Reactivity of fluorinated organic radicals in aqueous media

Autores
Barata Vallejo, Sebastian; Postigo, Jose Alberto
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Fluorinated radicals in water are shown to enable a useful array of synthetic organic transformations, reflecting these intermediates' distinct behavior in water or aqueous media. The enhanced reactivities of perfluroalkyl radicals in water facilitate their addition reactions to carbon–carbon and carbon–heteroatom multiple bonds. Activated and unactivated unsaturated substrates are equally reactive candidates for radical perfluoroalkylation reactions in aqueous systems. Parallel behavior of perfluorinated radicals in organic solvents and in water is presented, demonstrating the scope of reactions based on fluorinated radicals in aqueous media, as well as the ease of carbocyclic construction.
Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Radical Reactions
Green Chemistry
Radicals in Water
Fluorinated Radicals
Reaction Mechanisms
Fluorous Media
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/16272
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Reactivity of fluorinated organic radicals in aqueous mediaBarata Vallejo, SebastianPostigo, Jose AlbertoRadical ReactionsGreen ChemistryRadicals in WaterFluorinated RadicalsReaction MechanismsFluorous Mediahttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Fluorinated radicals in water are shown to enable a useful array of synthetic organic transformations, reflecting these intermediates' distinct behavior in water or aqueous media. The enhanced reactivities of perfluroalkyl radicals in water facilitate their addition reactions to carbon–carbon and carbon–heteroatom multiple bonds. Activated and unactivated unsaturated substrates are equally reactive candidates for radical perfluoroalkylation reactions in aqueous systems. Parallel behavior of perfluorinated radicals in organic solvents and in water is presented, demonstrating the scope of reactions based on fluorinated radicals in aqueous media, as well as the ease of carbocyclic construction.Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaWiley VCH Verlag2012-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/16272Barata Vallejo, Sebastian; Postigo, Jose Alberto; Reactivity of fluorinated organic radicals in aqueous media; Wiley VCH Verlag; European Journal of Organic Chemistry; 2012; 10; 4-2012; 1889-18991434-193Xenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/ejoc.201101808info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201101808/abstractinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:22:58Zoai:ri.conicet.gov.ar:11336/16272instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:22:58.745CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Reactivity of fluorinated organic radicals in aqueous media
title Reactivity of fluorinated organic radicals in aqueous media
spellingShingle Reactivity of fluorinated organic radicals in aqueous media
Barata Vallejo, Sebastian
Radical Reactions
Green Chemistry
Radicals in Water
Fluorinated Radicals
Reaction Mechanisms
Fluorous Media
title_short Reactivity of fluorinated organic radicals in aqueous media
title_full Reactivity of fluorinated organic radicals in aqueous media
title_fullStr Reactivity of fluorinated organic radicals in aqueous media
title_full_unstemmed Reactivity of fluorinated organic radicals in aqueous media
title_sort Reactivity of fluorinated organic radicals in aqueous media
dc.creator.none.fl_str_mv Barata Vallejo, Sebastian
Postigo, Jose Alberto
author Barata Vallejo, Sebastian
author_facet Barata Vallejo, Sebastian
Postigo, Jose Alberto
author_role author
author2 Postigo, Jose Alberto
author2_role author
dc.subject.none.fl_str_mv Radical Reactions
Green Chemistry
Radicals in Water
Fluorinated Radicals
Reaction Mechanisms
Fluorous Media
topic Radical Reactions
Green Chemistry
Radicals in Water
Fluorinated Radicals
Reaction Mechanisms
Fluorous Media
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Fluorinated radicals in water are shown to enable a useful array of synthetic organic transformations, reflecting these intermediates' distinct behavior in water or aqueous media. The enhanced reactivities of perfluroalkyl radicals in water facilitate their addition reactions to carbon–carbon and carbon–heteroatom multiple bonds. Activated and unactivated unsaturated substrates are equally reactive candidates for radical perfluoroalkylation reactions in aqueous systems. Parallel behavior of perfluorinated radicals in organic solvents and in water is presented, demonstrating the scope of reactions based on fluorinated radicals in aqueous media, as well as the ease of carbocyclic construction.
Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description Fluorinated radicals in water are shown to enable a useful array of synthetic organic transformations, reflecting these intermediates' distinct behavior in water or aqueous media. The enhanced reactivities of perfluroalkyl radicals in water facilitate their addition reactions to carbon–carbon and carbon–heteroatom multiple bonds. Activated and unactivated unsaturated substrates are equally reactive candidates for radical perfluoroalkylation reactions in aqueous systems. Parallel behavior of perfluorinated radicals in organic solvents and in water is presented, demonstrating the scope of reactions based on fluorinated radicals in aqueous media, as well as the ease of carbocyclic construction.
publishDate 2012
dc.date.none.fl_str_mv 2012-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/16272
Barata Vallejo, Sebastian; Postigo, Jose Alberto; Reactivity of fluorinated organic radicals in aqueous media; Wiley VCH Verlag; European Journal of Organic Chemistry; 2012; 10; 4-2012; 1889-1899
1434-193X
url http://hdl.handle.net/11336/16272
identifier_str_mv Barata Vallejo, Sebastian; Postigo, Jose Alberto; Reactivity of fluorinated organic radicals in aqueous media; Wiley VCH Verlag; European Journal of Organic Chemistry; 2012; 10; 4-2012; 1889-1899
1434-193X
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/ejoc.201101808
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201101808/abstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.493442

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