Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties

Autores
Osiry, Hernández; Cano, A.; Lemus Santana, Ana Adela; Rodríguez, Alejandro; Carbonio, Raul Ernesto; Reguera, Edilso
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This contribution discusses the intercalation of imidazole and its 2-ethyl derivative, and pyridine in 2D copper nitroprusside. In the interlayer region, neighboring molecules remain interacting throu gh their dipole and quadrupole moments, which supports the solid 3D crystal structure. The crystal structure of this series of intercalation compounds was solved and refined from powder X-ray diffraction patterns complemented with spectroscopic information. The intermolecular interactions were studied from the refined crystal structures and low temperature magnetic measurements. Due to strong attractive forces between neighboring molecules, the resulting π–π cloud overlapping enables the ferromagnetic coupling between metal centers on neighboring layers, which was actually observed for the solids containing imidazole and pyridine as intercalated molecules. For these two solids, the magnetic data were properly described with a model of six neighbors. For the solid containing 2-ethylimidazole and for 2D copper nitroprusside, a model of four neighbors in a plane is sufficient to obtain a reliable data fitting.
Fil: Osiry, Hernández. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Fil: Cano, A.. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Fil: Lemus Santana, Ana Adela. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Fil: Rodríguez, Alejandro. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Reguera, Edilso. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Materia
2-D Copper Nitroprusside
Intercalation of Organic Molecules
Intermolecular Interactions
Hybrid Inorganic Organic Solids
Molecular Magnets
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/52591
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/52591
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic propertiesOsiry, HernándezCano, A.Lemus Santana, Ana AdelaRodríguez, AlejandroCarbonio, Raul ErnestoReguera, Edilso2-D Copper NitroprussideIntercalation of Organic MoleculesIntermolecular InteractionsHybrid Inorganic Organic SolidsMolecular Magnetshttps://purl.org/becyt/ford/1.3https://purl.org/becyt/ford/1This contribution discusses the intercalation of imidazole and its 2-ethyl derivative, and pyridine in 2D copper nitroprusside. In the interlayer region, neighboring molecules remain interacting throu gh their dipole and quadrupole moments, which supports the solid 3D crystal structure. The crystal structure of this series of intercalation compounds was solved and refined from powder X-ray diffraction patterns complemented with spectroscopic information. The intermolecular interactions were studied from the refined crystal structures and low temperature magnetic measurements. Due to strong attractive forces between neighboring molecules, the resulting π–π cloud overlapping enables the ferromagnetic coupling between metal centers on neighboring layers, which was actually observed for the solids containing imidazole and pyridine as intercalated molecules. For these two solids, the magnetic data were properly described with a model of six neighbors. For the solid containing 2-ethylimidazole and for 2D copper nitroprusside, a model of four neighbors in a plane is sufficient to obtain a reliable data fitting.Fil: Osiry, Hernández. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; MéxicoFil: Cano, A.. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; MéxicoFil: Lemus Santana, Ana Adela. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; MéxicoFil: Rodríguez, Alejandro. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; MéxicoFil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Reguera, Edilso. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; MéxicoAcademic Press Inc Elsevier Science2015-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/52591Osiry, Hernández; Cano, A.; Lemus Santana, Ana Adela; Rodríguez, Alejandro; Carbonio, Raul Ernesto; et al.; Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 230; 10-2015; 374-3800022-4596CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022459615300931info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jssc.2015.07.042info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:13:33Zoai:ri.conicet.gov.ar:11336/52591instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:13:34.098CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties
title Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties
spellingShingle Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties
Osiry, Hernández
2-D Copper Nitroprusside
Intercalation of Organic Molecules
Intermolecular Interactions
Hybrid Inorganic Organic Solids
Molecular Magnets
title_short Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties
title_full Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties
title_fullStr Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties
title_full_unstemmed Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties
title_sort Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties
dc.creator.none.fl_str_mv Osiry, Hernández
Cano, A.
