Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media

Autores
Postigo, Jose Alberto
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This account is focused on carbon-carbon, and carbon-sulphur bond-forming reactions through the use of carbon- and sulphur-centred radicals in water, respectively. It intends to show the scope and applications on these types of radicals with a synthetic goal, thus helping the Radical Synthetic Chemist to grab the fundamental aspects devoted to the synthesis of a wide array of organic compounds through radical methods in environmentally friendly media. This account excludes the syntheses of organic substrates through the aid of organometallic / metal-centred radicals such as other Group IV-radicals and transition-metal radicals, and the important class of radical reductions currently accomplished in water through different metallic reducing species. The array of substrates synthesized through the present method encompasses intermolecular and intramolecular radical carbon-carbon bond formation reactions in water, and radical carbon-sulphur bond formation reactions. Among the radical carbon-carbon bond formation reactions, special attention is devoted to atom-transfer radical reactions, radical addition reactions to olefins, radical addition to carbon-nitrogen double bonds, and carboaminohydroxylation of alkenes, and the analogues of Knovonoegel reactions, synthesis of functionalized enol ethers, carboazidation and azidation, and ynol formation, and radical cyclization reactions in water.
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Materia
Carbon-Centred Radicals
Sulphur Centred Radicals
Radical Reactions in Water
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/13183
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous mediaPostigo, Jose AlbertoCarbon-Centred RadicalsSulphur Centred RadicalsRadical Reactions in Waterhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This account is focused on carbon-carbon, and carbon-sulphur bond-forming reactions through the use of carbon- and sulphur-centred radicals in water, respectively. It intends to show the scope and applications on these types of radicals with a synthetic goal, thus helping the Radical Synthetic Chemist to grab the fundamental aspects devoted to the synthesis of a wide array of organic compounds through radical methods in environmentally friendly media. This account excludes the syntheses of organic substrates through the aid of organometallic / metal-centred radicals such as other Group IV-radicals and transition-metal radicals, and the important class of radical reductions currently accomplished in water through different metallic reducing species. The array of substrates synthesized through the present method encompasses intermolecular and intramolecular radical carbon-carbon bond formation reactions in water, and radical carbon-sulphur bond formation reactions. Among the radical carbon-carbon bond formation reactions, special attention is devoted to atom-transfer radical reactions, radical addition reactions to olefins, radical addition to carbon-nitrogen double bonds, and carboaminohydroxylation of alkenes, and the analogues of Knovonoegel reactions, synthesis of functionalized enol ethers, carboazidation and azidation, and ynol formation, and radical cyclization reactions in water.Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; ArgentinaRoyal Society of Chemistry2011-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/13183Postigo, Jose Alberto; Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media; Royal Society of Chemistry; RSC Advances; 1; 1; 7-2011; 14-322046-2069enginfo:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2011/RA/C1RA00372K#!divAbstractinfo:eu-repo/semantics/altIdentifier/url/http://dx.doi.org/10.1039/C1RA00372Kinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:22:45Zoai:ri.conicet.gov.ar:11336/13183instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:22:45.627CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media
title Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media
spellingShingle Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media
Postigo, Jose Alberto
Carbon-Centred Radicals
Sulphur Centred Radicals
Radical Reactions in Water
title_short Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media
title_full Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media
title_fullStr Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media
title_full_unstemmed Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media
title_sort Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media
dc.creator.none.fl_str_mv Postigo, Jose Alberto
author Postigo, Jose Alberto
author_facet Postigo, Jose Alberto
author_role author
dc.subject.none.fl_str_mv Carbon-Centred Radicals
Sulphur Centred Radicals
Radical Reactions in Water
topic Carbon-Centred Radicals
Sulphur Centred Radicals
Radical Reactions in Water
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This account is focused on carbon-carbon, and carbon-sulphur bond-forming reactions through the use of carbon- and sulphur-centred radicals in water, respectively. It intends to show the scope and applications on these types of radicals with a synthetic goal, thus helping the Radical Synthetic Chemist to grab the fundamental aspects devoted to the synthesis of a wide array of organic compounds through radical methods in environmentally friendly media. This account excludes the syntheses of organic substrates through the aid of organometallic / metal-centred radicals such as other Group IV-radicals and transition-metal radicals, and the important class of radical reductions currently accomplished in water through different metallic reducing species. The array of substrates synthesized through the present method encompasses intermolecular and intramolecular radical carbon-carbon bond formation reactions in water, and radical carbon-sulphur bond formation reactions. Among the radical carbon-carbon bond formation reactions, special attention is devoted to atom-transfer radical reactions, radical addition reactions to olefins, radical addition to carbon-nitrogen double bonds, and carboaminohydroxylation of alkenes, and the analogues of Knovonoegel reactions, synthesis of functionalized enol ethers, carboazidation and azidation, and ynol formation, and radical cyclization reactions in water.
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
description This account is focused on carbon-carbon, and carbon-sulphur bond-forming reactions through the use of carbon- and sulphur-centred radicals in water, respectively. It intends to show the scope and applications on these types of radicals with a synthetic goal, thus helping the Radical Synthetic Chemist to grab the fundamental aspects devoted to the synthesis of a wide array of organic compounds through radical methods in environmentally friendly media. This account excludes the syntheses of organic substrates through the aid of organometallic / metal-centred radicals such as other Group IV-radicals and transition-metal radicals, and the important class of radical reductions currently accomplished in water through different metallic reducing species. The array of substrates synthesized through the present method encompasses intermolecular and intramolecular radical carbon-carbon bond formation reactions in water, and radical carbon-sulphur bond formation reactions. Among the radical carbon-carbon bond formation reactions, special attention is devoted to atom-transfer radical reactions, radical addition reactions to olefins, radical addition to carbon-nitrogen double bonds, and carboaminohydroxylation of alkenes, and the analogues of Knovonoegel reactions, synthesis of functionalized enol ethers, carboazidation and azidation, and ynol formation, and radical cyclization reactions in water.
publishDate 2011
dc.date.none.fl_str_mv 2011-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/13183
Postigo, Jose Alberto; Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media; Royal Society of Chemistry; RSC Advances; 1; 1; 7-2011; 14-32
2046-2069
url http://hdl.handle.net/11336/13183
identifier_str_mv Postigo, Jose Alberto; Synthetically useful carbon-carbon and carbon-sulphur bond constructions mediated by carbon- and sulphur-centred radicals in water and aqueous media; Royal Society of Chemistry; RSC Advances; 1; 1; 7-2011; 14-32
2046-2069
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2011/RA/C1RA00372K#!divAbstract
info:eu-repo/semantics/altIdentifier/url/http://dx.doi.org/10.1039/C1RA00372K
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.48226

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