Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds

Autores
Gil, Diego Mauricio; Osiry, Hernández; Pomiro, Fernando; Varetti, Eduardo Lelio; Carbonio, Raul Ernesto; Alejandro, R. R.; Ben Altabef, Aída; Reguera, Edilso
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The hydrogen bond and π-π stacking are two non-covalent interactions able to support cooperative magnetic ordering between paramagnetic centers. This contribution reports the crystal structure and related magnetic properties for VO[Fe(CN)5NO]·2H2O, which has a layered structure. This solid crystallizes with an orthorhombic unit cell, in the Pna21 space group, with cell parameters a=14.1804(2), b=10.4935(1), c=7.1722(8) Å and four molecules per unit cell (Z=4). Its crystal structure was solved and refined from powder X-ray diffraction data. Neighboring layers remain linked through a network of hydrogen bonds involving a water molecule coordinated to the axial position for the V atom and the unbridged axial NO and CN ligands. An uncoordinated water molecule is found forming a triple bridge between these last two ligands and the coordinated water molecule. The magnetic measurements, recorded down to 2 K, shows a ferromagnetic interaction between V atoms located at neighboring layers, with a Curie-Weiss constant of 3.14 K. Such ferromagnetic behavior was interpreted as resulting from a superexchange interaction through the network of strong OH····OH2O, OH····NCN, and OH····ONO hydrogen bonds that connects neighboring layers. The interaction within the layer must be of antiferromagnetic nature and it was detected close to 2 K.
Fil: Gil, Diego Mauricio. Universidad Nacional de Tucuman. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Osiry, Hernández. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Fil: Pomiro, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Fil: Varetti, Eduardo Lelio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Alejandro, R. R.. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Fil: Ben Altabef, Aída. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
Fil: Reguera, Edilso. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Materia
Nitroprusside
Molecular Magnetism
Hydrogen Bonds
Layered Solid
Vanadyl
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/27090
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/27090
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bondsGil, Diego MauricioOsiry, HernándezPomiro, FernandoVaretti, Eduardo LelioCarbonio, Raul ErnestoAlejandro, R. R.Ben Altabef, AídaReguera, EdilsoNitroprussideMolecular MagnetismHydrogen BondsLayered SolidVanadylhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The hydrogen bond and π-π stacking are two non-covalent interactions able to support cooperative magnetic ordering between paramagnetic centers. This contribution reports the crystal structure and related magnetic properties for VO[Fe(CN)5NO]·2H2O, which has a layered structure. This solid crystallizes with an orthorhombic unit cell, in the Pna21 space group, with cell parameters a=14.1804(2), b=10.4935(1), c=7.1722(8) Å and four molecules per unit cell (Z=4). Its crystal structure was solved and refined from powder X-ray diffraction data. Neighboring layers remain linked through a network of hydrogen bonds involving a water molecule coordinated to the axial position for the V atom and the unbridged axial NO and CN ligands. An uncoordinated water molecule is found forming a triple bridge between these last two ligands and the coordinated water molecule. The magnetic measurements, recorded down to 2 K, shows a ferromagnetic interaction between V atoms located at neighboring layers, with a Curie-Weiss constant of 3.14 K. Such ferromagnetic behavior was interpreted as resulting from a superexchange interaction through the network of strong OH····OH2O, OH····NCN, and OH····ONO hydrogen bonds that connects neighboring layers. The interaction within the layer must be of antiferromagnetic nature and it was detected close to 2 K.Fil: Gil, Diego Mauricio. Universidad Nacional de Tucuman. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Osiry, Hernández. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; MéxicoFil: Pomiro, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; ArgentinaFil: Varetti, Eduardo Lelio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; ArgentinaFil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Alejandro, R. R.. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; MéxicoFil: Ben Altabef, Aída. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; ArgentinaFil: Reguera, Edilso. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; MéxicoElsevier Inc2016-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/27090Gil, Diego Mauricio; Osiry, Hernández; Pomiro, Fernando; Varetti, Eduardo Lelio; Carbonio, Raul Ernesto; et al.; Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds; Elsevier Inc; Journal of Solid State Chemistry; 239; 4-2016; 159-1640022-4596CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.jssc.2016.04.025info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022459616301578info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:43:59Zoai:ri.conicet.gov.ar:11336/27090instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:43:59.795CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds
title Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds
spellingShingle Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds
Gil, Diego Mauricio
Nitroprusside
Molecular Magnetism
Hydrogen Bonds
Layered Solid
Vanadyl
title_short Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds
title_full Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds
title_fullStr Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds
title_full_unstemmed Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds
title_sort Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds
dc.creator.none.fl_str_mv Gil, Diego Mauricio
Osiry, Hernández
Pomiro, Fernando
Varetti, Eduardo Lelio
Carbonio, Raul Ernesto
Alejandro, R. R.
