Synthesis and Properties of Fumaric Copolymers as Potential Bitumen Modifiers

Autores
Oberti, Tamara Gisela; Larsen, Diego; Cortizo, Maria Susana
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
New copolymers of dioctyl fumarate (DOF) and styrene (S) were synthetized by radical polymerization and used to modify bitumen. The poly(dioctyl fumarate-co-styrene) copolymers, PFS, were characterized by 1H-NMR and FTIR spectroscopies and size exclusion chromatography (SEC) in order to determine their monomer composition and weight average molecular weights, respectively. The polymer-bitumen blending conditions were optimized and the samples analyzed by different methodologies. Fluorescence microscopy, rotational viscosity and differential scanning calorimetry (DSC) were used to study the morphological changes of blends during their manufacturing and the rheological and thermal behavior, respectively. All modified bitumen (MB) exhibited higher viscosity than the based bitumen (BB) under studied conditions and this effect was more evident for the MB containing the higher molecular weight polymer. The addition of polymers to BB enhances the bitumen viscosity and thus increased the energy required for the flowing (activation energy calculated by Arrhenius equation). Thermal and morphological analysis showed that all MB exhibited good polymer- bitumen compatibility, which could be consider as a good starting point for a potential applications of this new material in road engineering.
Fil: Oberti, Tamara Gisela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Larsen, Diego. Universidad Nacional de La Plata. Facultad de Ingeniería. Departamento de Construcciones; Argentina
Fil: Cortizo, Maria Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Materia
COMPATIBILITY
FUMARIC COPOLYMER
MODIFIED BITUMEN
RHEOLOGICAL PROPERTIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/100109
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Synthesis and Properties of Fumaric Copolymers as Potential Bitumen ModifiersOberti, Tamara GiselaLarsen, DiegoCortizo, Maria SusanaCOMPATIBILITYFUMARIC COPOLYMERMODIFIED BITUMENRHEOLOGICAL PROPERTIEShttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2New copolymers of dioctyl fumarate (DOF) and styrene (S) were synthetized by radical polymerization and used to modify bitumen. The poly(dioctyl fumarate-co-styrene) copolymers, PFS, were characterized by 1H-NMR and FTIR spectroscopies and size exclusion chromatography (SEC) in order to determine their monomer composition and weight average molecular weights, respectively. The polymer-bitumen blending conditions were optimized and the samples analyzed by different methodologies. Fluorescence microscopy, rotational viscosity and differential scanning calorimetry (DSC) were used to study the morphological changes of blends during their manufacturing and the rheological and thermal behavior, respectively. All modified bitumen (MB) exhibited higher viscosity than the based bitumen (BB) under studied conditions and this effect was more evident for the MB containing the higher molecular weight polymer. The addition of polymers to BB enhances the bitumen viscosity and thus increased the energy required for the flowing (activation energy calculated by Arrhenius equation). Thermal and morphological analysis showed that all MB exhibited good polymer- bitumen compatibility, which could be consider as a good starting point for a potential applications of this new material in road engineering.Fil: Oberti, Tamara Gisela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Larsen, Diego. Universidad Nacional de La Plata. Facultad de Ingeniería. Departamento de Construcciones; ArgentinaFil: Cortizo, Maria Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaTaylor & Francis2018-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/100109Oberti, Tamara Gisela; Larsen, Diego; Cortizo, Maria Susana; Synthesis and Properties of Fumaric Copolymers as Potential Bitumen Modifiers; Taylor & Francis; Polymer-Plastics Technology and Materials; 58; 4; 5-2018; 443-4530360-25592574-089XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/03602559.2018.1471722?journalCode=lpte21info:eu-repo/semantics/altIdentifier/doi/10.1080/03602559.2018.1471722info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:19:22Zoai:ri.conicet.gov.ar:11336/100109instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:19:23.156CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Synthesis and Properties of Fumaric Copolymers as Potential Bitumen Modifiers
title Synthesis and Properties of Fumaric Copolymers as Potential Bitumen Modifiers
spellingShingle Synthesis and Properties of Fumaric Copolymers as Potential Bitumen Modifiers
Oberti, Tamara Gisela
COMPATIBILITY
FUMARIC COPOLYMER
MODIFIED BITUMEN
RHEOLOGICAL PROPERTIES
