced from fibers obtained by hydrothermal and soda pulping were less nanofibrillated than the corresponding material produced by soda pulping. However, the CNF sample obtained from soda pulp was cytotoxic, apparently due to a larger content of silica particles. All the CNF materials were 3D printable. We conclude that the noncytotoxic CNF produced from hydrothermally and soda treated pulp can potentially be used as inks for 3D printing of biomedical devices.
Fil: Chinga Carrasco, Gary. RISE PFI; Noruega
Fil: Ehman, Nanci Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Pettersson, Jennifer. RISE Bioscience and Materials; Suecia
Fil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Hakansson, Joakim. RISE Bioscience and Materials; Suecia
Fil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Materia
3D PRINTING
BIOMEDICAL DEVICES
CHARACTERIZATION
CHEMICAL MODIFICATION
NANOCELLULOSE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/88779
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/88779
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Pulping and pretreatment affect the characteristics of bagasse inks for 3D printingChinga Carrasco, GaryEhman, Nanci VanesaPettersson, JenniferVallejos, María EvangelinaFelissia, Fernando EstebanHakansson, JoakimArea, Maria Cristina3D PRINTINGBIOMEDICAL DEVICESCHARACTERIZATIONCHEMICAL MODIFICATIONNANOCELLULOSEhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Bagasse is an underutilized agro-industrial residue with great potential as raw material for the production of cellulose nanofibrils (CNF) for a range of applications. In this study, we have assessed the suitability of bagasse for production of CNF for three-dimensional (3D) printing. First, pulp fibers were obtained from the bagasse raw material using two fractionation methods, i.e. soda and hydrothermal treatment combined with soda. Second, the pulp fibers were pretreated by TEMPO-mediated oxidation using two levels of oxidation for comparison purposes. Finally, the CNF were characterized in detail and assessed as inks for 3D printing. The results show that CNF produced from fibers obtained by hydrothermal and soda pulping were less nanofibrillated than the corresponding material produced by soda pulping. However, the CNF sample obtained from soda pulp was cytotoxic, apparently due to a larger content of silica particles. All the CNF materials were 3D printable. We conclude that the noncytotoxic CNF produced from hydrothermally and soda treated pulp can potentially be used as inks for 3D printing of biomedical devices.Fil: Chinga Carrasco, Gary. RISE PFI; NoruegaFil: Ehman, Nanci Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Pettersson, Jennifer. RISE Bioscience and Materials; SueciaFil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Hakansson, Joakim. RISE Bioscience and Materials; SueciaFil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaAmerican Chemical Society2018-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/88779Chinga Carrasco, Gary; Ehman, Nanci Vanesa; Pettersson, Jennifer; Vallejos, María Evangelina; Felissia, Fernando Esteban; et al.; Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing; American Chemical Society; ACS Sustainable Chemistry and Engineering; 6; 3; 3-2018; 4068-40752168-0485CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acssuschemeng.7b04440info:eu-repo/semantics/altIdentifier/doi/10.1021/acssuschemeng.7b04440info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:00:05Zoai:ri.conicet.gov.ar:11336/88779instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:00:05.903CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing
title Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing
spellingShingle Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing
Chinga Carrasco, Gary
3D PRINTING
BIOMEDICAL DEVICES
CHARACTERIZATION
CHEMICAL MODIFICATION
NANOCELLULOSE
title_short Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing
title_full Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing
title_fullStr Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing
title_full_unstemmed Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing
title_sort Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing
dc.creator.none.fl_str_mv Chinga Carrasco, Gary
Ehman, Nanci Vanesa
Pettersson, Jennifer
Vallejos, María Evangelina
Felissia, Fernando Esteban
Hakansson, Joakim
Area, Maria Cristina
author Chinga Carrasco, Gary
author_facet Chinga Carrasco, Gary
Ehman, Nanci Vanesa
Pettersson, Jennifer
Vallejos, María Evangelina
Felissia, Fernando Esteban
Hakansson, Joakim
Area, Maria Cristina
author_role author
author2 Ehman, Nanci Vanesa
Pettersson, Jennifer
Vallejos, María Evangelina
Felissia, Fernando Esteban
Hakansson, Joakim
Area, Maria Cristina
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv 3D PRINTING
BIOMEDICAL DEVICES
CHARACTERIZATION
CHEMICAL MODIFICATION
NANOCELLULOSE
topic 3D PRINTING
BIOMEDICAL DEVICES
CHARACTERIZATION
CHEMICAL MODIFICATION
NANOCELLULOSE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Bagasse is an underutilized agro-industrial residue with great potential as raw material for the production of cellulose nanofibrils (CNF) for a range of applications. In this study, we have assessed the suitability of bagasse for production of CNF for three-dimensional (3D) printing. First, pulp fibers were obtained from the bagasse raw material using two fractionation methods, i.e. soda and hydrothermal treatment combined with soda. Second, the pulp fibers were pretreated by TEMPO-mediated oxidation using two levels of oxidation for comparison purposes. Finally, the CNF were characterized in detail and assessed as inks for 3D printing. The results show that CNF produced from fibers obtained by hydrothermal and soda pulping were less nanofibrillated than the corresponding material produced by soda pulping. However, the CNF sample obtained from soda pulp was cytotoxic, apparently due to a larger content of silica particles. All the CNF materials were 3D printable. We conclude that the noncytotoxic CNF produced from hydrothermally and soda treated pulp can potentially be used as inks for 3D printing of biomedical devices.
Fil: Chinga Carrasco, Gary. RISE PFI; Noruega
Fil: Ehman, Nanci Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Pettersson, Jennifer. RISE Bioscience and Materials; Suecia
Fil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Hakansson, Joakim. RISE Bioscience and Materials; Suecia
Fil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
description Bagasse is an underutilized agro-industrial residue with great potential as raw material for the production of cellulose nanofibrils (CNF) for a range of applications. In this study, we have assessed the suitability of bagasse for production of CNF for three-dimensional (3D) printing. First, pulp fibers were obtained from the bagasse raw material using two fractionation methods, i.e. soda and hydrothermal treatment combined with soda. Second, the pulp fibers were pretreated by TEMPO-mediated oxidation using two levels of oxidation for comparison purposes. Finally, the CNF were characterized in detail and assessed as inks for 3D printing. The results show that CNF produced from fibers obtained by hydrothermal and soda pulping were less nanofibrillated than the corresponding material produced by soda pulping. However, the CNF sample obtained from soda pulp was cytotoxic, apparently due to a larger content of silica particles. All the CNF materials were 3D printable. We conclude that the noncytotoxic CNF produced from hydrothermally and soda treated pulp can potentially be used as inks for 3D printing of biomedical devices.
publishDate 2018
dc.date.none.fl_str_mv 2018-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/88779
Chinga Carrasco, Gary; Ehman, Nanci Vanesa; Pettersson, Jennifer; Vallejos, María Evangelina; Felissia, Fernando Esteban; et al.; Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing; American Chemical Society; ACS Sustainable Chemistry and Engineering; 6; 3; 3-2018; 4068-4075
2168-0485
CONICET Digital
CONICET
url http://hdl.handle.net/11336/88779
identifier_str_mv Chinga Carrasco, Gary; Ehman, Nanci Vanesa; Pettersson, Jennifer; Vallejos, María Evangelina; Felissia, Fernando Esteban; et al.; Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing; American Chemical Society; ACS Sustainable Chemistry and Engineering; 6; 3; 3-2018; 4068-4075
2168-0485
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acssuschemeng.7b04440
info:eu-repo/semantics/altIdentifier/doi/10.1021/acssuschemeng.7b04440
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.885934

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