catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihyd...

Autores
Perec, Mireille; Garland, M. T.; Baggio, Ricardo Fortunato
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title compound {[Cu2Ho2(C4H5O2)10(H2O)4]·3H2O}n, is a one-dimensional 3d/4f organic-inorganic hybrid complex, the HoIII member of the isotypic lanthanoid series with Ln = GdIII, ErIII and YIII. The structure shows an alternation of Cu2 and Ho2 dinuclear units bridged by the ligands and hydrogen bonds only. The chains are composed of Cu2 classical dinuclear [eta]1:[eta]1:[mu]2 fourfold bridges [Cu...Cu = 2.6417 (9) Å] and of Ho2 units bridged by two [eta]2:[eta]1:[mu]2 carboxyl­ate units. This results in distorted square-based pyramidal CuO5 units and irregular HoO9 units. The alternating Cu2 and Ho2 units are bridged into linear arrays along the a axis by a set of one [eta]2:[eta]1:[mu]2 carboxyl­ate O atom and two hydrogen bonds with Cu...Ho separations of 4.4883 (10) and 4.5086 (10) Å. The distance between adjacent chains, as calculated by the closest and furthest distances between two chains, covers the range 10-14 Å. The H atoms of the water mol­ecules could not be located, but the O...O separations for these species suggest the presence of O-H...O hydrogen bonds.
Fil: Perec, Mireille. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Garland, M. T.. Universidad de Chile; Chile
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/83700
Acceder
id CONICETDig_b2589a856358196c2e347c7ef5fd5112
oai_identifier_str oai:ri.conicet.gov.ar:11336/83700
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]Perec, MireilleGarland, M. T.Baggio, Ricardo Fortunatohttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The title compound {[Cu2Ho2(C4H5O2)10(H2O)4]·3H2O}n, is a one-dimensional 3d/4f organic-inorganic hybrid complex, the HoIII member of the isotypic lanthanoid series with Ln = GdIII, ErIII and YIII. The structure shows an alternation of Cu2 and Ho2 dinuclear units bridged by the ligands and hydrogen bonds only. The chains are composed of Cu2 classical dinuclear [eta]1:[eta]1:[mu]2 fourfold bridges [Cu...Cu = 2.6417 (9) Å] and of Ho2 units bridged by two [eta]2:[eta]1:[mu]2 carboxyl­ate units. This results in distorted square-based pyramidal CuO5 units and irregular HoO9 units. The alternating Cu2 and Ho2 units are bridged into linear arrays along the a axis by a set of one [eta]2:[eta]1:[mu]2 carboxyl­ate O atom and two hydrogen bonds with Cu...Ho separations of 4.4883 (10) and 4.5086 (10) Å. The distance between adjacent chains, as calculated by the closest and furthest distances between two chains, covers the range 10-14 Å. The H atoms of the water mol­ecules could not be located, but the O...O separations for these species suggest the presence of O-H...O hydrogen bonds.Fil: Perec, Mireille. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; ArgentinaFil: Garland, M. T.. Universidad de Chile; ChileFil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; ArgentinaWiley Blackwell Publishing, Inc2008-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/83700Perec, Mireille; Garland, M. T.; Baggio, Ricardo Fortunato; catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section E; 64; 11; 12-2008; 1-191600-5368CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1107/s1600536808034296info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S1600536808034296info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:00:18Zoai:ri.conicet.gov.ar:11336/83700instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:00:18.932CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]
title catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]
spellingShingle catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]
Perec, Mireille
title_short catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]
title_full catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]
title_fullStr catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]
title_full_unstemmed catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]
title_sort catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]
dc.creator.none.fl_str_mv Perec, Mireille
Garland, M. T.
Baggio, Ricardo Fortunato
author Perec, Mireille
author_facet Perec, Mireille
Garland, M. T.
Baggio, Ricardo Fortunato
author_role author
author2 Garland, M. T.
Baggio, Ricardo Fortunato
author2_role author
author
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The title compound {[Cu2Ho2(C4H5O2)10(H2O)4]·3H2O}n, is a one-dimensional 3d/4f organic-inorganic hybrid complex, the HoIII member of the isotypic lanthanoid series with Ln = GdIII, ErIII and YIII. The structure shows an alternation of Cu2 and Ho2 dinuclear units bridged by the ligands and hydrogen bonds only. The chains are composed of Cu2 classical dinuclear [eta]1:[eta]1:[mu]2 fourfold bridges [Cu...Cu = 2.6417 (9) Å] and of Ho2 units bridged by two [eta]2:[eta]1:[mu]2 carboxyl­ate units. This results in distorted square-based pyramidal CuO5 units and irregular HoO9 units. The alternating Cu2 and Ho2 units are bridged into linear arrays along the a axis by a set of one [eta]2:[eta]1:[mu]2 carboxyl­ate O atom and two hydrogen bonds with Cu...Ho separations of 4.4883 (10) and 4.5086 (10) Å. The distance between adjacent chains, as calculated by the closest and furthest distances between two chains, covers the range 10-14 Å. The H atoms of the water mol­ecules could not be located, but the O...O separations for these species suggest the presence of O-H...O hydrogen bonds.
Fil: Perec, Mireille. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina
Fil: Garland, M. T.. Universidad de Chile; Chile
Fil: Baggio, Ricardo Fortunato. Comisión Nacional de Energía Atómica; Argentina
description The title compound {[Cu2Ho2(C4H5O2)10(H2O)4]·3H2O}n, is a one-dimensional 3d/4f organic-inorganic hybrid complex, the HoIII member of the isotypic lanthanoid series with Ln = GdIII, ErIII and YIII. The structure shows an alternation of Cu2 and Ho2 dinuclear units bridged by the ligands and hydrogen bonds only. The chains are composed of Cu2 classical dinuclear [eta]1:[eta]1:[mu]2 fourfold bridges [Cu...Cu = 2.6417 (9) Å] and of Ho2 units bridged by two [eta]2:[eta]1:[mu]2 carboxyl­ate units. This results in distorted square-based pyramidal CuO5 units and irregular HoO9 units. The alternating Cu2 and Ho2 units are bridged into linear arrays along the a axis by a set of one [eta]2:[eta]1:[mu]2 carboxyl­ate O atom and two hydrogen bonds with Cu...Ho separations of 4.4883 (10) and 4.5086 (10) Å. The distance between adjacent chains, as calculated by the closest and furthest distances between two chains, covers the range 10-14 Å. The H atoms of the water mol­ecules could not be located, but the O...O separations for these species suggest the presence of O-H...O hydrogen bonds.
publishDate 2008
dc.date.none.fl_str_mv 2008-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/83700
Perec, Mireille; Garland, M. T.; Baggio, Ricardo Fortunato; catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section E; 64; 11; 12-2008; 1-19
1600-5368
CONICET Digital
CONICET
url http://hdl.handle.net/11336/83700
identifier_str_mv Perec, Mireille; Garland, M. T.; Baggio, Ricardo Fortunato; catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]; Wiley Blackwell Publishing, Inc; Acta Crystallographica Section E; 64; 11; 12-2008; 1-19
1600-5368
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1107/s1600536808034296
info:eu-repo/semantics/altIdentifier/url/http://scripts.iucr.org/cgi-bin/paper?S1600536808034296
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
publisher.none.fl_str_mv Wiley Blackwell Publishing, Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083142139510784
score 13.22299

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