Lemus Santana, Ana Adela
Rodríguez, Alejandro
Carbonio, Raul Ernesto
Reguera, Edilso
author Osiry, Hernández
author_facet Osiry, Hernández
Cano, A.
Lemus Santana, Ana Adela
Rodríguez, Alejandro
Carbonio, Raul Ernesto
Reguera, Edilso
author_role author
author2 Cano, A.
Lemus Santana, Ana Adela
Rodríguez, Alejandro
Carbonio, Raul Ernesto
Reguera, Edilso
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv 2-D Copper Nitroprusside
Intercalation of Organic Molecules
Intermolecular Interactions
Hybrid Inorganic Organic Solids
Molecular Magnets
topic 2-D Copper Nitroprusside
Intercalation of Organic Molecules
Intermolecular Interactions
Hybrid Inorganic Organic Solids
Molecular Magnets
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.3
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This contribution discusses the intercalation of imidazole and its 2-ethyl derivative, and pyridine in 2D copper nitroprusside. In the interlayer region, neighboring molecules remain interacting throu gh their dipole and quadrupole moments, which supports the solid 3D crystal structure. The crystal structure of this series of intercalation compounds was solved and refined from powder X-ray diffraction patterns complemented with spectroscopic information. The intermolecular interactions were studied from the refined crystal structures and low temperature magnetic measurements. Due to strong attractive forces between neighboring molecules, the resulting π–π cloud overlapping enables the ferromagnetic coupling between metal centers on neighboring layers, which was actually observed for the solids containing imidazole and pyridine as intercalated molecules. For these two solids, the magnetic data were properly described with a model of six neighbors. For the solid containing 2-ethylimidazole and for 2D copper nitroprusside, a model of four neighbors in a plane is sufficient to obtain a reliable data fitting.
Fil: Osiry, Hernández. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Fil: Cano, A.. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Fil: Lemus Santana, Ana Adela. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Fil: Rodríguez, Alejandro. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Reguera, Edilso. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
description This contribution discusses the intercalation of imidazole and its 2-ethyl derivative, and pyridine in 2D copper nitroprusside. In the interlayer region, neighboring molecules remain interacting throu gh their dipole and quadrupole moments, which supports the solid 3D crystal structure. The crystal structure of this series of intercalation compounds was solved and refined from powder X-ray diffraction patterns complemented with spectroscopic information. The intermolecular interactions were studied from the refined crystal structures and low temperature magnetic measurements. Due to strong attractive forces between neighboring molecules, the resulting π–π cloud overlapping enables the ferromagnetic coupling between metal centers on neighboring layers, which was actually observed for the solids containing imidazole and pyridine as intercalated molecules. For these two solids, the magnetic data were properly described with a model of six neighbors. For the solid containing 2-ethylimidazole and for 2D copper nitroprusside, a model of four neighbors in a plane is sufficient to obtain a reliable data fitting.
publishDate 2015
dc.date.none.fl_str_mv 2015-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/52591
Osiry, Hernández; Cano, A.; Lemus Santana, Ana Adela; Rodríguez, Alejandro; Carbonio, Raul Ernesto; et al.; Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 230; 10-2015; 374-380
0022-4596
CONICET Digital
CONICET
url http://hdl.handle.net/11336/52591
identifier_str_mv Osiry, Hernández; Cano, A.; Lemus Santana, Ana Adela; Rodríguez, Alejandro; Carbonio, Raul Ernesto; et al.; Intercalation of organic molecules in 2D copper (II) nitroprusside: Intermolecular interactions and magnetic properties; Academic Press Inc Elsevier Science; Journal of Solid State Chemistry; 230; 10-2015; 374-380
0022-4596
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0022459615300931
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jssc.2015.07.042
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Academic Press Inc Elsevier Science
publisher.none.fl_str_mv Academic Press Inc Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.993085

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