Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminants

Autores
Fernandez, Maria Emilia; Ledesma, B.; Román, S.; Bonelli, Pablo Ricardo; Cukierman, Ana Lea
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Activated hydrochars obtained from the hydrothermal carbonization of orange peels (Citrus sinensis) followed by various thermochemical processing were assessed as adsorbents for emerging contaminants in water. Thermal activation under flows of CO2 or air as well as chemical activation with phosphoric acid were applied to the hydrochars. Their characteristics were analyzed and related to their ability to uptake three pharmaceuticals (diclofenac sodium, salicylic acid and flurbiprofen) considered as emerging contaminants. The hydrothermal carbonization and subsequent activations promoted substantial chemical transformations which affected the surface properties of the activated hydrochars; they exhibited specific surface areas ranging from 300 to ∼620 m2/g. Morphological characterization showed the development of coral-like microspheres dominating the surface of most hydrochars. Their ability to adsorb the three pharmaceuticals selected was found largely dependent on whether the molecules were ionized or in their neutral form and on the porosity developed by the new adsorbents.
Fil: Fernandez, Maria Emilia. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ledesma, B.. Universidad de Extremadura; España
Fil: Román, S.. Universidad de Extremadura; España
Fil: Bonelli, Pablo Ricardo. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cukierman, Ana Lea. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Tecnología Farmacéutica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Activated Hydrochars
Emerging Contaminants
Hydrothermal Carbonization
Orange Peels
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/43188
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminantsFernandez, Maria EmiliaLedesma, B.Román, S.Bonelli, Pablo RicardoCukierman, Ana LeaActivated HydrocharsEmerging ContaminantsHydrothermal CarbonizationOrange Peelshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Activated hydrochars obtained from the hydrothermal carbonization of orange peels (Citrus sinensis) followed by various thermochemical processing were assessed as adsorbents for emerging contaminants in water. Thermal activation under flows of CO2 or air as well as chemical activation with phosphoric acid were applied to the hydrochars. Their characteristics were analyzed and related to their ability to uptake three pharmaceuticals (diclofenac sodium, salicylic acid and flurbiprofen) considered as emerging contaminants. The hydrothermal carbonization and subsequent activations promoted substantial chemical transformations which affected the surface properties of the activated hydrochars; they exhibited specific surface areas ranging from 300 to ∼620 m2/g. Morphological characterization showed the development of coral-like microspheres dominating the surface of most hydrochars. Their ability to adsorb the three pharmaceuticals selected was found largely dependent on whether the molecules were ionized or in their neutral form and on the porosity developed by the new adsorbents.Fil: Fernandez, Maria Emilia. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Ledesma, B.. Universidad de Extremadura; EspañaFil: Román, S.. Universidad de Extremadura; EspañaFil: Bonelli, Pablo Ricardo. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Cukierman, Ana Lea. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Tecnología Farmacéutica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier2015-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/43188Fernandez, Maria Emilia; Ledesma, B.; Román, S.; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminants; Elsevier; Bioresource Technology; 183; 5-2015; 221-2280960-8524CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.biortech.2015.02.035info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0960852415002047info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:56:16Zoai:ri.conicet.gov.ar:11336/43188instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:56:17.054CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminants
title Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminants
spellingShingle Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminants
Fernandez, Maria Emilia
Activated Hydrochars
Emerging Contaminants
Hydrothermal Carbonization
Orange Peels
title_short Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminants
title_full Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminants
title_fullStr Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminants
title_full_unstemmed Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminants
title_sort Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminants
dc.creator.none.fl_str_mv Fernandez, Maria Emilia
Ledesma, B.
Román, S.
Bonelli, Pablo Ricardo
Cukierman, Ana Lea
author Fernandez, Maria Emilia
author_facet Fernandez, Maria Emilia
Ledesma, B.
Román, S.
Bonelli, Pablo Ricardo
Cukierman, Ana Lea
author_role author
author2 Ledesma, B.
Román, S.
Bonelli, Pablo Ricardo
Cukierman, Ana Lea
author2_role author
author
author
author
dc.subject.none.fl_str_mv Activated Hydrochars
Emerging Contaminants
Hydrothermal Carbonization
Orange Peels
topic Activated Hydrochars
Emerging Contaminants
Hydrothermal Carbonization
Orange Peels
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Activated hydrochars obtained from the hydrothermal carbonization of orange peels (Citrus sinensis) followed by various thermochemical processing were assessed as adsorbents for emerging contaminants in water. Thermal activation under flows of CO2 or air as well as chemical activation with phosphoric acid were applied to the hydrochars. Their characteristics were analyzed and related to their ability to uptake three pharmaceuticals (diclofenac sodium, salicylic acid and flurbiprofen) considered as emerging contaminants. The hydrothermal carbonization and subsequent activations promoted substantial chemical transformations which affected the surface properties of the activated hydrochars; they exhibited specific surface areas ranging from 300 to ∼620 m2/g. Morphological characterization showed the development of coral-like microspheres dominating the surface of most hydrochars. Their ability to adsorb the three pharmaceuticals selected was found largely dependent on whether the molecules were ionized or in their neutral form and on the porosity developed by the new adsorbents.
Fil: Fernandez, Maria Emilia. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Ledesma, B.. Universidad de Extremadura; España
Fil: Román, S.. Universidad de Extremadura; España
Fil: Bonelli, Pablo Ricardo. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Cukierman, Ana Lea. Universidad de Buenos Aires. Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Tecnología Farmacéutica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description Activated hydrochars obtained from the hydrothermal carbonization of orange peels (Citrus sinensis) followed by various thermochemical processing were assessed as adsorbents for emerging contaminants in water. Thermal activation under flows of CO2 or air as well as chemical activation with phosphoric acid were applied to the hydrochars. Their characteristics were analyzed and related to their ability to uptake three pharmaceuticals (diclofenac sodium, salicylic acid and flurbiprofen) considered as emerging contaminants. The hydrothermal carbonization and subsequent activations promoted substantial chemical transformations which affected the surface properties of the activated hydrochars; they exhibited specific surface areas ranging from 300 to ∼620 m2/g. Morphological characterization showed the development of coral-like microspheres dominating the surface of most hydrochars. Their ability to adsorb the three pharmaceuticals selected was found largely dependent on whether the molecules were ionized or in their neutral form and on the porosity developed by the new adsorbents.
publishDate 2015
dc.date.none.fl_str_mv 2015-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/43188
Fernandez, Maria Emilia; Ledesma, B.; Román, S.; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminants; Elsevier; Bioresource Technology; 183; 5-2015; 221-228
0960-8524
CONICET Digital
CONICET
url http://hdl.handle.net/11336/43188
identifier_str_mv Fernandez, Maria Emilia; Ledesma, B.; Román, S.; Bonelli, Pablo Ricardo; Cukierman, Ana Lea; Development and characterization of activated hydrochars from orange peels as potential adsorbents for emerging organic contaminants; Elsevier; Bioresource Technology; 183; 5-2015; 221-228
0960-8524
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.biortech.2015.02.035
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0960852415002047
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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