Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]

Autores
Gutkowski, Karin; Freire Espeleta, Eleonora; Baggio, Ricardo
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title complex, {[Pr4(C2H3O 2)10(C2O4)(H2O)2] ·2H2O} n , was synthesized under hydro-thermal conditions from praseodymium acetate and the ionic liquid 1-butyl-3-methyl-imidazolium chloride via an in situ oxalate-ligand synthesis. The compound is a two-dimensional polymer and in the structure presents tightly bound planes parallel to (100), which are in turn linked into a three-dimensional network by hydrogen bonds involving both coordinated and solvent water mol-ecules. The oxalate anion lies across an inversion centre and acts as a bridge between pairs of Pr atoms within a tetra-nuclear segment of the polymer.
Fil: Gutkowski, Karin. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Freire Espeleta, Eleonora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Baggio, Ricardo. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Materia
IONIC LIQUIDS
CRYSTALS
PRASEODIMIUM
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/186690
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/186690
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]Gutkowski, KarinFreire Espeleta, EleonoraBaggio, RicardoIONIC LIQUIDSCRYSTALSPRASEODIMIUMhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The title complex, {[Pr4(C2H3O 2)10(C2O4)(H2O)2] ·2H2O} n , was synthesized under hydro-thermal conditions from praseodymium acetate and the ionic liquid 1-butyl-3-methyl-imidazolium chloride via an in situ oxalate-ligand synthesis. The compound is a two-dimensional polymer and in the structure presents tightly bound planes parallel to (100), which are in turn linked into a three-dimensional network by hydrogen bonds involving both coordinated and solvent water mol-ecules. The oxalate anion lies across an inversion centre and acts as a bridge between pairs of Pr atoms within a tetra-nuclear segment of the polymer.Fil: Gutkowski, Karin. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaFil: Freire Espeleta, Eleonora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; ArgentinaFil: Baggio, Ricardo. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; ArgentinaInternational Union of Crystallography2011-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/186690Gutkowski, Karin; Freire Espeleta, Eleonora; Baggio, Ricardo; Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]; International Union of Crystallography; Acta Crystallographica Section C-Crystal Structure Communications; 67; 3; 3-2011; 77-800108-2701CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://scripts.iucr.org/cgi-bin/paper?S0108270111005403info:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270111005403info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:49:15Zoai:ri.conicet.gov.ar:11336/186690instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:49:16.08CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]
title Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]
spellingShingle Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]
Gutkowski, Karin
IONIC LIQUIDS
CRYSTALS
PRASEODIMIUM
title_short Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]
title_full Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]
title_fullStr Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]
title_full_unstemmed Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]
title_sort Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]
dc.creator.none.fl_str_mv Gutkowski, Karin
Freire Espeleta, Eleonora
Baggio, Ricardo
author Gutkowski, Karin
author_facet Gutkowski, Karin
Freire Espeleta, Eleonora
Baggio, Ricardo
author_role author
author2 Freire Espeleta, Eleonora
Baggio, Ricardo
author2_role author
author
dc.subject.none.fl_str_mv IONIC LIQUIDS
CRYSTALS
PRASEODIMIUM
topic IONIC LIQUIDS
CRYSTALS
PRASEODIMIUM
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The title complex, {[Pr4(C2H3O 2)10(C2O4)(H2O)2] ·2H2O} n , was synthesized under hydro-thermal conditions from praseodymium acetate and the ionic liquid 1-butyl-3-methyl-imidazolium chloride via an in situ oxalate-ligand synthesis. The compound is a two-dimensional polymer and in the structure presents tightly bound planes parallel to (100), which are in turn linked into a three-dimensional network by hydrogen bonds involving both coordinated and solvent water mol-ecules. The oxalate anion lies across an inversion centre and acts as a bridge between pairs of Pr atoms within a tetra-nuclear segment of the polymer.
Fil: Gutkowski, Karin. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
Fil: Freire Espeleta, Eleonora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina
Fil: Baggio, Ricardo. Comisión Nacional de Energía Atómica. Centro Atómico Constituyentes; Argentina
description The title complex, {[Pr4(C2H3O 2)10(C2O4)(H2O)2] ·2H2O} n , was synthesized under hydro-thermal conditions from praseodymium acetate and the ionic liquid 1-butyl-3-methyl-imidazolium chloride via an in situ oxalate-ligand synthesis. The compound is a two-dimensional polymer and in the structure presents tightly bound planes parallel to (100), which are in turn linked into a three-dimensional network by hydrogen bonds involving both coordinated and solvent water mol-ecules. The oxalate anion lies across an inversion centre and acts as a bridge between pairs of Pr atoms within a tetra-nuclear segment of the polymer.
publishDate 2011
dc.date.none.fl_str_mv 2011-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/186690
Gutkowski, Karin; Freire Espeleta, Eleonora; Baggio, Ricardo; Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]; International Union of Crystallography; Acta Crystallographica Section C-Crystal Structure Communications; 67; 3; 3-2011; 77-80
0108-2701
CONICET Digital
CONICET
url http://hdl.handle.net/11336/186690
identifier_str_mv Gutkowski, Karin; Freire Espeleta, Eleonora; Baggio, Ricardo; Poly[[tetra-μ3-acetato-hexa-μ2-acetato-diaqua- μ2-oxalato-tetra-praseodymium(III)] dihydrate]; International Union of Crystallography; Acta Crystallographica Section C-Crystal Structure Communications; 67; 3; 3-2011; 77-80
0108-2701
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://scripts.iucr.org/cgi-bin/paper?S0108270111005403
info:eu-repo/semantics/altIdentifier/doi/10.1107/S0108270111005403
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083014436585472
score 13.22299

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