Ben Altabef, Aída
Reguera, Edilso
author Gil, Diego Mauricio
author_facet Gil, Diego Mauricio
Osiry, Hernández
Pomiro, Fernando
Varetti, Eduardo Lelio
Carbonio, Raul Ernesto
Alejandro, R. R.
Ben Altabef, Aída
Reguera, Edilso
author_role author
author2 Osiry, Hernández
Pomiro, Fernando
Varetti, Eduardo Lelio
Carbonio, Raul Ernesto
Alejandro, R. R.
Ben Altabef, Aída
Reguera, Edilso
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Nitroprusside
Molecular Magnetism
Hydrogen Bonds
Layered Solid
Vanadyl
topic Nitroprusside
Molecular Magnetism
Hydrogen Bonds
Layered Solid
Vanadyl
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The hydrogen bond and π-π stacking are two non-covalent interactions able to support cooperative magnetic ordering between paramagnetic centers. This contribution reports the crystal structure and related magnetic properties for VO[Fe(CN)5NO]·2H2O, which has a layered structure. This solid crystallizes with an orthorhombic unit cell, in the Pna21 space group, with cell parameters a=14.1804(2), b=10.4935(1), c=7.1722(8) Å and four molecules per unit cell (Z=4). Its crystal structure was solved and refined from powder X-ray diffraction data. Neighboring layers remain linked through a network of hydrogen bonds involving a water molecule coordinated to the axial position for the V atom and the unbridged axial NO and CN ligands. An uncoordinated water molecule is found forming a triple bridge between these last two ligands and the coordinated water molecule. The magnetic measurements, recorded down to 2 K, shows a ferromagnetic interaction between V atoms located at neighboring layers, with a Curie-Weiss constant of 3.14 K. Such ferromagnetic behavior was interpreted as resulting from a superexchange interaction through the network of strong OH····OH2O, OH····NCN, and OH····ONO hydrogen bonds that connects neighboring layers. The interaction within the layer must be of antiferromagnetic nature and it was detected close to 2 K.
Fil: Gil, Diego Mauricio. Universidad Nacional de Tucuman. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Osiry, Hernández. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Fil: Pomiro, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Fil: Varetti, Eduardo Lelio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica ; Argentina
Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Alejandro, R. R.. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
Fil: Ben Altabef, Aída. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; Argentina
Fil: Reguera, Edilso. Instituto Politécnico Nacional. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada; México
description The hydrogen bond and π-π stacking are two non-covalent interactions able to support cooperative magnetic ordering between paramagnetic centers. This contribution reports the crystal structure and related magnetic properties for VO[Fe(CN)5NO]·2H2O, which has a layered structure. This solid crystallizes with an orthorhombic unit cell, in the Pna21 space group, with cell parameters a=14.1804(2), b=10.4935(1), c=7.1722(8) Å and four molecules per unit cell (Z=4). Its crystal structure was solved and refined from powder X-ray diffraction data. Neighboring layers remain linked through a network of hydrogen bonds involving a water molecule coordinated to the axial position for the V atom and the unbridged axial NO and CN ligands. An uncoordinated water molecule is found forming a triple bridge between these last two ligands and the coordinated water molecule. The magnetic measurements, recorded down to 2 K, shows a ferromagnetic interaction between V atoms located at neighboring layers, with a Curie-Weiss constant of 3.14 K. Such ferromagnetic behavior was interpreted as resulting from a superexchange interaction through the network of strong OH····OH2O, OH····NCN, and OH····ONO hydrogen bonds that connects neighboring layers. The interaction within the layer must be of antiferromagnetic nature and it was detected close to 2 K.
publishDate 2016
dc.date.none.fl_str_mv 2016-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/27090
Gil, Diego Mauricio; Osiry, Hernández; Pomiro, Fernando; Varetti, Eduardo Lelio; Carbonio, Raul Ernesto; et al.; Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds; Elsevier Inc; Journal of Solid State Chemistry; 239; 4-2016; 159-164
0022-4596
CONICET Digital
CONICET
url http://hdl.handle.net/11336/27090
identifier_str_mv Gil, Diego Mauricio; Osiry, Hernández; Pomiro, Fernando; Varetti, Eduardo Lelio; Carbonio, Raul Ernesto; et al.; Layered vanadyl (IV) nitroprusside: Magnetic interaction through a network of hydrogen bonds; Elsevier Inc; Journal of Solid State Chemistry; 239; 4-2016; 159-164
0022-4596
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jssc.2016.04.025
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0022459616301578
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Inc
publisher.none.fl_str_mv Elsevier Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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