title_short Synthesis and Properties of Fumaric Copolymers as Potential Bitumen Modifiers
title_full Synthesis and Properties of Fumaric Copolymers as Potential Bitumen Modifiers
title_fullStr Synthesis and Properties of Fumaric Copolymers as Potential Bitumen Modifiers
title_full_unstemmed Synthesis and Properties of Fumaric Copolymers as Potential Bitumen Modifiers
title_sort Synthesis and Properties of Fumaric Copolymers as Potential Bitumen Modifiers
dc.creator.none.fl_str_mv Oberti, Tamara Gisela
Larsen, Diego
Cortizo, Maria Susana
author Oberti, Tamara Gisela
author_facet Oberti, Tamara Gisela
Larsen, Diego
Cortizo, Maria Susana
author_role author
author2 Larsen, Diego
Cortizo, Maria Susana
author2_role author
author
dc.subject.none.fl_str_mv COMPATIBILITY
FUMARIC COPOLYMER
MODIFIED BITUMEN
RHEOLOGICAL PROPERTIES
topic COMPATIBILITY
FUMARIC COPOLYMER
MODIFIED BITUMEN
RHEOLOGICAL PROPERTIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv New copolymers of dioctyl fumarate (DOF) and styrene (S) were synthetized by radical polymerization and used to modify bitumen. The poly(dioctyl fumarate-co-styrene) copolymers, PFS, were characterized by 1H-NMR and FTIR spectroscopies and size exclusion chromatography (SEC) in order to determine their monomer composition and weight average molecular weights, respectively. The polymer-bitumen blending conditions were optimized and the samples analyzed by different methodologies. Fluorescence microscopy, rotational viscosity and differential scanning calorimetry (DSC) were used to study the morphological changes of blends during their manufacturing and the rheological and thermal behavior, respectively. All modified bitumen (MB) exhibited higher viscosity than the based bitumen (BB) under studied conditions and this effect was more evident for the MB containing the higher molecular weight polymer. The addition of polymers to BB enhances the bitumen viscosity and thus increased the energy required for the flowing (activation energy calculated by Arrhenius equation). Thermal and morphological analysis showed that all MB exhibited good polymer- bitumen compatibility, which could be consider as a good starting point for a potential applications of this new material in road engineering.
Fil: Oberti, Tamara Gisela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Larsen, Diego. Universidad Nacional de La Plata. Facultad de Ingeniería. Departamento de Construcciones; Argentina
Fil: Cortizo, Maria Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
description New copolymers of dioctyl fumarate (DOF) and styrene (S) were synthetized by radical polymerization and used to modify bitumen. The poly(dioctyl fumarate-co-styrene) copolymers, PFS, were characterized by 1H-NMR and FTIR spectroscopies and size exclusion chromatography (SEC) in order to determine their monomer composition and weight average molecular weights, respectively. The polymer-bitumen blending conditions were optimized and the samples analyzed by different methodologies. Fluorescence microscopy, rotational viscosity and differential scanning calorimetry (DSC) were used to study the morphological changes of blends during their manufacturing and the rheological and thermal behavior, respectively. All modified bitumen (MB) exhibited higher viscosity than the based bitumen (BB) under studied conditions and this effect was more evident for the MB containing the higher molecular weight polymer. The addition of polymers to BB enhances the bitumen viscosity and thus increased the energy required for the flowing (activation energy calculated by Arrhenius equation). Thermal and morphological analysis showed that all MB exhibited good polymer- bitumen compatibility, which could be consider as a good starting point for a potential applications of this new material in road engineering.
publishDate 2018
dc.date.none.fl_str_mv 2018-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/100109
Oberti, Tamara Gisela; Larsen, Diego; Cortizo, Maria Susana; Synthesis and Properties of Fumaric Copolymers as Potential Bitumen Modifiers; Taylor & Francis; Polymer-Plastics Technology and Materials; 58; 4; 5-2018; 443-453
0360-2559
2574-089X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/100109
identifier_str_mv Oberti, Tamara Gisela; Larsen, Diego; Cortizo, Maria Susana; Synthesis and Properties of Fumaric Copolymers as Potential Bitumen Modifiers; Taylor & Francis; Polymer-Plastics Technology and Materials; 58; 4; 5-2018; 443-453
0360-2559
2574-089X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.1080/03602559.2018.1471722?journalCode=lpte21
info:eu-repo/semantics/altIdentifier/doi/10.1080/03602559.2018.1471722
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis
publisher.none.fl_str_mv Taylor & Francis
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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