Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuli

Autores
Rocha, L. S. R.; Cilense, M.; Ponce, Miguel Adolfo; Aldao, Celso Manuel; Oliveira, L. L.; Longo, E.; Simoes, A. Z.
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, a lanthanum (La) doped ceria (CeO2) film, which depicted a dual gas sensing response (electric and optical) for CO(g) detection, was obtained by the microwave-assisted hydrothermal (HAM) synthesis and deposited by the screen-printing technique, in order to prevent deaths by intoxication with this life-threatening gas. An electric response under CO(g) exposure was obtained, along with an extremely fast optical response for a temperature of 380 °C, associated with Ce+4 reduction and vacancy generation. A direct optical gap was found to be around 2.31 eV from UV–Vis results, which corresponds to a transition from valence band to 4f states. Due to the anomalous electron configuration of cerium atoms with 4f electrons in its reduced state, they are likely to present an electric conduction based on the small polaron theory with a hopping mechanism responsible for its dual sensing response with a complete reversible behaviour.
Fil: Rocha, L. S. R.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Cilense, M.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Ponce, Miguel Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Aldao, Celso Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Oliveira, L. L.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Longo, E.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Simoes, A. Z.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Materia
Carbon Monoxide
Cerium Dioxide
Dual Response
Gas Sensors
Lanthanum
Thin Films
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/82528
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuliRocha, L. S. R.Cilense, M.Ponce, Miguel AdolfoAldao, Celso ManuelOliveira, L. L.Longo, E.Simoes, A. Z.Carbon MonoxideCerium DioxideDual ResponseGas SensorsLanthanumThin Filmshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this work, a lanthanum (La) doped ceria (CeO2) film, which depicted a dual gas sensing response (electric and optical) for CO(g) detection, was obtained by the microwave-assisted hydrothermal (HAM) synthesis and deposited by the screen-printing technique, in order to prevent deaths by intoxication with this life-threatening gas. An electric response under CO(g) exposure was obtained, along with an extremely fast optical response for a temperature of 380 °C, associated with Ce+4 reduction and vacancy generation. A direct optical gap was found to be around 2.31 eV from UV–Vis results, which corresponds to a transition from valence band to 4f states. Due to the anomalous electron configuration of cerium atoms with 4f electrons in its reduced state, they are likely to present an electric conduction based on the small polaron theory with a hopping mechanism responsible for its dual sensing response with a complete reversible behaviour.Fil: Rocha, L. S. R.. Universidade Estadual Paulista Julio de Mesquita Filho; BrasilFil: Cilense, M.. Universidade Estadual Paulista Julio de Mesquita Filho; BrasilFil: Ponce, Miguel Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Aldao, Celso Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Oliveira, L. L.. Universidade Estadual Paulista Julio de Mesquita Filho; BrasilFil: Longo, E.. Universidade Estadual Paulista Julio de Mesquita Filho; BrasilFil: Simoes, A. Z.. Universidade Estadual Paulista Julio de Mesquita Filho; BrasilElsevier Science2018-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/82528Rocha, L. S. R.; Cilense, M.; Ponce, Miguel Adolfo; Aldao, Celso Manuel; Oliveira, L. L.; et al.; Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuli; Elsevier Science; Physica B: Condensed Matter; 536; 5-2018; 280-2880921-4526CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0921452617308104info:eu-repo/semantics/altIdentifier/doi/10.1016/j.physb.2017.10.083info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:10:13Zoai:ri.conicet.gov.ar:11336/82528instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:10:13.423CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuli
title Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuli
spellingShingle Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuli
Rocha, L. S. R.
Carbon Monoxide
Cerium Dioxide
Dual Response
Gas Sensors
Lanthanum
Thin Films
title_short Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuli
title_full Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuli
title_fullStr Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuli
title_full_unstemmed Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuli
title_sort Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuli
dc.creator.none.fl_str_mv Rocha, L. S. R.
Cilense, M.
Ponce, Miguel Adolfo
Aldao, Celso Manuel
Oliveira, L. L.
Longo, E.
Simoes, A. Z.
author Rocha, L. S. R.
author_facet Rocha, L. S. R.
Cilense, M.
Ponce, Miguel Adolfo
Aldao, Celso Manuel
Oliveira, L. L.
Longo, E.
Simoes, A. Z.
author_role author
author2 Cilense, M.
Ponce, Miguel Adolfo
Aldao, Celso Manuel
Oliveira, L. L.
Longo, E.
Simoes, A. Z.
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv Carbon Monoxide
Cerium Dioxide
Dual Response
Gas Sensors
Lanthanum
Thin Films
topic Carbon Monoxide
Cerium Dioxide
Dual Response
Gas Sensors
Lanthanum
Thin Films
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work, a lanthanum (La) doped ceria (CeO2) film, which depicted a dual gas sensing response (electric and optical) for CO(g) detection, was obtained by the microwave-assisted hydrothermal (HAM) synthesis and deposited by the screen-printing technique, in order to prevent deaths by intoxication with this life-threatening gas. An electric response under CO(g) exposure was obtained, along with an extremely fast optical response for a temperature of 380 °C, associated with Ce+4 reduction and vacancy generation. A direct optical gap was found to be around 2.31 eV from UV–Vis results, which corresponds to a transition from valence band to 4f states. Due to the anomalous electron configuration of cerium atoms with 4f electrons in its reduced state, they are likely to present an electric conduction based on the small polaron theory with a hopping mechanism responsible for its dual sensing response with a complete reversible behaviour.
Fil: Rocha, L. S. R.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Cilense, M.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Ponce, Miguel Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Aldao, Celso Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Oliveira, L. L.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Longo, E.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
Fil: Simoes, A. Z.. Universidade Estadual Paulista Julio de Mesquita Filho; Brasil
description In this work, a lanthanum (La) doped ceria (CeO2) film, which depicted a dual gas sensing response (electric and optical) for CO(g) detection, was obtained by the microwave-assisted hydrothermal (HAM) synthesis and deposited by the screen-printing technique, in order to prevent deaths by intoxication with this life-threatening gas. An electric response under CO(g) exposure was obtained, along with an extremely fast optical response for a temperature of 380 °C, associated with Ce+4 reduction and vacancy generation. A direct optical gap was found to be around 2.31 eV from UV–Vis results, which corresponds to a transition from valence band to 4f states. Due to the anomalous electron configuration of cerium atoms with 4f electrons in its reduced state, they are likely to present an electric conduction based on the small polaron theory with a hopping mechanism responsible for its dual sensing response with a complete reversible behaviour.
publishDate 2018
dc.date.none.fl_str_mv 2018-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/82528
Rocha, L. S. R.; Cilense, M.; Ponce, Miguel Adolfo; Aldao, Celso Manuel; Oliveira, L. L.; et al.; Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuli; Elsevier Science; Physica B: Condensed Matter; 536; 5-2018; 280-288
0921-4526
CONICET Digital
CONICET
url http://hdl.handle.net/11336/82528
identifier_str_mv Rocha, L. S. R.; Cilense, M.; Ponce, Miguel Adolfo; Aldao, Celso Manuel; Oliveira, L. L.; et al.; Novel gas sensor with dual response under CO(g) exposure: Optical and electrical stimuli; Elsevier Science; Physica B: Condensed Matter; 536; 5-2018; 280-288
0921-4526
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0921452617308104
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.physb.2017.10.083
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846781461409038336
score 12.982451

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