Revisiting the hydrogenation of sunflower oil over a Ni catalyst

Autores
Fernández, María Belén; Tonetto, Gabriela Marta; Crapiste, Guillermo Hector; Damiani, Daniel Eduardo
Año de publicación
2007
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In the present paper the performance of commercial Ni catalyst in edible oil hydrogenation is evaluated under different operating conditions. Particularly, the influence of mass transport resistance on the trans-isomers selectivity is analyzed. Initially a series of experiments aim to analyze the effect of four process variables (reaction temperature, hydrogen bubbling device, agitation rate and stirrer design) on catalyst activity and selectivity to trans-isomers. These experiments are conducted in diffusional regimes. A simpler set of experiments is carried out operating under conditions that allow the authors to neglect some diffusional resistances although those associated to the catalyst are still present. In the first case activity and selectivity appear to be independent of the hydrogen bubbling system and the catalyst loading. The whole set of data analyzed in terms of the C18:1/C18:20 ratio as a function of the C18:2/C18:20 ratio shows that the former, a sort of selectivity, depends on the agitation regime. The formation of trans-isomers however, appears to be a function of the reaction extent only.
Fil: Fernández, María Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Crapiste, Guillermo Hector. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Hydrogenation
Nickel
Sfc
Sunflower Oil
Trans-Isomers
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/83517
Acceder
id CONICETDig_e39a79226607c12c83b3a3ea3f3e0bdc
oai_identifier_str oai:ri.conicet.gov.ar:11336/83517
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Revisiting the hydrogenation of sunflower oil over a Ni catalystFernández, María BelénTonetto, Gabriela MartaCrapiste, Guillermo HectorDamiani, Daniel EduardoHydrogenationNickelSfcSunflower OilTrans-Isomershttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In the present paper the performance of commercial Ni catalyst in edible oil hydrogenation is evaluated under different operating conditions. Particularly, the influence of mass transport resistance on the trans-isomers selectivity is analyzed. Initially a series of experiments aim to analyze the effect of four process variables (reaction temperature, hydrogen bubbling device, agitation rate and stirrer design) on catalyst activity and selectivity to trans-isomers. These experiments are conducted in diffusional regimes. A simpler set of experiments is carried out operating under conditions that allow the authors to neglect some diffusional resistances although those associated to the catalyst are still present. In the first case activity and selectivity appear to be independent of the hydrogen bubbling system and the catalyst loading. The whole set of data analyzed in terms of the C18:1/C18:20 ratio as a function of the C18:2/C18:20 ratio shows that the former, a sort of selectivity, depends on the agitation regime. The formation of trans-isomers however, appears to be a function of the reaction extent only.Fil: Fernández, María Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Crapiste, Guillermo Hector. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaElsevier2007-02-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/83517Fernández, María Belén; Tonetto, Gabriela Marta; Crapiste, Guillermo Hector; Damiani, Daniel Eduardo; Revisiting the hydrogenation of sunflower oil over a Ni catalyst; Elsevier; Journal of Food Engineering; 82; 2; 21-2-2007; 199-2080260-8774CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0260877407000908info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jfoodeng.2007.02.010info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:38:59Zoai:ri.conicet.gov.ar:11336/83517instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:38:59.819CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Revisiting the hydrogenation of sunflower oil over a Ni catalyst
title Revisiting the hydrogenation of sunflower oil over a Ni catalyst
spellingShingle Revisiting the hydrogenation of sunflower oil over a Ni catalyst
Fernández, María Belén
Hydrogenation
Nickel
Sfc
Sunflower Oil
Trans-Isomers
title_short Revisiting the hydrogenation of sunflower oil over a Ni catalyst
title_full Revisiting the hydrogenation of sunflower oil over a Ni catalyst
title_fullStr Revisiting the hydrogenation of sunflower oil over a Ni catalyst
title_full_unstemmed Revisiting the hydrogenation of sunflower oil over a Ni catalyst
title_sort Revisiting the hydrogenation of sunflower oil over a Ni catalyst
dc.creator.none.fl_str_mv Fernández, María Belén
Tonetto, Gabriela Marta
Crapiste, Guillermo Hector
Damiani, Daniel Eduardo
author Fernández, María Belén
author_facet Fernández, María Belén
Tonetto, Gabriela Marta
Crapiste, Guillermo Hector
Damiani, Daniel Eduardo
author_role author
author2 Tonetto, Gabriela Marta
Crapiste, Guillermo Hector
Damiani, Daniel Eduardo
author2_role author
author
author
dc.subject.none.fl_str_mv Hydrogenation
Nickel
Sfc
Sunflower Oil
Trans-Isomers
topic Hydrogenation
Nickel
Sfc
Sunflower Oil
Trans-Isomers
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv In the present paper the performance of commercial Ni catalyst in edible oil hydrogenation is evaluated under different operating conditions. Particularly, the influence of mass transport resistance on the trans-isomers selectivity is analyzed. Initially a series of experiments aim to analyze the effect of four process variables (reaction temperature, hydrogen bubbling device, agitation rate and stirrer design) on catalyst activity and selectivity to trans-isomers. These experiments are conducted in diffusional regimes. A simpler set of experiments is carried out operating under conditions that allow the authors to neglect some diffusional resistances although those associated to the catalyst are still present. In the first case activity and selectivity appear to be independent of the hydrogen bubbling system and the catalyst loading. The whole set of data analyzed in terms of the C18:1/C18:20 ratio as a function of the C18:2/C18:20 ratio shows that the former, a sort of selectivity, depends on the agitation regime. The formation of trans-isomers however, appears to be a function of the reaction extent only.
Fil: Fernández, María Belén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Tonetto, Gabriela Marta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Crapiste, Guillermo Hector. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Damiani, Daniel Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description In the present paper the performance of commercial Ni catalyst in edible oil hydrogenation is evaluated under different operating conditions. Particularly, the influence of mass transport resistance on the trans-isomers selectivity is analyzed. Initially a series of experiments aim to analyze the effect of four process variables (reaction temperature, hydrogen bubbling device, agitation rate and stirrer design) on catalyst activity and selectivity to trans-isomers. These experiments are conducted in diffusional regimes. A simpler set of experiments is carried out operating under conditions that allow the authors to neglect some diffusional resistances although those associated to the catalyst are still present. In the first case activity and selectivity appear to be independent of the hydrogen bubbling system and the catalyst loading. The whole set of data analyzed in terms of the C18:1/C18:20 ratio as a function of the C18:2/C18:20 ratio shows that the former, a sort of selectivity, depends on the agitation regime. The formation of trans-isomers however, appears to be a function of the reaction extent only.
publishDate 2007
dc.date.none.fl_str_mv 2007-02-21
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/83517
Fernández, María Belén; Tonetto, Gabriela Marta; Crapiste, Guillermo Hector; Damiani, Daniel Eduardo; Revisiting the hydrogenation of sunflower oil over a Ni catalyst; Elsevier; Journal of Food Engineering; 82; 2; 21-2-2007; 199-208
0260-8774
CONICET Digital
CONICET
url http://hdl.handle.net/11336/83517
identifier_str_mv Fernández, María Belén; Tonetto, Gabriela Marta; Crapiste, Guillermo Hector; Damiani, Daniel Eduardo; Revisiting the hydrogenation of sunflower oil over a Ni catalyst; Elsevier; Journal of Food Engineering; 82; 2; 21-2-2007; 199-208
0260-8774
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0260877407000908
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jfoodeng.2007.02.010
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613232866623488
score 13.069144

Publicaciones similares