Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route

Autores
Oestreicher, Víctor Santiago Jesús; Jobbagy, Matias
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Highly crystalline HKUST-1 and COK-16-like phases were obtained based on a mild in situ alkalinization one-pot epoxide driven method. A slurry composed of finely ground trimesic acid, H3BTC, dispersed in a CuCl2 aqueous solution quantitatively developed well crystallized HKUST-1 after the addition of propylene oxide. The use of solid H3BTC ensures a low concentration of free linker, favoring crystalline growth over the precipitation of amorphous or metastable impurities. An extreme space-time yield of 2.1 × 105 kg m-3 day-1 was reached, with no linker excess and minimum use of solvent. The method was equally efficient in the achievement of pure NENU/COK-16 phases, containing [PW12O40]3-, [PMo12O40]3- and [SiMo12O40]4- polyoxometalates.
Fil: Oestreicher, Víctor Santiago Jesús. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Jobbagy, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Materia
Mof
Epóxidos
Alto Rendimiento
Ecodesign
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
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CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
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oai:ri.conicet.gov.ar:11336/65219
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide routeOestreicher, Víctor Santiago JesúsJobbagy, MatiasMofEpóxidosAlto RendimientoEcodesignhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Highly crystalline HKUST-1 and COK-16-like phases were obtained based on a mild in situ alkalinization one-pot epoxide driven method. A slurry composed of finely ground trimesic acid, H3BTC, dispersed in a CuCl2 aqueous solution quantitatively developed well crystallized HKUST-1 after the addition of propylene oxide. The use of solid H3BTC ensures a low concentration of free linker, favoring crystalline growth over the precipitation of amorphous or metastable impurities. An extreme space-time yield of 2.1 × 105 kg m-3 day-1 was reached, with no linker excess and minimum use of solvent. The method was equally efficient in the achievement of pure NENU/COK-16 phases, containing [PW12O40]3-, [PMo12O40]3- and [SiMo12O40]4- polyoxometalates.Fil: Oestreicher, Víctor Santiago Jesús. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaFil: Jobbagy, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; ArgentinaRoyal Society of Chemistry2017-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/65219Oestreicher, Víctor Santiago Jesús; Jobbagy, Matias; Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route; Royal Society of Chemistry; Chemical Communications; 53; 24; 3-2017; 3466-34681359-7345CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1039/c7cc00737jinfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2017/CC/C7CC00737Jinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:48Zoai:ri.conicet.gov.ar:11336/65219instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:48.934CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
title Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
spellingShingle Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
Oestreicher, Víctor Santiago Jesús
Mof
Epóxidos
Alto Rendimiento
Ecodesign
title_short Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
title_full Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
title_fullStr Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
title_full_unstemmed Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
title_sort Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route
dc.creator.none.fl_str_mv Oestreicher, Víctor Santiago Jesús
Jobbagy, Matias
author Oestreicher, Víctor Santiago Jesús
author_facet Oestreicher, Víctor Santiago Jesús
Jobbagy, Matias
author_role author
author2 Jobbagy, Matias
author2_role author
dc.subject.none.fl_str_mv Mof
Epóxidos
Alto Rendimiento
Ecodesign
topic Mof
Epóxidos
Alto Rendimiento
Ecodesign
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Highly crystalline HKUST-1 and COK-16-like phases were obtained based on a mild in situ alkalinization one-pot epoxide driven method. A slurry composed of finely ground trimesic acid, H3BTC, dispersed in a CuCl2 aqueous solution quantitatively developed well crystallized HKUST-1 after the addition of propylene oxide. The use of solid H3BTC ensures a low concentration of free linker, favoring crystalline growth over the precipitation of amorphous or metastable impurities. An extreme space-time yield of 2.1 × 105 kg m-3 day-1 was reached, with no linker excess and minimum use of solvent. The method was equally efficient in the achievement of pure NENU/COK-16 phases, containing [PW12O40]3-, [PMo12O40]3- and [SiMo12O40]4- polyoxometalates.
Fil: Oestreicher, Víctor Santiago Jesús. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
Fil: Jobbagy, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina
description Highly crystalline HKUST-1 and COK-16-like phases were obtained based on a mild in situ alkalinization one-pot epoxide driven method. A slurry composed of finely ground trimesic acid, H3BTC, dispersed in a CuCl2 aqueous solution quantitatively developed well crystallized HKUST-1 after the addition of propylene oxide. The use of solid H3BTC ensures a low concentration of free linker, favoring crystalline growth over the precipitation of amorphous or metastable impurities. An extreme space-time yield of 2.1 × 105 kg m-3 day-1 was reached, with no linker excess and minimum use of solvent. The method was equally efficient in the achievement of pure NENU/COK-16 phases, containing [PW12O40]3-, [PMo12O40]3- and [SiMo12O40]4- polyoxometalates.
publishDate 2017
dc.date.none.fl_str_mv 2017-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/65219
Oestreicher, Víctor Santiago Jesús; Jobbagy, Matias; Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route; Royal Society of Chemistry; Chemical Communications; 53; 24; 3-2017; 3466-3468
1359-7345
CONICET Digital
CONICET
url http://hdl.handle.net/11336/65219
identifier_str_mv Oestreicher, Víctor Santiago Jesús; Jobbagy, Matias; Extremely efficient crystallization of HKUST-1 and Keggin-loaded related phases through the epoxide route; Royal Society of Chemistry; Chemical Communications; 53; 24; 3-2017; 3466-3468
1359-7345
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1039/c7cc00737j
info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/en/Content/ArticleLanding/2017/CC/C7CC00737J
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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